Hostname: page-component-586b7cd67f-dsjbd Total loading time: 0 Render date: 2024-11-24T17:39:49.171Z Has data issue: false hasContentIssue false
  • English
  • Français

Kaolinite Aggregation in Book-Like Structures from Non-Aqueous Media

Published online by Cambridge University Press:  01 January 2024

Rola Mansa ,
Guy B. Ngassa Piegang  and
Christian Detellier
Rola Mansa
Affiliation:
Center for Catalysis Research and Innovation and Department of Chemistry and Biomolecular Sciences, University of Ottawa, K1N 6N5, Ottawa, Ontario, Canada
Guy B. Ngassa Piegang
Affiliation:
Center for Catalysis Research and Innovation and Department of Chemistry and Biomolecular Sciences, University of Ottawa, K1N 6N5, Ottawa, Ontario, Canada
Christian Detellier*
Affiliation:
Center for Catalysis Research and Innovation and Department of Chemistry and Biomolecular Sciences, University of Ottawa, K1N 6N5, Ottawa, Ontario, Canada
*
*E-mail address of corresponding author: [email protected]
Rights & Permissions [Opens in a new window]

Abstract

Core share and HTML view are not available for this content. However, as you have access to this content, a full PDF is available via the ‘Save PDF’ action button.

To control a vast spectrum of applications and processes, an understanding of the morphologies of clay mineral assemblies dispersed in aqueous or non-aqueous media is important. As such, the objective of this study was to verify the relationship between dispersion medium type and the size and morphology of the clay aggregates that are formed, which can increase knowledge on the assembly formation process. Scanning electron microscopy (SEM), X-ray diffraction (XRD), and Fourier-transform infrared (FTIR) spectroscopy were used in an attempt to describe kaolinite platelet organization in non-aqueous media and to compare it to the organization in aqueous media or in media with or without a selection of dissolved organic polymers. The SEM images indicated that the kaolinite platelet assembly process occurs during slow evaporation of the solvent. Because the experimental procedure was rigorously identical for all cases in this study, the SEM images compared how the effects of various media and environments on kaolinite platelet interactions can lead to different morphologies. Quite spectacular morphological differences were indeed observed between samples dispersed in aqueous and non-aqueous media, particularly when the kaolinite platelets were dispersed in an organic solvent with dissolved organic polymers. For kaolinite dispersed in water, only small aggregates were observed after slow evaporation. In contrast, large kaolinite booklets or vermiform aggregates were formed by slow solvent evaporation when kaolinite was first dispersed into some organic solvents. The aggregates were particularly large when an organic polymer was dissolved in the organic solvent. For example, kaolinite aggregates dispersed in a binary cyclohexane/toluene mixture with dissolved ethyl cellulose (EC) had top apparent surface areas (i.e. stacking length × width) of more than 3,000 µm2. Other dissolved polymers, such as polystyrene or the polysaccharide, guar gum, gave similar results. Kaolinite platelet aggregation resulted from face-to-face interactions as well as edge-to-face and edge-to-edge interactions. The XRD results showed that ethyl cellulose led to the formation of smaller kaolinite platelets with an increased tendency to form larger aggregates, which is due to the ability of EC to chemically interact with silanol and/or the aluminol groups of kaolinite.

Keywords

AggregationAqueous MediaBookletsKaoliniteMorphologyNon-aqueous MediaOrganic SolventPlateletPolymerVermiform Structure
Type
Article
Information
Clays and Clay Minerals , Volume 65 , Issue 3 , June 2017 , pp. 193 - 205
Copyright
Copyright © Clay Minerals Society 2017

