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Electric Charge and Surface Characteristics of Hydroxyaluminosilicate- and Hydroxyaluminum-Vermiculite Complexes

Published online by Cambridge University Press:  28 February 2024

Katsuhiro Inoue  and
Chiaki Satoh
Katsuhiro Inoue
Affiliation:
Faculty of Agriculture, Iwate University, 3-18-8 Ueda, Morioka 020, Japan
Chiaki Satoh
Affiliation:
Faculty of Agriculture, Iwate University, 3-18-8 Ueda, Morioka 020, Japan
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Abstract

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Hydroxyaluminosilicate (HAS) ions prepared from hydroxy-Al (HyA) ions and orthosilicic acid at different NaOH/Al molar and Si/Al atomic ratios were fixed in the interlayer spaces of vermiculite (Vt). The electric charge and surface characteristics of HAS-Vt and HyA-Vt complexes formed were investigated in the pH range of 4 to 8. At pH 4 to 6, the magnitude of negative charge (CEC) of HAS-Vt and HyA-Vt complexes was drastically reduced by a HAS- or HyA-interlayer formation of Vt. At pH 7 to 8, especially in NaOH/Al molar ratio of 2.5, the magnitude of negative charge was from 62 to 89% of CEC in untreated Vt, suggesting that part of HAS or HyA ions fixed on Vt was excluded from its interlayer spaces. The positive charge did not develop on HAS-Vt and HyA-Vt complexes at pH between 4 and 8. The fixation of HAS or HyA ions on Vt caused the significant reduction of its total and internal surface areas as well as the slight increase of its external surface area. The HAS- or HyA-fixation in the interlayer spaces of Vt was confirmed by X-ray diffraction analysis. Our results provided evidence of a possibility that Vt could fix HAS ions in the same way as HyA ions, transforming to chloritized-Vt. These interlayer materials could play a significant role in modifying the surface and mineralogical properties and cation exchange capacity of clays and soils.

Keywords

Electric charge characteristicsFixationHydroxy-AlHydroxyaluminosilicateSpecific surface areaVermiculite
Type
Research Article
Information
Clays and Clay Minerals , Volume 40 , Issue 3 , June 1992 , pp. 311 - 318
Copyright
Copyright © 1992, The Clay Minerals Society

