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Effect of Illite Particle Shape on Cesium Sorption

Published online by Cambridge University Press:  28 February 2024

Pavol Rajec ,
Vladimír Šucha ,
Dennis D. Eberl ,
Jan Środoń  and
Françoise Elsass
Pavol Rajec
Affiliation:
Department of Nuclear Chemistry, Comenius University, Mlynská dolina, 842 15 Bratislava, Slovakia
Vladimír Šucha*
Affiliation:
Department of Geology of Mineral Deposits, Comenius University, Mlynská dolina, 842 15 Bratislava, Slovakia
Dennis D. Eberl
Affiliation:
U.S. Geological Survey, 3215 Marine Street, Boulder, Colorado 80303, USA
Jan Środoń
Affiliation:
Institute of Geology, Polish Academy of Sciences, Senacka 1, Krakow, Poland
Françoise Elsass
Affiliation:
INRA, Station de Science du Sol, Route de St. Cyr, 78026 Versailles, France
*
E-mail of corresponding author: [email protected]
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Abstract

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Samples containing illite and illite-smectite, having different crystal shapes (plates, “barrels”, and filaments), were selected for sorption experiments with cesium. There is a positive correlation between total surface area and Cs-sorption capacity, but no correlation between total surface area and the distribution coefficient, Kd. Generally Kd increases with the edge surface area, although “hairy” (filamentous) illite does not fit this pattern, possibly because elongation of crystals along one axis reduces the number of specific sorption sites.

Keywords

Cesium SorptionDistribution CoefficientIlliteParticle Shape
Type
Research Article
Information
Clays and Clay Minerals , Volume 47 , Issue 6 , December 1999 , pp. 755 - 760
Copyright
Copyright © 1999, The Clay Minerals Society

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