Hostname: page-component-78c5997874-4rdpn Total loading time: 0 Render date: 2024-11-15T15:17:11.681Z Has data issue: false hasContentIssue false
  • English
  • Français

Hydroxy-Interlayers in Expansible Layer Silicates and Their Relation to Potassium Fixation

Published online by Cambridge University Press:  28 February 2024

Uttam K. Saha  and
Katsuhiro Inoue
Uttam K. Saha*
Affiliation:
Faculty of Agriculture, Iwate University, 3-18-8 Ueda, Morioka 020, Japan
Katsuhiro Inoue
Affiliation:
Faculty of Agriculture, Iwate University, 3-18-8 Ueda, Morioka 020, Japan
*
†Permanent address: Bangabandhu University of Post-graduate Education in Agriculture, Gazipur-1703, Bangladesh.
Rights & Permissions [Opens in a new window]

Abstract

Core share and HTML view are not available for this content. However, as you have access to this content, a full PDF is available via the ‘Save PDF’ action button.

Hydroxyaluminosilicate (HAS) and hydroxyaluminum (HyA) ionic solutions having final Al concentrations ranging from 3.74 to 4.00 mM; NaOH/Al molar ratios of 1.0, 2.0 and 2.5; and Si/Al molar ratios of 0.00, 0.27–0.30, 0.51–0.56 and 0.95–1.01 were prepared through the interaction of AlCl3, or-thosilicic acid and NaOH solutions. When these solutions reacted with <2 µm sized vermiculite (Vt) and montmorillonite (Mt), varying amounts of Al and Si were fixed on Vt and Mt clays. Potassium fixation and exchange capacities of HyA/HAS (OH/Al = 1.0, 2.0 and 2.5)-Vt and HyA/HAS (OH/AI = 2.0)-Mt complexes were compared with those of untreated Vt and Mt at added K levels ranging from 21 to 319 cmolc kg−1. The untreated Vt clay showed K fixation as high as 94 cmolc kg−1, in contrast to only 16 cmolc kg−1 exchangeable K. The untreated Mt fixed a maximum of 9 cmolc K kg−1 out of a total K adsorption capacity of 67 creole kg−1. In the HyA/HAS-Vt complexes, K fixation reduced drastically in comparison to untreated Vt, and ranged from 9 to 24 cmolc kg−1 out of their total K adsorption capacities of 61 to 81 cmolc kg−1. In the HyA/HAS-Mt complexes, too, the amount of K fixed reduced to a great extent in comparison to Mt and ranged from 1.48 to 1.84 cmolc kg−1. Potassium became more exchangeable due to the presence of hydroxy-interlayers in the clays. The reduction in CEC and the well-known propping effects of hydroxy-cations’ islands in the interlayers might have hindered K fixation by the complexes. The relationships of maximum K fixing capacities of the HyA/HAS-Vt complexes with the amounts of Al, Si and Al + Si fixed on Vt were all exponential and negative. However, the amount of Al + Si or only Al fixed on Vt appeared to be the best indicator of K fixation capacities of hydroxyinterlayered Vt clay.

Keywords

HydroxyaluminumHydroxyaluminosilicateMontmorillonitePotassium FixationVermiculite
Type
Research Article
Information
Clays and Clay Minerals , Volume 46 , Issue 5 , October 1998 , pp. 556 - 566
Copyright
Copyright © 1998, The Clay Minerals Society

Footnotes

‡

Deceased 16 August 1998.

