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Effect of Temperature on Halloysite Acid Treatment for Efficient Chloroaniline Removal from Aqueous Solutions

Published online by Cambridge University Press:  01 January 2024

Beata Szczepanik ,
Piotr Słomkiewicz ,
Magdalena Garnuszek ,
Paweł Rogala ,
Dariusz Banaś ,
Aldona Kubala-Kukuś  and
Ilona Stabrawa
Beata Szczepanik*
Affiliation:
Institute of Chemistry, Jan Kochanowski University, Świętokrzyska 15G, 25-406, Kielce, Poland The Structural Research Laboratory, Jan Kochanowski University, Świętokrzyska 15G, 25-406, Kielce, Poland
Piotr Słomkiewicz
Affiliation:
Institute of Chemistry, Jan Kochanowski University, Świętokrzyska 15G, 25-406, Kielce, Poland The Structural Research Laboratory, Jan Kochanowski University, Świętokrzyska 15G, 25-406, Kielce, Poland
Magdalena Garnuszek
Affiliation:
Institute of Chemistry, Jan Kochanowski University, Świętokrzyska 15G, 25-406, Kielce, Poland
Paweł Rogala
Affiliation:
Institute of Chemistry, Jan Kochanowski University, Świętokrzyska 15G, 25-406, Kielce, Poland
Dariusz Banaś
Affiliation:
Institute of Physics, Jan Kochanowski University, Świętokrzyska 15G, 25-406, Kielce, Poland Holycross Cancer Center, Artwińskiego 3, 25-734, Kielce, Poland
Aldona Kubala-Kukuś
Affiliation:
Institute of Physics, Jan Kochanowski University, Świętokrzyska 15G, 25-406, Kielce, Poland Holycross Cancer Center, Artwińskiego 3, 25-734, Kielce, Poland
Ilona Stabrawa
Affiliation:
Institute of Physics, Jan Kochanowski University, Świętokrzyska 15G, 25-406, Kielce, Poland
*
*E-mail address of corresponding author: [email protected]
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Abstract

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Monochloroanilines and dichloroanilines are important reagents or chemical intermediates in the production of dyes, pharmaceuticals, and agricultural chemicals. These toxic compounds have a large tendency to accumulate in the environment and a low natural biodegradability, so improved methods to remove or sequester them are needed. Halloysite is used as an efficient adsorbent to remove toxic compounds, such as aniline, from aqueous solutions. The purpose of this study was to evaluate whether acid-activated halloysites from the “Dunino” (Poland) strip mine could be effective in the removal of not just aniline but also of its chloro-substituted forms from aqueous solutions. The composition, structure, and morphology of activated halloysites were characterized using the following methods: wavelength dispersive X-ray fluorescence analysis (WDXRF), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), energy dispersive X-ray spectroscopy (EDX), Fourier-transform infrared spectroscopy (FTIR), and N2 adsorption-desorption analysis. The acidactivated halloysites had an increased ability to remove aniline and chloroanilines from aqueous solutions as the acid activation temperature was increased. This suggests that the acid activation temperature is an important factor that influences the ability of acid activated halloysites to adsorb aromatic amines (anilines) from water. The efficiency of aniline and chloroaniline removal by halloysite activated at 80°C reached maximum levels, especially for the removal of aniline and 4-chloroaniline. The adsorption isotherm data were best described by the Langmuir adsorption model. The values of the Langmuir adsorption constants were calculated using the inverse liquid chromatography method.

Keywords

Acid ActivationAdsorptionChloroanilinesHalloysite
Type
Article
Information
Clays and Clay Minerals , Volume 65 , Issue 3 , June 2017 , pp. 155 - 167
Copyright
Copyright © Clay Minerals Society 2017

