Hostname: page-component-586b7cd67f-t7fkt Total loading time: 0 Render date: 2024-11-28T04:10:52.645Z Has data issue: false hasContentIssue false
  • English
  • Français

Hydrothermal synthesis of smectite from dickite

Published online by Cambridge University Press:  01 January 2024

Kyoung-Won Ryu ,
Young-Nam Jang ,
Soo-Chun Chae ,
In-Kook Bae  and
Sang-Hoon Choi
Kyoung-Won Ryu*
Affiliation:
Department of Earth and Environmental Sciences, Chungbuk University, Cheongju 361-763, Korea
Young-Nam Jang
Affiliation:
Korea Institute of Geoscience and Mineral Resources, Minerals and Materials Processing Division, Daejeon 305-350, Korea
Soo-Chun Chae
Affiliation:
Korea Institute of Geoscience and Mineral Resources, Minerals and Materials Processing Division, Daejeon 305-350, Korea
In-Kook Bae
Affiliation:
Korea Institute of Geoscience and Mineral Resources, Minerals and Materials Processing Division, Daejeon 305-350, Korea
Sang-Hoon Choi
Affiliation:
Department of Earth and Environmental Sciences, Chungbuk University, Cheongju 361-763, Korea
*
*E-mail address of corresponding author: [email protected]
Rights & Permissions [Opens in a new window]

Abstract

Core share and HTML view are not available for this content. However, as you have access to this content, a full PDF is available via the ‘Save PDF’ action button.

Dioctahedral smectite was prepared hydrothermally from dickite [Al2Si2O5(OH)4] as a starting material by autoclaving in a closed stainless steel vessel with variable temperature, pressure, time and pH conditions. Highly crystalline smectite can be obtained at 290°C under a pressure of 69 bar for 48 h. The pH of the solution was an important factor and should be maintained at 10 to 11 for the successful formation of smectite. Characterization by X-ray powder diffraction, scanning electron microscopy, infrared spectroscopy, thermogravimetric analysis, differential thermal analysis and the Greene-Kelly test showed that the smectite synthesized was Na-beidellite, mostly because of the heat treatment of the starting material and the stoichiometric batch composition.

Keywords

BeidelliteGreene-Kelly TestHydrothermal SynthesisSmectite
Type
Research Article
Information
Clays and Clay Minerals , Volume 54 , Issue 1 , February 2006 , pp. 80 - 86
Copyright
Copyright © 2006, The Clay Minerals Society

