Hostname: page-component-78c5997874-dh8gc Total loading time: 0 Render date: 2024-11-15T09:23:24.587Z Has data issue: false hasContentIssue false
  • English
  • Français

Gallium and Chromium Substitution for Aluminum in Synthesized Beidellite

Published online by Cambridge University Press:  28 February 2024

Kerstin B. Brandt  and
Ronald A. Kydd
Kerstin B. Brandt
Affiliation:
Department of Chemistry, University of Calgary, 2500 University Dr. N.W., Calgary, Alberta, Canada T2N 1N4
Ronald A. Kydd
Affiliation:
Department of Chemistry, University of Calgary, 2500 University Dr. N.W., Calgary, Alberta, Canada T2N 1N4
Rights & Permissions [Opens in a new window]

Abstract

Core share and HTML view are not available for this content. However, as you have access to this content, a full PDF is available via the ‘Save PDF’ action button.

The hydrothermal synthesis of Mg-beidellite in which limited amounts of Ga and Cr are clearly shown to be incorporated into nonexchangeable positions in the clay layer framework is reported for the first time. Elemental analyses indicate that, up to at least 15 mole percent, Ga can replace Al virtually completely; Cr incorporation is more difficult. It appears that the Ga that is incorporated into the beidellite is located primarily in the octahedral sheet. Pillaring of the synthesized beidellite by replacing the Mg2+ with large AlO4Al12(OH)24(H2O)127+ ions showed that approximately 5.5 meq Al3+ was required per g of beidellite to achieve complete pillaring. This amount is very similar to that required for montmorillonite, and suggests that the cation exchange capacity (CEC) of the beidellite is about 98 meq/g.

Keywords

Beidellite SynthesisChromiumGalliumIsomorphous Substitution
Type
Research Article
Information
Clays and Clay Minerals , Volume 46 , Issue 2 , April 1998 , pp. 139 - 144
Copyright
Copyright © 1998, The Clay Minerals Society

References

Bhatia, S. Beltramini, J. and Do, D.D., 1990 Deactivation of zeolite catalysts Catal Rev-Sci Eng 31 431–480 10.1080/01614948909349937.CrossRefGoogle Scholar
Bradley, S.M., 1991 Synthesis and characterization of hetero-poly and isopoly oxometal cations and their use in the formation of pillared clay mineral catalysts [Ph.D. thesis] Calgary, Alberta, Canada Univ of Calgary.Google Scholar
Bradley, S.M. Howe, R.R. and Kydd, R.A., 1993 Correlation between 27Al and 71Ga NMR chemical shifts Magn Reson Chem 31 883–886 10.1002/mrc.1260311002.CrossRefGoogle Scholar
Bradley, S.M. Kydd, R.A. and Yamdagni, R., 1990 Detection of a new polymeric species formed through the hydrolysis of gallium(III) salt solutions J Chem Soc, Dalton Trans 1990: 413–417, and Comparison of the hydrolyses of gallium(III) and aluminum(III) solutions by nuclear magnetic resonance spectroscopy 2653–2656.CrossRefGoogle Scholar
Burch, R., 1988 Catalysis Today 2 (No. 2, 3): Pillared clays Amsterdam Elsevier.Google Scholar
Choudhary, V.R. Sivadinarayana, C. Kinage, A.K. Devadas, P. and Guisnet, M., 1996 H-Gallosilicate (MFI) propane aromati-zation catalyst Applied Catal 136 125–142 10.1016/0926-860X(95)00277-4.CrossRefGoogle Scholar
Diddams, P.A., 1985 Sheet silicates: Structure and catalytic properties [Ph.D. thesis] Cambridge, UK Darwin College, Univ of Cambridge.Google Scholar
Diddams, P.A. Thomas, J.M. Jones, W. Ballantine, J.A. and Purnell, J.H., 1984 Synthesis, characterization, and catalytic activity of beidellite-montmorillonite layered silicates and their pillared analogues J Chem Soc, Chem Comm 1340–1342.CrossRefGoogle Scholar
Kloprogge, J.T. Booy, E. Jansen, J.B.H. and Geus, J.W., 1994 The effect of thermal treatment on the properties of hydroxy-Al and hydroxy-Ga pillared montmorillonite and beidellite Clay Miner 29 153–167 10.1180/claymin.1994.029.2.02.CrossRefGoogle Scholar
Kloprogge, J.T. van der Eerden, A.M.J. Jansen, J.B.H. Geus, J.W. and Schuiling, R.D., 1993 Synthesis and paragenesis of Na-bei-dellite as a function of temperature, water pressure, and sodium activity Clays Clay Miner 41 423–430 10.1346/CCMN.1993.0410403.CrossRefGoogle Scholar
Kloprogge, J.T. Jansen, J.B.H. and Geus, J.W., 1990 Characterization of synthetic Na-beidellite Clays Clay Miner 38 409–414 10.1346/CCMN.1990.0380410.CrossRefGoogle Scholar
Kloprogge, J.T. and Vogels, R., 1995 Hydrothermal synthesis of ammonium-beidellite Clays Clay Miner 43 135–137 10.1346/CCMN.1995.0430117.CrossRefGoogle Scholar
Moore, D.M. and Reynolds, R.C., 1989 X-ray diffraction and the identification and analysis of clay minerals Oxford, UK Oxford Univ Pr..Google Scholar
Plee, D. Gatineau, L. and Fripiat, J.J., 1987 Pillaring processes of smectites with and without tetrahedral substitution Clays Clay Miner 35 81–88 10.1346/CCMN.1987.0350201.CrossRefGoogle Scholar
Schutz, A. Stone, W.E.E. Poncelet, G. and Fripiat, J.J., 1987 Preparation and characterization of bidimensional zeolitic structures obtained from synthetic beidellite and hydroxy-alu-minum solutions Clays Clay Miner 35 251–261 10.1346/CCMN.1987.0350402.CrossRefGoogle Scholar
Tarte, P. and Prins, J.A., 1964 The determination of cation coordination in glasses by infrared spectroscopy Physics of Non-crystalline Solids 549–565.Google Scholar
Tennakoon, D.T.B. Thomas, J.M. Jones, W. Carpenter, T.A. and Ramdas, S., 1986 Characterization of clays and clay-organic systems J Chem Soc, Faraday Trans 1 82 545–562 10.1039/f19868200545.CrossRefGoogle Scholar
Weir, A. G.-K. R., 1962 Beidellite Am Mineral 47 137–146.Google Scholar
Yamada, H. Nakazawa, H. and Yoshioka, K., 1991 Smectites in the montmorillonite-beidellite series Clay Miner 26 359–369 10.1180/claymin.1991.026.3.05.CrossRefGoogle Scholar
Yamada, H. Yoshioka, K. and Nakazawa, H., 1991 Hydrothermal synthesis of beidellite from aluminosilicate glass by varying water/solid ratio Mineral J 15 300–308 10.2465/minerj.15.300.CrossRefGoogle Scholar
Yanagisawa, K. Kusunose, T. Ioku, K. Yamasaki, N. Malla, P.B. and Komarneni, S., 1995 Hydrothermal crystallization mechanism of sodium beidellite from amorphous gel J Mat Sci Lett 14 1770–1772 10.1007/BF00271003.CrossRefGoogle Scholar