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The Effects of Salinity and Shear History on The Rheological Characteristics of Illite-Rich and Na-Montmorillonite-Rich Clays

Published online by Cambridge University Press:  01 January 2024

Sueng Won Jeong ,
Jacques Locat  and
Serge Leroueil
Sueng Won Jeong*
Affiliation:
Geologic Environment Division, Korea Institute of Geoscience and Mineral Resources, 124 Gwahang-no, Yuseong-gu, Daejeon, 305-350, Korea
Jacques Locat
Affiliation:
Department of Geology and Engineering Geology, Laval University, Sainte-Foy, Adrien-Pouliot, local 4317, QC G1K 7P4, Canada
Serge Leroueil
Affiliation:
Department of Civil Engineering, Laval University, Sainte-Foy, Adrien-Pouliot, local 2906, QC G1K 7P4, Canada
*
*E-mail address of corresponding author: [email protected]
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Abstract

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Particle–particle interactions in natural clays can be evaluated by their rheological behavior, but the results are often affected by the physicochemical properties of the clays. The behaviors of two fundamentally different types of clays (low-activity and high-activity) differ with respect to salinity and a time factor (duration of shearing at a given shear rate): illite-rich Jonquiere clay (low-activity clay, Canada) and montmorillonite-rich Wyoming bentonite (high-activity clay, USA). The purpose of the present study was to investigate these different behaviors. Most natural clays exhibit shear-thinning and thixotropic behavior with respect to salinity and the volumetric concentration of the solids. Natural clays also exhibit time-dependent non-Newtonian behavior. In terms of index value and shear strength, lowactivity and high-activity clays are known to exhibit contrasting responses to salinity. The geotechnical and rheological characteristics as a function of salinity and the shearing time for the given materials are compared here. The clay minerals were compared to estimate the inherent shear strengths, such as remolded shear strength (which is similar to the yield strength). Low-activity clay exhibits thixotropic behavior in a time-dependent manner. High-activity clay is also thixotropic for a short period of shearing, although rare cases of rheopectic behavior have been measured for long periods of shearing at high shear rates. The change from thixotropic to rheopectic behavior by bentonite clay has little effect at low shearing speeds, but appears to have a significant effect at higher speeds.

Keywords

Low-activity ClayHigh-activity ClaySalinityRheopecticThixotropicYield Strength
Type
Article
Information
Clays and Clay Minerals , Volume 60 , Issue 2 , April 2012 , pp. 108 - 120
Copyright
Copyright © Clay Minerals Society 2012