References

Akitt, J.W. and Farthing, A., 1981 Aluminum-27 nuclear magnetic resonance studies of hydrolysis of aluminum (III). Part 3: Stopped-flow kinetic studies J Chem Soc Dalton Trans 1981 1609–1614 10.1039/dt9810001609.CrossRefGoogle Scholar
Bamhisel, R.I. Bertsch, P.M., Dixon, J.B. and Weed, S.B., 1989 Chlorites and hydroxy-interlayered vermiculite and smectite Minerals in soil environments Madison, WI Soil Sci Soc Am. 729–788.Google Scholar
Barshad, I., 1948 Vermiculite and its relation to biotite as revealed by base exchange reactions, X-ray analysis, differential thermal curves and water content Am Mineral 33 655–678.Google Scholar
Barshad, I., 1950 The effect of the interlayer cations on the expansion of mica type crystal lattice Am Mineral 35 225–238.Google Scholar
Bautista-Tulin, A.T. and Inoue, K., 1997 Hydroxy-interlayered minerals in Japanese soils influenced by eolian deposition Soil Sci Soc Am J 61 631–640 10.2136/sssaj1997.03615995006100020037x.CrossRefGoogle Scholar
Bertsch, P.M. Layton, W.J. and Barnhisel, R.I., 1986 Speciation of hydroxy-aluminum solution by wet chemical and aluminum-27 NMR methods Soil Sci Soc Am J 50 1449–1454 10.2136/sssaj1986.03615995005000060014x.CrossRefGoogle Scholar
Bertsch, P.M. Parker, D.R. and Sposito, G., 1996 Aqueous polynuclear aluminum species The environmental chemistry of aluminum Tokyo Lewis Publ, CRC Pr. 117–168.Google Scholar
Bottero, J.Y. Cases, J.M. Fiessinger, F. and Poirier, J.E., 1980 Studies on the hydrolyzed aluminum chloride solutions: 1. Nature of aluminum species and composition of aqueous solution J Phys Chem 84 2933–2939 10.1021/j100459a021.CrossRefGoogle Scholar
Davenport, W.H., 1949 Determination of aluminum in presence of iron-spectrophotometric method using ferron Ana Chem 21 710–711 10.1021/ac60030a020.CrossRefGoogle Scholar
Farmer, V.C., 1981 Possible roles of a mobile hydroxyaluminium orthosilicate complex (proto-imogolite) and other hydroxyaluminium and hydroxy-iron species in podzolization Colloques Int CNRS 303 275–279.Google Scholar
Farmer, V.C. Fraser, A.R. and Tait, J.M., 1979 Characterization of chemical structure of natural and synthetic aluminosilicate gels and sols by infrared spectroscopy Geochim Cosmochim Acta 43 1417–1420 10.1016/0016-7037(79)90135-2.CrossRefGoogle Scholar
Grim, R.E., 1968 Clay mineralogy McGraw-Hill New York.Google Scholar
Hsu, P.H., Dixon, J.B. and Weed, S.B., 1989 Aluminum oxides and oxyhydroxides Minerals in soil environments Madison, WI Soil Sci Soc Am. 331–371.Google Scholar
Hsu, P.H., 1992 Reaction of OH-Al polymers with smectites and ventriculites Clays Clay Miner 40 300–305 10.1346/CCMN.1992.0400308.CrossRefGoogle Scholar
Inoue, A., 1983 Potassium fixation by clay minerals during hydrothermal treatment Clays Clay Miner 31 81–91 10.1346/CCMN.1983.0310201.CrossRefGoogle Scholar
Inoue, K. Pavan, M.A. and Yoshida, M., 1988 Fixation of hydroxyaluminosilicate ions (proto-imogolite) on smectite Soil Sci Plant Nutr 34 277–285 10.1080/00380768.1988.10415682.CrossRefGoogle Scholar
Inoue, K. and Satoh, C., 1992 Electric charge and surface characteristics of hydroxyaluminosilicate- and hydroxyaluminum-vermiculite complexes Clays Clay Miner 40 311–318 10.1346/CCMN.1992.0400310.CrossRefGoogle Scholar
Inoue, K. and Satoh, C., 1993 Surface charge characteristics of hydroxyaluminosilicate- and hydroxyaluminum-vermiculite complexes Soil Sci Soc Am J 57 547–552.CrossRefGoogle Scholar
Jackson, M.L., 1963 Interlayering of expansible layer silicates in soils by chemical weathering Clays Clay Miner 11 29–46 10.1346/CCMN.1962.0110104.CrossRefGoogle Scholar
Jackson, M.L., 1979 Soil chemical analysis—Advanced course 2nd ed. Madison, WI Jackson ML, Univ of Wisconsin.Google Scholar
Kittrick, J.A., 1966 Forces involved in ion fixation by vermiculite Soil Sci Soc Am Proc 30 801–803 10.2136/sssaj1966.03615995003000060040x.CrossRefGoogle Scholar
Kozak, L.M. and Huang, P.M., 1971 Adsorption of hydroxy-Al by certain phyllosilicates and its relation to K/Ca cation exchange selectivity Clays Clay Miner 19 95–102 10.1346/CCMN.1971.0190205.CrossRefGoogle Scholar
Lou, G. and Huang, P.M., 1988 Hydroxy-aluminosilicate interlayers in montmorillonite: Implications for acidic environments Nature 335 625–627 10.1038/335625a0.CrossRefGoogle Scholar
Lou, G.Q.J. and Huang, P.M., 1994 Interlayer adsorption of hydroxy-aluminosilicate ions by montmorillonite Soil Sci Soc Am J 58 745–750 10.2136/sssaj1994.03615995005800030015x.CrossRefGoogle Scholar
Mackenzie, R.C., Rosenqvist, T. and Graff-Petersen, P., 1963 Retention of exchangeable ions by montmorillonite Proc Int Clay Conf Stockholm. Oxford Pergamon Pr. 183–193.Google Scholar