References

Bae, I.K. Jang, Y.N. Chae, S.C. Ryu, K.W. and Choi, S.H., (2003) Hydrothemal synthesis of saponite from talc Journal of the Mineralogical Society of Korea 16 125–133 (in Korean).Google Scholar
Bradley, W.F. and Grim, R.E., (1951) High temperature thermal effects of clay and related materials American Mineralogist 36 182–120.Google Scholar
Brown, G. Brindley, G.W., Brindley, G.W. and Brown, G., (1980) X-ray diffraction procedures for clay mineral identification Crystal Structures of Clay Minerals and their X-ray Identification London Mineralogical Society 328.Google Scholar
De Kimpe, C.R., (1975) Formation of phyllosilicate and zeolites from pure silica-alumina gels Clays and Clay Minerals 24 200–207 10.1346/CCMN.1976.0240408.CrossRefGoogle Scholar
Eberl, D.D. and Hower, J., (1977) The hydrothermal transformation of sodium and potassium smectite into mixed-layer clay Clays and Clay Minerals 25 215–227 10.1346/CCMN.1977.0250308.CrossRefGoogle Scholar
Farmer, V.C. and Farmer, V.C., (1974) The layer silicates The Infrared Spectra of Minerals London Mineralogical Society 331–363 10.1180/mono-4.15.CrossRefGoogle Scholar
Frank-Kamentskii, V.A. Kotov, N.V. and Tomashenko, A.N., (1973) The role of AlIV and AlVI in transformation and synthesis of layer silicates Kristall und Technik 8 425–435 10.1002/crat.19730080404.CrossRefGoogle Scholar
Frank-Kamentskii, V.A. Kotov, N.V. and Tomashenko, A.N., (1973) The role of AlIV (tetrahedral) and AlVI (octahedral) in layer silicate synthesis and alteration Geokhimiya 8 1153–1162 (English translation, Geochemistry International, 1973, 867–874).Google Scholar
Goh, T.B. and Huang, P.M., (1986) Influence of citric and tannic acids on hydroxy-Al interlayering in montmorillonite Clays and Clay Minerals 34 37–44 10.1346/CCMN.1986.0340105.CrossRefGoogle Scholar
Greene-Kelly, R. and Mackenzie, R.C., (1957) The montmorillonite minerals (smectite) The Differential Thermal Investigation of Clays London Mineralogical Society 140–161.Google Scholar
Grim, R.E. and Bradley, W.F., (1940) Effect of heat on illite and montmorillonite Journal of American Ceramics Society 23 242–248 10.1111/j.1151-2916.1940.tb14263.x.CrossRefGoogle Scholar
Iwasaki, T. Onodera, Y. and Torii, K., (1989) Rheological properties of organophilic synthetic hectorites and saponites Clays and Clay Minerals 37 248–257 10.1346/CCMN.1989.0370308.CrossRefGoogle Scholar
Kawano, M. and Tomita, K., (1995) Experimental study on the formation of clay minerals from obsidian by interaction with acid solution at 150°C and 200°C Clays and Clay Minerals 43 212–222 10.1346/CCMN.1995.0430208.CrossRefGoogle Scholar
Kloprogge, J.T. Jansen, J.B.H. and Geus, J.W., (1990) Characterization of synthetic Na-beidellite Clays and Clay Minerals 38 409–414 10.1346/CCMN.1990.0380410.CrossRefGoogle Scholar
Kloprogge, J.T. Van der Erden, A.M.J. Jansen, J.B.H. Geus, J.W. and Schuiling, R.D., (1993) Synthesis and paragenesis of Na-beidellite as a function of temperature, water pressure and sodium activity Clays and Clay Minerals 41 423–430 10.1346/CCMN.1993.0410403.CrossRefGoogle Scholar
Kloprogge, J.T. Komarneni, S. and Amonette, J.E., (1999) Synthesis of smectite clay minerals: A critical review Clays and Clay Minerals 47 529–554 10.1346/CCMN.1999.0470501.CrossRefGoogle Scholar
Komarneni, S. and Breval, E., (1985) Characerization of smectites synthesised from zeolites and mechanism of smectite synthesis Clay Minerals 20 181–188 10.1180/claymin.1985.020.2.03.CrossRefGoogle Scholar
MacEwan, D.M.C. Wilson, M.J., Brindley, G.W. and Brown, G., (1980) Interlayer and intercalation complexes of clay minerals Crystal Structures of Clay Minerals and their X-ray Identification London Mineralogical Society 224.Google Scholar
Nadeau, P.H. Farmer, V.C. McHardy, W.J. and Bain, D.C., (1985) Compositional variations of the Unterrupsroth beidellite American Mineralogist 70 1004–1010.Google Scholar
Nemecz, E., (1981) Clay Minerals, Part I: Genesis of Clay Budapest Akademiai Kiado.Google Scholar
Plee, D. Gatineau, L. and Fripiat, J.J., (1987) Pillaring processes of smectites with and without tetrahedral substitution Clays and Clay Minerals 35 81–88 10.1346/CCMN.1987.0350201.CrossRefGoogle Scholar
Sanji, K. Shin, K. Masayoshi, A. and Masayuki, K., (1988) Novel synthetic silicate and its manufacture .Google Scholar
Schultz, L.G., (1969) Lithium and potassium, dehydroxylation temperature, and structural water content in aluminous smectites Clays and Clay Minerals 17 115–149 10.1346/CCMN.1969.0170302.CrossRefGoogle Scholar
Schutz, A. Stone, W. Poncelet, G. and Fripiat, J.J., (1987) Preparation and characterization of bidimensional zeolitic structures obtained from synthetic beidellite and hydroxy-aluminum solution Clays and Clay Minerals 35 251–261 10.1346/CCMN.1987.0350402.CrossRefGoogle Scholar
Stubican, V. and Roy, R., (1961) A new approach to assignment of infrared absorption bands in layer-structure silicates Zeitschrift für Kristallographie 115 200–214 10.1524/zkri.1961.115.3-4.200.CrossRefGoogle Scholar
Tomita, K. and Kawano, M. (2004) Synthesis of smectite from pyroclastic flow deposit. Proceedings of International Symposium on Minerals and Materials Processing, Seoul, Korea, pp. 93–106.Google Scholar
Tomita, K. Kawano, M. and Yamane, H., (1994) Synthesis of smectite and zeolites from an obsidian at low temperature Journal of Mineralogy, Petrology and Economic Geology 89 219–226 10.2465/ganko.89.219.CrossRefGoogle Scholar
Torii, K., (1985) Industrial synthesis of trioctahedral smectite Journal of the Clay Science Society of Japan 25 71–78 (in Japanese).Google Scholar
Torii, Kazuo and Iwasaki, Takashi, (1986) Synthesis of New Trioctahedral Mg-Smectite Chemistry Letters 15 12 2021–2024 10.1246/cl.1986.2021.CrossRefGoogle Scholar
Torii, K. and Iwasaki, T., (1987) Synthesis of hectorite Clay Science 7 1–6.Google Scholar
Tsunashima, A. Konmura, F. Veda, S. Koizumi, M. and Matsushita, T., (1975) Hydrothermal synthesis of amino acid-montmorillonites and ammonium micas Clays and Clay Minerals 23 115–118 10.1346/CCMN.1975.0230206.CrossRefGoogle Scholar
Vogels, J.M.J. Breukellar, J. Kloprogge, J.T. Jansen, J.B.H. and Geus, J.W., (1997) Hydrothermal crystallization of ammonium-saponite at 200°C and autogenous water pressure Clays and Clay Minerals 45 1–7 10.1346/CCMN.1997.0450101.CrossRefGoogle Scholar