References

Barnhisel, R. I., Dixon, J. B. and Weed, S. B., Chlorites and hydroxy interlayered vermiculiteand smectite Minerals in Soil Environments 1977 Madison, Wisconsin Soil Science Society of America 331 – 356.Google Scholar
Bamhisel, R. I., Bertsch, P. M., Dixon, J. B. and Weed, S. B., Chlorites and hydroxy interlayered vermiculite and smectite Minerals in Soil Environments 1989 2nd ed. Madison, Wisconsin Soil Science Society of America 729 – 788.Google Scholar
Dixon, J. B. and Jackson, M. L., Properties of intergradient chlorite-expansible layer silicates of soils Soil Sci. Soc. Am. Proc. 1962 26 358 – 362 10.2136/sssaj1962.03615995002600040016x.Google Scholar
Egashira, K., Physical properties of clays Handbook of Clays (Nendo Handbook 1987 2nd ed. Tokyo Gihodo 131 – 150.Google Scholar
Eltantawy, I. M. and Arnold, P. W., Reappraisal of ethylene glycol mono-ethyl ether (EGME) method for surface area estimations of clays J. Soil Sci. 1973 24 232 – 238 10.1111/j.1365-2389.1973.tb00759.x.Google Scholar
Farmer, V. C., Possible roles of a mobile hydroxyaluminium orthosilicate complex (proto-imogolite) and other hydroxyaluminium and hydroxy-iron species in podzolization Migrations Organominérales dans les Sols Tempérés 1981 275 – 279.Google Scholar
Farmer, V. C., Fraser, A. R. and Tait, J. M., Characterization of the chemical structures of natural and synthetic aluminosilicates gels and sols by infrared spectroscopy Geochim. Cosmochim. Acta 1979 43 1417 – 1420 10.1016/0016-7037(79)90135-2.Google Scholar
Farmer, V. C., Russell, J. D. and Berrow, M. L., Imogolite and proto-imogolite allophane in spodic horizons: Evidence for a mobile aluminium silicate complex in podzol formation J. Soil Sci. 1980 31 673 – 684 10.1111/j.1365-2389.1980.tb02113.x.Google Scholar
Frink, C. R., Characterization of aluminum interlayers in soil clays Soil Sci. Soc. Am. Proc. 1965 29 379 – 382 10.2136/sssaj1965.03615995002900040011x.Google Scholar
Hsu, P. H., Dixon, J. B. and Weed, S. B., Aluminum hydroxides and oxyhydroxides Minerals in Soil Environments 1977 Madison, Wisconsin Soil Science Society of America 99 – 143.Google Scholar
Hsu, P. H. and Bates, T. F., Fixation of hydroxyaluminum polymers by vermiculite Soil Sci. Soc. Am. Proc. 1964 28 763 – 769 10.2136/sssaj1964.03615995002800060025x.Google Scholar
Inoue, K., Active aluminum and iron components in Andisols and related soils Transactions of 14th Int. Cong. Soil Sci. Kyoto, 1990 1990 VII 153 – 158.Google Scholar
Inoue, K., Higashi, T., Kinloch, D. I., Shoji, S., Beinroth, F. H. and Eswaran, H., Al- and Fe-humus complexes in Andisols Proceedings of International Soil Classification Workshop, Japan, 1987 1988 Washington D.C. Japanese Committee for the 9th International Soil Classification Workshop, for the Soil Management Support Services 81 – 96.Google Scholar
Inoue, K. and Huang, P. M., Influence of citric acid on the natural formation of imogolite Nature 1984 308 58 – 60 10.1038/308058a0.Google Scholar
Inoue, K. and Huang, P. M., Influence of citric acid on the formation of short-range ordered aluminosilicates Clays & Clay Minerals 1985 33 312 – 322 10.1346/CCMN.1985.0330406.Google Scholar
Inoue, K. and Mizota, C., Eolian origin of 2:1 layer silicates and fine quartz in Andosols and Red-Yellow soils developed on limestones and basalts J. Clay Sci. Soc. Jpn. 1988 28 1 30 – 47.Google Scholar
Inoue, K., Naruse, T., Okuda, S., Rapp, A. and Zhang, L., Accumulation of Asian long-range eolian dust in Japan and Korea from the late Pleistocene to the Holocene LOESS Geomorphological Hazards and Processes 1991 Germany Catena Verlag, Cremlingen 25 – 42.Google Scholar
Inoue, K., Pavan, M. A. and Yoshida, M., Fixation of hydroxy aluminosilicate ions (proto-imogolite) on smectite Soil Sci. Plant Nutr. 1988 34 277 – 285 10.1080/00380768.1988.10415682.Google Scholar
Inoue, K., Zhao, L. P. and Huang, P. M., Adsorption of humic substances by hydroxyaluminum- and hydroxyaluminosilicate-montmorillonite complexes Soil Sci. Soc. Amer. J. 1990 54 1166 – 1172 10.2136/sssaj1990.03615995005400040042x.Google Scholar
Jackson, M. L., Soil Chemical Analysis—Advanced Course 1979 2nd ed. Madison, Wisconsin M. L. Jackson.Google Scholar
Lou, G. and Huang, P. M., Hydroxy-aluminosilicate interlayers in montmorillonite: Implications for acidic environments Nature 1988 335 625 – 627 10.1038/335625a0.Google Scholar
Matsue, N. and Wada, K., Interlayer materials of partially interlayered vermiculite in Dystrochrepts derived from Tertiary sediments J. Soil Sci. 1988 39 155 – 162 10.1111/j.1365-2389.1988.tb01202.x.Google Scholar
McKeague, J. A., Ross, G. J., Gamble, D. S. and Mahancy, W. C., Properties, criteria of classification and concepts of genesis of podzolic soils in Canada Quaternary Soils: 3rd Conference on Quaternary Research 1976 Norwich, England Geo Abstracts Ltd. 27 – 60.Google Scholar
Mehra, O. P. and Jackson, M. L., Iron oxide removal from soils and clays by a dithionite-citrate system buffered with sodium bicarbonate Clays and Clay Minerals, Proc. 7th Conf 1960 London Pergamon Press 317 – 327.Google Scholar
Rich, C. I., Aluminum in interlayers of vermiculite Soil Sci. Soc. Am. Proc. 1960 24 26 – 32 10.2136/sssaj1960.03615995002400010016x.Google Scholar
Rich, C. I., Hydroxy interlayers in expansible layer silicates Clays & Clay Minerals 1968 16 15 – 30 10.1346/CCMN.1968.0160104.Google Scholar
Ross, G. J. and Theng, B. K. G., The mineralogy of spodosols Soils with Variable Charge 1980 Lower Hutt, New Zealand New Zealand Society of Soil Science 127 – 143.Google Scholar
Shoji, S., Ito, T., Saigusa, M. and Yamada, I., Properties of nonallophanic Andosols from Japan Soil Sci. 1985 140 264 – 277 10.1097/00010694-198510000-00005.Google Scholar
Shoji, S. and Ono, T., Physical and chemical properties and clay mineralogy of Andosols from Kitakami, Japan Soil Sci. 1978 126 297 – 312 10.1097/00010694-197811000-00007.Google Scholar
Shoji, S., Suzuki, Y. and Saigusa, M., Clay mineralogical and chemical properties of montmorillonitic Andepts (Andisols) from Oregon, USA Soil Sci. Soc. Amer. J. 1987 51 986 – 990 10.2136/sssaj1987.03615995005100040030x.Google Scholar
Tamura, T., Identification of clay minerals from acid soils J. Soil Sci. 1958 9 141 – 147 10.1111/j.1365-2389.1958.tb01906.x.Google Scholar
Wada, K. and Kakuto, Y., Intergradient vermiculitekaolinite mineral in Korean Ultisol Clays & Clay Minerals 1983 31 183 – 190 10.1346/CCMN.1983.0310303.Google Scholar
Wada, K., Kakuto, Y. and Fukuhara, K., Chloritized vermiculite and smectite in some Inceptisols and Spodosols Soil Sci. Plant Nutr. 1987 33 317 – 326 10.1080/00380768.1987.10557578.Google Scholar
Wada, K. and Okamura, Y., Electric charge characteristics of Ando Al and buried Al horizon soils J. Soil Sci. 1980 31 307 – 314 10.1111/j.1365-2389.1980.tb02083.x.Google Scholar
Wada, S. and Wada, K., Formation, composition and structure of hydroxyaluminosilicate ions J. Soil Sci. 1980 31 457 – 467 10.1111/j.1365-2389.1980.tb02095.x.Google Scholar