Manley, E.P. Chesworth, W. and Evans, L.J., 1987 The solution chemistry of podzolic soils from eastern Canadian shields: A thermodynamic interpretation of mineral phases controlling soluble Al3+ and H4SiO4 J Soil Sci 38 39–51 10.1111/j.1365-2389.1987.tb02121.x.CrossRefGoogle Scholar
Matsue, N. and Wada, K., 1988 Interlayer materials of partially interlayered vermiculite in Dystrochrepts derived from Tertiary sediments J Soil Sci 39 155–162 10.1111/j.1365-2389.1988.tb01202.x.CrossRefGoogle Scholar
Mehra, O.P. Jackson, M.L., Swineford, A. and Plummer, N., 1960 Iron oxide removal from soils and clays by a dithionite-citrate system buffered with sodium bicarbonates Clays Clay Miner, Proc 7th Natl Conf New York Pergamon Pr. 317–327.Google Scholar
Nagasawa, K. Brown, G. and Newman, A.C.D., 1974 Artificial alteration of biotite into a 14A layer silicate with hydroxyaluminum interlayers Clays Clay Miner 22 241–252 10.1346/CCMN.1974.0220306.CrossRefGoogle Scholar
Page, A.L. Burge, W.D. Ganje, T.J. and Garber, M.J., 1967 Potassium and ammonium fixation by vermiculitic soils Soil Sci Soc Am Proc 31 337–341 10.2136/sssaj1967.03615995003100030016x.CrossRefGoogle Scholar
Page, J.B. and Baver, L.D., 1940 Ionic size relation to fixation of cations by colloidal clay Soil Sci Soc Am Proc 4 150–155 10.2136/sssaj1940.036159950004000C0028x.CrossRefGoogle Scholar
Parker, D.R. and Bertsch, P.M., 1992 Formation of “A113” tridecameric polycation under diverse synthesis conditions Environ Sci Technol 26 914–919 10.1021/es00029a007.CrossRefGoogle Scholar
Rich, C.I., 1960 Aluminum interlayers of vermiculites Soil Sci Soc Am Proc 24 26–32 10.2136/sssaj1960.03615995002400010016x.CrossRefGoogle Scholar
Rich, C.I., 1968 Hydroxy interlayers in expansible layer silicates Clays Clay Miner 16 15–30 10.1346/CCMN.1968.0160104.CrossRefGoogle Scholar
Rich, C.I. and Black, W.R., 1964 Potassium exchange as affected by cation size, pH and mineral structure Soil Sci 97 384–390 10.1097/00010694-196406000-00004.CrossRefGoogle Scholar
Rich, C. and Lutz, J.A. Jr, 1965 Mineralogical changes associated with ammonium and potassium fixation in soil clays Soil Sci Soc Am Proc 29 167–170 10.2136/sssaj1965.03615995002900020017x.CrossRefGoogle Scholar
Rich, C.I. and Obenshain, S.S., 1955 Chemical and clay mineral properties of a Red-Yellow Podzolic soil derived from muscovite schist Soil Sci Soc Am Proc 19 334–339 10.2136/sssaj1955.03615995001900030021x.CrossRefGoogle Scholar
Saha, U.K. and Inoue, K., 1997 Phosphate adsorption behavior of hydroxyaluminum- and hydroxyaluminosilicate-vermiculite complexes Clay Sci 10 113–132.Google Scholar
Sawhney, B.L., 1972 Selective sorption and fixation of cations by clay minerals: A review Clays Clay Miner 20 93–100 10.1346/CCMN.1972.0200208.CrossRefGoogle Scholar
Shainberg, I. and Kemper, W.D., 1966 Hydration status of adsorbed cations Soil Sci Soc Am Proc 30 707–713 10.2136/sssaj1966.03615995003000060017x.CrossRefGoogle Scholar
Shoji, S. Ito, T. Saigusa, M. and Yamada, I., 1985 Properties of nonallophanic Andisols from Japan Soil Sci 140 264–277 10.1097/00010694-198510000-00005.CrossRefGoogle Scholar
Shoji, S. Suzuki, Y. and Saigusa, M., 1987 Clay mineralogical and chemical properties of nonallophanic Andepts (Andisols) from Oregon, USA Soil Sci Soc Am J 51 986–990 10.2136/sssaj1987.03615995005100040030x.CrossRefGoogle Scholar
Somasiri, S. and Huang, P.M., 1974 Effect of hydrolysis of aluminum on competitive adsorption of potassium and aluminum by expansible phyllosilicates Soil Sci 117 110–116 10.1097/00010694-197402000-00006.CrossRefGoogle Scholar
Stanford, G., 1948 Fixation of potassium in soils under moist conditions and on drying in relation to type of clay mineral Soil Sci Soc Am Proc 12 167–171 10.2136/sssaj1948.036159950012000C0037x.CrossRefGoogle Scholar
Wada, K. and Okamura, Y., 1980 Electric charge characteristics of Ando Al and buried Al horizon soils J Soil Sci 31 307–314 10.1111/j.1365-2389.1980.tb02083.x.CrossRefGoogle Scholar
Wada, S.-I. and Wada, K., 1980 Formation, composition and structure of hydroxy-aluminosilicate ions J Soil Sci 31 457–467 10.1111/j.1365-2389.1980.tb02095.x.CrossRefGoogle Scholar
Weaver, R.M. Syers, J.K. and Jackson, M.L., 1968 Determination of silica in citrate-bicarbonate extracts of soils Soil Sci Soc Am Proc 32 497–501 10.2136/sssaj1968.03615995003200040023x.CrossRefGoogle Scholar
Wear, J.I. and White, J.L., 1951 Potassium fixation in clay minerals as related to crystal structure Soil Sci 71 1–14 10.1097/00010694-195101000-00001.CrossRefGoogle Scholar