References

Adeyinka, O.B. Samiei, S. Xu, Z., and Masliyah, J.H., 2009 Effect of particle size on the rheology of Athabasca clay suspensions Canadian Journal of Chemical Engineering 87 422–434.CrossRefGoogle Scholar
Aung, L.L. Tertre, E., and Petit, S., 2015 Effect of the morphology of synthetic kaolinites on their sorption properties Journal of Colloid and Interface Science 443 177–186.CrossRefGoogle ScholarPubMed
Balköse, D. Horak, D., and Soltès, L., 2014 Key Enginering Materials, Vol. 1: Current State-of-the-Art on Novel Materials Boca Raton, Florida, USA CRC Press 445–446.CrossRefGoogle Scholar
Beaufort, D. Cassagnabere, A. Petit, S. Lanson, B. Berger, G. Lacharpagne, J.C., and Johansen, H., 1998 Kaolinite-todickite reaction in sandstone reservoirs Clay Minerals 33 297–316.CrossRefGoogle Scholar
Brack, A., Bergaya, F. and Lagaly, G., 2013 Clay minerals and the origin of life Handbook of Clay Science, 2nd Edition; Developments in Clay Science 507–522.CrossRefGoogle Scholar
Brigatti, M.F. Galán, E. Theng, B.K.G., Bergaya, F. and Lagaly, G., 2013 Structure and mineralogy of clay minerals Handbook of Clay Science, 2nd Edition; Developments in Clay Science 29–35.CrossRefGoogle Scholar
Brindley, G.W., Brindley, G.W., and Brown, G., 1980 Order-disorder in clay mineral structures Crystal Structures of Clay Minerals and their X-ray Identification 125–195.CrossRefGoogle Scholar
Christidis, G.E., Bergaya, F. and Lagaly, G., 2013 Assessment of industrial clays Handbook of Clay Science, 2nd Edition; Developments in Clay Science, Volume 5, Part A 425–450.CrossRefGoogle Scholar
Dedzo, G.K., and Detellier, C., 2016 Functional nanohybrid materials derived from kaolinite Applied Clay Science 130 33–39.CrossRefGoogle Scholar
Detellier, C., and Schoonheydt, R.A., 2014 From platy kaolinite to nanorolls Elements 10 201–206.CrossRefGoogle Scholar
Detellier, C. Letaief, S. Fafard, J. and Dedzo, G.K., 2015.Desorption of bitumen from clay particles and mature fine tailingsGoogle Scholar
Dziadkowiek, J. Mansa, R. Quintela, A. Rocha, F., and Detellier, C., 2017 Preparation, characterization and application in controlled release of Ibuprofen-loaded guar gum/Montmorillonite bionanocomposites Applied Clay Science 135 52–63.CrossRefGoogle Scholar
Eberl, D.D. Drits, V. Srodon, J. and Nüesch, R., 1996.MudMaster: A program for calculating crystallite size distributions and strain from the shapes of X-ray diffraction peaks US Geological Survey Open File ReportCrossRefGoogle Scholar
Fafard, J. Lyubimova, O. Stoyanov, S.R. Dedzo, G.K. Gusarov, S. Kovalenko, A., and Detellier, C., 2013 Adsorption of indole on kaolinite in non-aqueous media: organoclay preparation and characterization, and 3D-RISMKH molecular theory of solvation investigation Journal of Physical Chemistry 117 18556–18566.Google Scholar
Franco, F. Pérez-Maqueda, L.A., and Pérez-Rodriguez, J.L., 2004 The effect of ultrasound on the particle size and structural disorder of a well-ordered kaolinite Journal of Colloid and Interface Science 274 107–117.CrossRefGoogle ScholarPubMed
Galimberti, M. Cipolletti, V.R. Coombs, M., Bergaya, F. and Lagaly, G., 2013 Applications of clay-polymer nanocomposites Handbook of Clay Science, 2nd Edition; Developments in Clay Science 539–586.CrossRefGoogle Scholar
Giese, R.F., 1982 Theoretical studies of the kaolin minerals electrostatic calculations Bulletin de Minéralogie 105 417–424.CrossRefGoogle Scholar
Gupta, V. Hampton, M.A. Stokes, J.R. Nguyen, A.V., and Miller, J.D., 2011 Particle interactions in kaolinite suspensions and corresponding aggregate structures Journal of Colloid and Interface Science 359 95–103.CrossRefGoogle ScholarPubMed
Hu, Y. Liu, L. Min, F. Zhang, M., and Song, S., 2013 Hydrophobic agglomeration of colloidal kaolinite in aqueous suspensions with dodecylamine Colloids and Surfaces A: Physicochem. Engineering. Aspects 434 281–286.CrossRefGoogle Scholar
Johnston, C.T., 2010 Probing the nanoscale architecture of clay minerals Clay Minerals 45 245–279.CrossRefGoogle Scholar