References

Andini, S. Cioffi, R. Colangelo, F. Montagnaro, F., and Santoro, L., 2008 Adsorption of chlorophenol, chloroaniline and methylene blue on fuel oil fly ash Journal of Hazardous Materials 157 599–604.CrossRefGoogle ScholarPubMed
Angioi, S. Polati, S. Roa, M. Rinaudo, C. Gianotti, V., and Gennaro, M.C., 2005 Sorption studies of chloroanilines on kaolinite and montmorillonite Environmental Pollution 134 35–43.CrossRefGoogle ScholarPubMed
Balbuena, P.B., and Gubbins, K.E., 1993 Theoretical interpretation of adsorption behavior of simple fluids in slit pores Langmuir 9 1801–1814.CrossRefGoogle Scholar
Banaś, D. Kubala-Kukuś, A. Braziewicz, J. Majewsk,a, U. Pajek, M. Wudarczyk-Moćko, J. Czech, K. Garnuszek, M. Słomkiewicz, P. J., and Szczepanik, B., 2013 Study of properties of chemically modified samples of halloysite mineral with X-ray fluorescence and X-ray powder diffraction methods Radiation Physics Chemistry 93 129–134.CrossRefGoogle Scholar
Belkassa, K. Bessaha, F. Marouf-Khelifa, K. Batonneau-Generb, I. Comparot, J., and Khelifa, A., 2013 Physicochemical and adsorptive properties of a heat-treated and acid-leached Algerian halloysite Colloids and Surfaces A: Physicochemical and Engineering Aspects 421 26–33.CrossRefGoogle Scholar
Belver, C. Munoz, M.A.B., and Vicente, M.A., 2002 Chemical activation of a kaolinite under acid and alkaline conditions Chemistry of Materials 14 2033–2043.CrossRefGoogle Scholar
Brigatti, M.F. Galan, E. Theng, B.K.G. Lagaly, G., Bergaya, F. Theng, B.K.G., and Lagaly, G., 2006 Structures and mineralogy of clay minerals Handbook of Clay Science, Volume 1 Amsterdam. Developments in Clay Science, Elsevier.Google Scholar
Brunauer, S. Emmett, P.H., and Teller, E., 1938 Adsorption of gases in multimolecular layers Journal of the American Chemical Society 60 309–39.CrossRefGoogle Scholar
Chang, Y. Ren, C.-L. Qu, J-Ch and Chen, X.-G., 2012 Preparation and characterization of Fe3O4/graphene nanocomposite and investigation of its adsorption performance for aniline and p-chloroaniline Applied Surface Science 261 504–509.CrossRefGoogle Scholar
Cheng, H. Frost, R.L. Yang, J. Liu, Q., and He, J., 2010 Infrared and infrared emission spectroscopic study of typical Chinese kaolinite and halloysite Spectrochimica Acta Part A 77 1014–1020.CrossRefGoogle ScholarPubMed
Cheng, H. Liu, Q. Yang, J. Zhang, J. Frost, R.L., and Du, X., 2011 Infrared spectroscopic study of halloysite-potassium acetate intercalation complex Journal of Molecular Structure 990 21–25.CrossRefGoogle Scholar
Dong, Y. Liu, Z., and Chen, L., 2012 Removal of Zn(II) from aqueous solution by natural halloysite nanotubes Journal of Radioanalytical and Nuclear Chemistry 292 435–443.CrossRefGoogle Scholar
Ece, O., and Schroeder, P., 2007 Hydrothermal alteration of oligocene volcanic rocks and genesis of halloysite-alunitekaolinite deposits in the Turpla area, Balikesir, Turkey Clays and Clay Minerals 55 18–36.CrossRefGoogle Scholar
Frini-Srasra, N., and Srasra, E., 2008 Effect of heating on palygorskite and acid-treated palygorskite properties Surface Engineering and Applied Electrochemistry 44 43–49.CrossRefGoogle Scholar
Gosetti, F. Bottaro, M. Gianotti, V. Mazzucco, E. Frascarolo, P. Zampieri, D. Oliveri, C. Viarenga, A., and Gennaro, M.C., 2010 Sun light degradation of 4-chloroaniline in waters and its effect on toxicity A high performance liquid chromatography Diode array Tandem mass spectrometry study. Environmental Pollution 158 592–598.Google ScholarPubMed
Joussein, E. Petit, S. Churchman, G.J. Theng, B.K.G. Righi, D., and Delvaux, B., 2005 Halloysite clay minerals-A review Clays and Clay Minerals 40 383–426.CrossRefGoogle Scholar
Laszlo, K., 2005 Adsorption from aqueous phenol and aniline solutions on activated carbons with different surface chemistry Colloids and Surfaces A 265 32–39.CrossRefGoogle Scholar
Lenarda, M. Storaro, L. Talon, A. Moretti, E., and Riello, P., 2007 Solid acid catalysts from clays: preparation of mesoporous catalysts by chemical activation of metakaolin under acid conditions Journal of Colloid and Interface Science 31 537–543.CrossRefGoogle Scholar
Liu, R.C. Zhang, B. Mei, D.D. Zhang, H.Q., and Liu, J.D., 2011 Adsorption of methyl violet from aqueous solution by halloysite nanotubes Desalination 268 111–116.CrossRefGoogle Scholar
Loos, R. Hanke, G., and Eisereich, S.J., 2003 Multicomponent analysis of polar water pollutants using sequential solid-phase extraction followed by LC-ESI-MS Journal of Environmental Monitoring 5 384–394.CrossRefGoogle ScholarPubMed
