Hostname: page-component-cd9895bd7-jkksz Total loading time: 0 Render date: 2024-12-26T17:20:57.867Z Has data issue: false hasContentIssue false
  • English
  • Français

Hydrothermal Synthesis of Mesoporous Magadiite Plates via Heterogeneous Nucleation

Published online by Cambridge University Press:  01 January 2024

Yalu Ma ,
Na Liu ,
Xiaoning Jin  and
Tianshi Feng
Yalu Ma*
Affiliation:
Department of Chemistry, Institute of Science, Tianjin University, Tianjin 300072, China
Na Liu
Affiliation:
Department of Chemistry, Institute of Science, Tianjin University, Tianjin 300072, China
Xiaoning Jin
Affiliation:
Department of Chemistry, Institute of Science, Tianjin University, Tianjin 300072, China
Tianshi Feng
Affiliation:
Department of Chemistry, Institute of Science, Tianjin University, Tianjin 300072, China
*
*E-mail address of corresponding author: [email protected]
Rights & Permissions [Opens in a new window]

Abstract

Core share and HTML view are not available for this content. However, as you have access to this content, a full PDF is available via the ‘Save PDF’ action button.

The conventional cauliflower-like shape of magadiite imposes serious limitations on its applications in adsorption, catalysis, ion exchange, etc. To overcome this problem, a method to prepare it with plate-like structures was developed. This novel approach is based on an interface-controlled heterogeneous nucleation process. Zirconia grinding balls with diameters of 2.0 mm were dispersed in the starting solution to provide solid-liquid interfaces. Then the starting solution with a SiO2:NaOH:H2O molar ratio of 9:2:75 was subjected to hydrothermal treatment at 433 K for 96 h. The presence of the solid-liquid interface improved the crystallization yield and controlled the morphology and specific surface area of the crystals. With the zirconia balls, the yield and sizes of the plate-like magadiite were 52 wt.% and 1–3 μm, respectively. In the absence of zirconia balls, the yield was smaller (45 wt.%) and magadiite shaped like cauliflower was formed. The plate-like magadiite had a specific surface area of 66 m2 g−1 and a pore-size distribution between 4 and 5 nm, compared with a surface area of 28 m2 g−1 for the cauliflower-like magadiite. In addition, the plate-like magadiite was a more effective ion exchanger than the cauliflower-like magadiite with a cation exchange capacity of 64.5 mmol/100 g (compared to 53.8 mmol/100 g for the cauliflower-like form) and it had a faster sorption rate for calcium ions.

Keywords

Ca2+ AdsorptionCauliflower-like MagadiiteHeterogeneous NucleationHydrothermal ReactionPlate-like Magadiite
Type
Research Article
Information
Clays and Clay Minerals , Volume 61 , Issue 6 , December 2013 , pp. 525 - 531
Copyright
Copyright © Clay Minerals Society 2013