References

Alther, G.R., 1987 The qualifications of bentonites as a soil sealant Engineering Geology 23 177–191.CrossRefGoogle Scholar
ASTM D 422, 1997 Standard test method for particle-size analysis of soils Annual book of ASTM standards 10–16.Google Scholar
ASTM D 5890, 2002 Standard test method for swell index of clay mineral component of geosynthetic clay liners Annual book of ASTM standards 232–234.Google Scholar
Bekkour, K. Leyama, M. Benchabane, A. and Scrivener, O., 2005 Time-dependent rheological behavior of bentonite suspensions: An experimental study Journal of Rheology 49 1329–1345.CrossRefGoogle Scholar
Besq, A. Malfoy, C. Pantet, A. Monnet, P. and Righi, D., 2003 Physicochemical characterisation and flow properties of some bentonite muds Applied Clay Science 23 275–286.CrossRefGoogle Scholar
Bonn, D. and Denn, M.M., 2009 Yield stress fluids slowly yield to analysis Science 324 1401–1402.CrossRefGoogle ScholarPubMed
Churchman, G.J. Askary, M. Peter, P. Wright, M. Raven, M.D. and Self, P.G., 2002 Geotechnical properties indicating environmental uses for an unusual Australian bentonite Applied Clay Science 20 199–209.CrossRefGoogle Scholar
Coussot, P. and Piau, J.-M., 1994 On the behavior of fine mud suspensions Rheologica Acta 33 175–184.CrossRefGoogle Scholar
Coussot, P. Nguyen, G.D. Huynh, H.T. and Bonn, D., 2002 Viscosity bifurcation in thixotropic, yielding fluids Journal of Rheology 46 573–589.CrossRefGoogle Scholar
Dixon, D.A. Graham, J. and Gray, M.N., 1999 Hydraulic conductivity of clays in confined tests under low hydraulic gradients Canadian Geotechnical Journal 36 815–825.CrossRefGoogle Scholar
Hansbo, S., 1957 A new approach to the determination of the shear strength of clay by the fall-cone test Stockholm Royal Swedish Geotechnical Institute Proc. No. 14.Google Scholar
Heath, D. and Tadros, T.h.F., 1983 Influence of pH, electrolyte, and poly(vinyl alcohol) addition on the rheological characteristics of aqueous dispersions of sodium montmorillonite Journal of Colloid and Interface Science 93 307–319.CrossRefGoogle Scholar
Heller, H. and Keren, R., 2001 Rheology of Na-rich montmorillonite suspension as affected by electrolyte concentration and shear rate Clays and Clay Minerals 49 286–291.CrossRefGoogle Scholar
Jeong, S.W., 2006 Influence of physico-chemical characteristics of fine-grained sediments on their rheological behavior PhD thesis Québec, Canada Laval University.Google Scholar
Jeong, S.W. Leroueil, S. and Locat, J., 2009 Applicability of power law for describing the rheology of soils of different origins and characteristics Canadian Geotechnical Journal 46 1011–1023.CrossRefGoogle Scholar
Jeong, S.W. Locat, J. Leroueil, S. and Malet, J.-P., 2010 Rheological properties of fine-grained sediments: the roles of texture and mineralogy Canadian Geotechnical Journal 47 1085–1100.CrossRefGoogle Scholar
Kelessidis, V.C. Maglione, R. Tsamantaki, C. and Aspirtakis, Y., 2006 Optimal determination of rheological parameters for Herschel-Bulkley drilling fluids and impact on pressure drop, velocity profiles and penetration rates during drilling Journal of Petroleum Science and Engineering 53 203–224.CrossRefGoogle Scholar
Kelessidis, V.C. Tsamantaki, C. and Dalamarinis, P., 2007 Effect of pH and electrolyte on the rheology of aqueous Wyoming bentonite dispersions Applied Clay Science 38 86–96.CrossRefGoogle Scholar
Khaldoun, A. Eiser, E. Wegdam, G.H. and Bonn, D., 2005 Liquefaction of quicksand under shear Nature 437 635.CrossRefGoogle Scholar
Khaldoun, A. Møller, P. Fall, A. Wegdam, G. De Leeuw, B. Meheust, Y. Fossum, J.O. and Bonn, D., 2009 Quick clay and landslides of clayey soils Physical Reviews Letters 103 188301.CrossRefGoogle ScholarPubMed
Lagaly, G., 1989 Principles of flow of kaolin and bentonite dispersions Applied Clay Science 4 105–123.CrossRefGoogle Scholar
Laribi, S. Fleureau, J.M. Grossiord, J.L. and Kbir-Ariguib, N., 2006 Effect of pH on the rheological behavior of pure and interstratified smectite clays Clays and Clay Minerals 54 29–37.CrossRefGoogle Scholar
Legrand, C. and Da Costa, F., 1990 The effect of shearing on the rheological behaviour of thixotropic bentonite muds Materials and Structures 23 126–130.CrossRefGoogle Scholar