Kameda, J. Saruwatari, K. Beaufort, D., and Kogure, T., 2008 Textures and polytypes in vermiform kaolins diagenetically formed in a sandstone reservoir: A FIB-TEM investigation European Journal of Mineralogy 20 199–204.CrossRefGoogle Scholar
Laszlo, P., 1986 Catalysis of organic reactions by inorganic solids Accounts of Chemical Research 19 121–127.CrossRefGoogle Scholar
Lin, F. He, L. Hou, J. Masliyah, J., and Xu, Z., 2016 Role of ethyl cellulose in bitumen extraction from oil sands ores using an aqueous-nonaqueous hybrid process Energy & Fuels 30 121–129.CrossRefGoogle Scholar
Liu, J. Gaikwad, R. Hande, A. Das, S., and Thundat, T., 2015 Mapping and quantifying surface charges on clay nanoparticles Langmuir 31 10469–10476.CrossRefGoogle ScholarPubMed
Liu, J. Lin, C., and Miller, J.D., 2015 Simulation of cluster formation from kaolinite suspensions International Journal of Mineral Processing 145 38–47.CrossRefGoogle Scholar
Liu, X. Lu, X. Sprik, M. Cheng, J. Meijer, E.J., and Wang, R., 2013 Acidity of edge surface sites of montmorillonite and kaolinite Geochimica et Cosmochimica Acta 117 180–190.CrossRefGoogle Scholar
Mansa, R., and Detellier, C., 2013 Preparation and characterization of guar-montmorillonite nanocomposites Materials 6 5199–5216.CrossRefGoogle ScholarPubMed
Mccabe, R.W. Adams, J.M., Bergaya, F. and Lagaly, G., 2013 Clay minerals as catalysts Handbook of Clay Science, 2nd Edition; Developments in Clay Science 491–523.CrossRefGoogle Scholar
Moll, W.F. Jr., 2001 Baseline studies of The Clay Minerals Society source clays: geological origin Clays and Clay Minerals 49 374–380.CrossRefGoogle Scholar
Morato, A., and Rives, V., 2017 Comments on the application of the Scherrer equation Applied Catalysis B: Environmental 202 418–419.CrossRefGoogle Scholar
Murray, H.H. Keller, W.D., Murray, H.H. Bundy, W.M., and Harvey, C.C., 1993 Kaolins, kaolins, and kaolins Kaolin Genesis and Utilization Boulder, Colorado, USA. The Clay Minerals Society 1–24.CrossRefGoogle Scholar
Ngnie, G. Dedzo, G.K., and Detellier, C., 2016 Synthesis and catalytic application of palladium nanoparticles supported on kaolini te-based nanohybrid materials Dalton Transactions 45 9065–9072.CrossRefGoogle Scholar
Nikakhtari, H. Pal, K. Wolf, S. Choi, P. Liu, Q., and Gray, M.R., 2016 Solvent removal from cyclohexane-extracted oil sands gangue Canadian Journal of Chemical Engineering 94 408–414.CrossRefGoogle Scholar
Osacky, M. Geramian, M. Ivey, D.G. Liu, Q., and Etsell, T.H., 2013 Mineralogical and chemical composition of petrologic end members of Alberta oil sands Fuel 113 148–157.CrossRefGoogle Scholar
Pruett, R.J., and Webb, H.L., 1993 Sampling and analysis of KGa-1b well-crystallized kaolin source clay Clays and Clay Minerals 41 514–519.CrossRefGoogle Scholar
Psyrillos, A. Howe, J.H. Manning, D.A.C., and Burley, S.D., 1999 Geological shape and controls on kaolin particle and consequences for mineral processing Clay Minerals 34 193–208.CrossRefGoogle Scholar
Rebertus, R.A. Weed, S.B., and Buol, S.W., 1986 Transformations of biotite to kaolinite during saprolite-soil weathering Soil Science Society of America Journal 50 810–819.CrossRefGoogle Scholar
Schroeder, P.A., and Erickson, G., 2014 Kaolin: from ancient porcelains to nanocomposites Elements 10 177–182.CrossRefGoogle Scholar
Srivastava, M., and Kapoor, V.P., 2005 Seed gallactomannans: An overview Chemistry & Biodiversity 2 295–317.CrossRefGoogle ScholarPubMed
Warren, B.E., and Bodenstein, P., 1966 The shape of two dimensional carbon black reflections Acta Crystallographica 20 602–605.CrossRefGoogle Scholar
Wilson, MJ W L I, 2014 The influence of individual clay minerals on formation damage of reservoir sandstones: a critical review with some new insights Clay Minerals 49 147–164.CrossRefGoogle Scholar
Yong, R.N., and Mourato, D., 1990 Influence of polysaccharides on kaolinite structure and properties in a kaolinitewater system Canadian Geotechnical Journal 27 774–788.CrossRefGoogle Scholar