References

Agnes, F. Imre, K. Niwa, S.I. Toba, M. Kiyozumi, Y. and Mizukami, F., 1999 Mesoporous materials synthesized by intercalation of silicate tubes between magadiite layers. Applied Catalysis A: General 176 L153–L158.CrossRefGoogle Scholar
Almond, G.G. Harris, R.K. and Franklin, K.R., 1997 A structural consideration of kanemite, octosilicate, magadiite and kenyaite. Journal of Materials Chemistry 7 681–687.CrossRefGoogle Scholar
Beugster, H.P., 1967 Hydrous sodium silicates from Lake Magadi, Kenya: Precursors of bedded chert. Science 157 1177–1180.CrossRefGoogle Scholar
Bi, Y. Lambert, J.F. Millot, Y. Casale, S. Blanchard, J. Zeng, S. Nie, H. and Li, D., 2011 Relevant parameters for obtaining high-surface area materials by delamination of magadiite, a layered sodium silicate. Journal of Materials Chemistry 45 18403–18411.CrossRefGoogle Scholar
Binette, M.J. and Detellier, C., 2002 Lamellar polysilicate nanocomposite materials: Intercalation of polyethylene glycols into protonated magadiite. Canadian Journal of Chemistry 80 1708–1714.CrossRefGoogle Scholar
Chen, Y. Yu, G. Li, F. and Wei, J., 2013 Structure and photoluminescence of composites based on CdS enclosed in magadiite. Clays and Clay Minerals 61 26–33.CrossRefGoogle Scholar
de Lucas, A. Rodríguez, L. Lobato, J. and Sanchez, P., 2002 Synthesis of crystalline δ-Na2Si2O5 from sodium silicate solution for use as a builder in detergents. Chemical Engineering Science 57 479–486.CrossRefGoogle Scholar
Díaz, U C Á and Corma, A., 2007 Novel layered organic-inorganic hybrid materials with bridged silsesquiox-anes as pillars. Chemistry of Materials 19 3686–3693.CrossRefGoogle Scholar
Eypert-Blaison, C. Sauzéat, E. Pelletier, M. Michot, L.J. Villiéras, F. and Humbert, B., 2001 Hydration mechanisms and swelling behavior of Namagadiite. Chemistry of Materials 13 1480–1486.CrossRefGoogle Scholar
Eypert-Blaison, C. Michot, L.J. Humbert, B. Pelletier, M. Villiéras, F. and de la d’Espinose Caillerie, J.-B., 2002 Hydration water and swelling behavior of magadiite. The H+, Na+, K+, Mg2+, and Ca2+ exchanged forms. The Journal of Physical Chemistry B 106 730–742.CrossRefGoogle Scholar
Fujita, I. Kuroda, K. and Ogawa, M., 2003 Synthesis of interlamellar silylated derivatives of magadiite and the adsorption behavior for aliphatic alcohols. Chemistry of Materials 15 3134–3141.CrossRefGoogle Scholar
Garcés, J.M. Rocke, S.C. Crowder, C.E. and Hasha, D.L., 1988 Hypothetical structures of magadiite and sodium octosilicate and structural relationships between the layered alkali metal silicates and the mordenite- and pentasil-group zeolites. Clays and Clay Minerals 36 409–418.CrossRefGoogle Scholar
Guerra, D.L. Ferrreira, J.N. Pereira, M.J. Viana, R.R. and Airoldi, C., 2010 Use of natural and modified magadiite as adsorbents to remove Th(IV), U(VI), and Eu(III) from aqueous media-thermodynamic and equilibrium study. Clays and Clay Minerals 58 327–339.CrossRefGoogle Scholar
Huang, Y. Jiang, Z. and Schwieger, W., 1999 Vibrational spectroscopic studies of layered silicates. Chemistry of Materials 11 1210–1217.CrossRefGoogle Scholar
Ide, Y. Ochi, N. and Ogawa, M., 2011 Effective and selective adsorption of Zn2+ from seawater on a layered silicate. Angewandte Chemie 50 654–656.CrossRefGoogle ScholarPubMed
Kikuta, K. Ohta, K. and Takagi, K., 2002 Synthesis of transparent magadiite-silica hybrid monoliths. Chemistry of Materials 14 3123–3127.CrossRefGoogle Scholar
Kooli, F. Mianhui, L. Alshahateet, S.F. Chen, F. and Yinghuai, Z., 2006 Characterization and thermal stability properties of intercalated Na-magadiite with cetyltrimethy-lammonium (C16TMA) surfactants. Journal of Physics and Chemistry of Solids 67 926–931.CrossRefGoogle Scholar
Kwon, O.Y. and Park, K.W., 2004 Synthesis of layered silicates from sodium silicate solution. Bulletin - Korean Chemical Society 25 25–26.Google Scholar
Lagaly, G. and Beneke, K., 1975 Magadiite and H-magadiite: I. Sodium magadiite and some of its derivatives. American Mineralogist 60 642–649.Google Scholar
Macedo, T.S.R. Petrucelli, G.C. and Airoldi, C., 2007 Silicic acid magadiite as a host for n-alkyldiamine guest molecules and features related to the thermodynamics of intercalation. Clays and Clay Minerals 55 151–159.CrossRefGoogle Scholar
Mallouk, T.E. and Gavin, J.A., 1988 Molecular recognition in lamellar solids and thin films. Accounts of Chemical Research 31 209–217.CrossRefGoogle Scholar
Nunes, A.R. Moura, A.O. and Prado, A.G., 2011 Calorimetric aspects of adsorption of pesticides 2, 4-D, diuron and atrazine on a magadiite surface. Journal of Thermal Analysis and Calorimetry 106 445–452.CrossRefGoogle Scholar
Pastore, H.O. Munsignatti, M. and Mascarenhas, A.J.S., 2000 One-step synthesis of alkyltrimethylammonium-intercalated magadiite Clays and Clay Minerals 48 224–229.CrossRefGoogle Scholar
Schwieger, W. and Lagaly, G., 2004 Alkali silicates and crystalline silicic acids Handbook of Layered Materials 541–551.CrossRefGoogle Scholar
Sprung, R. Davis, M.E. Kauffman, J.S. and Dybowski, C., 1990 Pillaring of magadiite with silicate species Industrial & Engineering Chemistry Research 29 213–220.CrossRefGoogle Scholar
Supronowicz, W. Roessner, F. Schwieger, W. Meilikhov, M. and Esken, D., 2012 Synthesis and properties of Sn-containing magadiite Clays and Clay Minerals 60 254–264.CrossRefGoogle Scholar
Szostak, R., 1998 Molecular Sieves second edition Glasgow, UK Blackie Academic & Professional.Google Scholar
Takahashi, N. and Kuroda, K., 2011 Materials design of layered silicates through covalent modification of interlayer surfaces Journal of Materials Chemistry 21 14336–14353.CrossRefGoogle Scholar
Wang, Y.R. Wang, S.F. and Chang, L.C., 2006 Hydrothermal synthesis of magadiite Applied Clay Science 33 73–77.CrossRefGoogle Scholar
Zhang, Z. Saengkerdsub, S. and Dai, S., 2003 Intersurface ion-imprinting synthesis on layered magadiite hosts Chemistry of Materials 15 2921–2925.CrossRefGoogle Scholar