Luo, P. Zhang, B. Zhao, Y. Wang, J. Zhang, H., and Liu, J., 2011 Removal of methylene blue from aqueous solutions by adsorption onto chemically activated halloysite nanotubes Korean Journal of Chemical Engineering 28 800–807.CrossRefGoogle Scholar
Madejová, J., and Komadel, P., 2001 Baseline studies of the clay minerals society source clays: infrared methods Clays and Clay Minerals 49 410–432.CrossRefGoogle Scholar
Matusik, J., 2016 Hallysite for adsorption and pollution remediation Chapter 23 in: Developments in Clay Science 7 606–627.Google Scholar
Paderewski, M., 1999 Adsorption Processes in the Chemical Engineering Warsaw, Poland WNT.Google Scholar
Panda, A.K. Mishra, B.G. Mishra, D.K., and Singh, R.K., 2010 Effects of sulfuric acid treatment on the physicochemical characteristics of kaolin clay Colloids and Surfaces A: Physicochemical and Engineering Aspects 363 98–104.CrossRefGoogle Scholar
Pasbakhsh, P. Churchman, G.J. Jock, G., and Keeling, J.L., 2013 Characterisation of properties of various halloysites relevant to their use as nanotubes and microfibre fillers Applied Clay Science 74 47–57.CrossRefGoogle Scholar
Pentrak, M. Madejová, J., and Komadel, P., 2009 Acid and alkali treatment of kaolins Clay Minerals 44 511–523.CrossRefGoogle Scholar
Sarbak, Z., 2000 Adsorption and Adsorbents. Theory and Application Poznań, Poland WN.Google Scholar
Słomkiewicz, P. Szczepanik, B., and Garnuszek, M., 2015 Determination of adsorption isotherms of aniline and 4- chloroaniline on halloysite adsorbent by inverse liquid chromatography Applied Clay Science 114 221–228.CrossRefGoogle Scholar
Szczepanik, B. Słomkiewicz, P. Garnuszek, M. and Czech, K., 2014a Adsorption of chloroanilines from aqueous solutions on the modified halloysite Applied Clay Science 101 260–264.CrossRefGoogle Scholar
Szczepanik, B. Słomkiewicz, P. Garnuszek, M. and Czech, K., 2014b Adsorption studies of chlorpropham and 3- chloroaniline on chemically activated halloysite Journal of Chemistry and Chemical Engineering 8 626–634.Google Scholar
Szczepanik, B. Słomkiewicz, P. Garnuszek, M. Czech, K. Banaś, D. Kubala-Kukuś, A., and Stabrawa, I., 2015 The effect of chemical modification on the physico-chemical characteristics of halloysite: FTIR, XRF, and XRD studies Journal of Molecular Structure 1084 16–22.CrossRefGoogle Scholar
Thanh, L.N. Setinek, K., and Beranek, L., 1972 Kinetics and adsorption on acid catalysts IV. Kinetics of gas phase dehydration of methanol on sulfonated ion exchanger. Collection of Czechoslovak Chemical Communications 37 3878–3884.Google Scholar
Wang, Q. Zhang, J., and Wang, A., 2013 Alkali activation of halloysite for adsorption and release of ofloxacin Applied Surface Science 287 54–61.CrossRefGoogle Scholar
Wang, Q. Zhang, J. Mu, B. Fan, L. and Wang, A., 2014a Facile preparation of magnetic 2-hydroxypropyltrimethyl ammonium chloride chitosan/Fe3O4/halloysite nanotubes microspheres for the controlled release of ofloxacin Carbohydrate Polymers 102 877–883.CrossRefGoogle ScholarPubMed
Wang, Q. Zhang, J. Zheng, Y. and Wang, A., 2014b Adsorption and release of ofloxacin from acid- and heattreated halloysite Colloids and Surfaces B: Biointerfaces 113 51–58.CrossRefGoogle ScholarPubMed
White, R.D. Bavykin, D.V., and Walsh, F.C., 2012 The stability of halloysite nanotubes in acidic and alkaline aqueous suspensions Nanotechnology 23 065705.CrossRefGoogle ScholarPubMed
Yuan, P. Tan, D., and Annabi-Bergaya, F., 2015 Properties and applications of halloysite nanotubes: recent research advances and future prospects Applied Clay Science 112–113 75–93.CrossRefGoogle Scholar
Zampori, L. Gallo, Stampino, P. Dotelli, G. Botta, D. Natali Sora, I., and Setti, M., 2008 Interlayer expansion of dimethyl ditallowylammonium montmorillonite as a function of 2-chloroaniline adsorption Applied Clay Science 41 149–157.CrossRefGoogle Scholar
Zhang, A.B. Pan, L. Zhang, H.Y. Liu, S.T. Ye, Y. Xia, M.S., and Chen, X.G., 2012 Effects of acid treatment on the physico-chemical and pore characteristics of halloysite Colloids and Surfaces A: Physicochemical and Engineering Aspects 396 182–188.CrossRefGoogle Scholar
Zhao, M.F., and Liu, P., 2008 Adsorption behavior of methylene blue on halloysite nanotubes Microporous and Mesoporous Materials 112 419–424.CrossRefGoogle Scholar
Zhao, Y. Abdullayev, E. Vasiliev, A., and Lvov, Y., 2013 Halloysite nanotube clay for efficient water purification Journal of Colloid and Interface Science 406 121–129.CrossRefGoogle ScholarPubMed
Zheng, K. Pan, B. Zhang, Q. Han, Y. Zhang, W. Pan, B. Xu, Z. Zhang, Q. Du, W., and Zhang, Q., 2007 Enhanced removal of p-chloroaniline from aqueous solution by a carboxylated polymeric sorbent Journal of Hazardous Materials 143 462–468.CrossRefGoogle ScholarPubMed