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Chemistry of Illite/Smectite and End-Member Illite

Published online by Cambridge University Press:  02 April 2024

Jan Środoń ,
David J. Morgan ,
Eric V. Eslinger ,
Dennis D. