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Composition and Properties of Synthetic Hydrotalcites

Published online by Cambridge University Press:  28 February 2024

C. Misra  and
A. J. Perrotta
C. Misra
Affiliation:
Alcoa Laboratories, Alcoa Center, Pennsylvania 15069
A. J. Perrotta
Affiliation:
Alcoa Laboratories, Alcoa Center, Pennsylvania 15069
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Abstract

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Hydrotalcites of high aluminum content have been synthesized from aluminate liquors of varying composition and activated magnesia obtained by calcination of hydroxide or hydroxycarbonate precursors. Lattice parameter measurements and chemical analyses of 21 synthetic hydrotalcites show that the aluminum substitution $$\left( {\rm{X = \frac{{Al}}{{Al + Mg}}}} \right)$$ for most of the products is about 0.35, which is at the maximum experimentally-observed limit of solid solubility. Pillared hydrotalcites were also prepared by molybdate, Chromate, and silicate anion replacement. A maximum distance of 10.4 Å between the brucite-like layers was observed for the Mo7O246− intercalated material.

Keywords

Aluminate liquorAluminum substitutionAnion replacementHydrotalciteMagnesium oxidePillaring
Type
Research Article
Information
Clays and Clay Minerals , Volume 40 , Issue 2 , April 1992 , pp. 145 - 150
Copyright
Copyright © 1992, The Clay Minerals Society

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