Leroueil, S. Tavenas, F. and LeBihan, J.P., 1983 Propriétés caracté ristiques des argiles de l’est du Canada Canadian Geotechnical Journal 20 681–705.CrossRefGoogle Scholar
Liang, H.N. Long, Z. Zhang, H. and Yang, S.H., 2010 Rheological properties of acid-activated bentonite dispersions Clays and Clay Minerals 58 311–317.CrossRefGoogle Scholar
Locat, J., 1982 Origine de la surconsolidation des argiles sensibles de l’Est du Canada PhD thesis, Department of Civil Engineering Québec, Canada University of Sherbrooke, Sherbrooke.Google Scholar
Locat, J., 1997 Normalized rheological behaviour of fine muds and their flow properties in a pseudoplastic regime Proceedings of the 1st International conference on Debris-Flow Hazards Mitigation 260–269.Google Scholar
Locat, J. and Demers, D., 1988 Viscosity, yield stress, remoulded strength, and liquidity index relationships for sensitive clays Canadian Geotechnical Journal 25 799–806.CrossRefGoogle Scholar
Luckham, P.F. and Rossi, S., 1999 The colloidal and rheological properties of bentonite suspensions Advances in Colloid and Interface Sciences 82 43–92.CrossRefGoogle Scholar
Malfoy, C. Pantet, A. Monnet, P. and Righi, D., 2003 Effects of the nature of the exchangeable cation and clay concentration on the rheological properties of smectite suspensions Clays and Clay Minerals 51 656–663.CrossRefGoogle Scholar
Marr, J.G. Shanmugam, G. and Parker, G., 2001 Experiments on subaqueous sandy gravity flows: The role of clay and water content in flow dynamics and depositional structures Geological Society of America Bulletin 113 1377–1386.2.0.CO;2>CrossRefGoogle Scholar
Mewis, J. and Wagner, N.J., 2009 Thxiotropy Advances in Colloid and Interface Science 147–148 214–227.CrossRefGoogle Scholar
Mitchell, J.K., 1993 Fundamentals of Soil Behavior second edition.Google Scholar
Møller, P.C.F. Mewis, J. and Bonn, D., 2006 Yield stress and thixotropy: on the difficulty of measuring yield stresses in practice Soft Matter 2 274–283.CrossRefGoogle ScholarPubMed
Møller, P.C.F. Rodts, S. Michels, M.A.J. and Bonn, D., 2008 Shear banding and yield stress in soft glassy materials Physical Review E 77 041507.CrossRefGoogle ScholarPubMed
O’Brien, J.S. and Julien, P.Y., 1988 Laboratory analysis of mud flow properties Journal of Hydraulic Engineering 114 877–887.CrossRefGoogle Scholar
Penner, D. and Lagaly, G., 2000 Influence of organic and inorganic salts on the coagulation of montmorillonite dispersions Clays and Clay Minerals 48 246–255.CrossRefGoogle Scholar
Perret, D. Locat, J. and Martignoni, P., 1996 Thixotropic behavior during shear of a fine-grained mud from Eastern Canada Engineering Geology 43 31–44.CrossRefGoogle Scholar
Petrov, R.J. and Rowe, R.K., 1997 Geosynthetic clay liner (GCL) — chemical compatibility by hydraulic conductivity testing and factors impacting its performance Canadian Geotechnical Journal 34 863–885.CrossRefGoogle Scholar
Santamarina, J.C. Klein, K.A. Wang, Y.H. and Prencke, E., 2002 Specific surface: determination and relevance Canadian Geotechnical Journal 39 233–241.CrossRefGoogle Scholar
Schatzmann, M. Fischer, P. and Bezzola, G.R., 2003 Rheological behavior of fine and large particle suspensions Journal of Hydraulic Engineering 129 796–803.CrossRefGoogle Scholar
Schmitz, R.M. and van Paassen, L.A., 2003 The decay of the liquid limit of clays with increasing salt concentration Ingeokring Newsletter (published by the Dutch Association of Engineering Geology) 9 10–14.Google Scholar
Terzaghi, K. Peck, R.B. and Mesri, G., 1996 Soil Mechanics in Engineering Practice third edition New York John Wiley & Sons, Inc..Google Scholar
Torrance, J.K., 1974 A laboratory investigation of the effect of leaching on the compressibility and shear strength of Norwegian marine clays Géotechnique 24 155–173.CrossRefGoogle Scholar
Vali, H. and Bachmann, L., 1988 Ultrastructure and flow behavior of colloidal smectite dispersions Journal of Colloid and Interface Science 126 278–291.CrossRefGoogle Scholar
van Olphen, H., 1963 An Introduction to Clay Colloid Chemistry New York John Wiley & Sons Inc..Google Scholar
van Olphen, H., 1964 Internal mutual flocculation in clay suspension Journal of Colloid Science 19 313–322.CrossRefGoogle Scholar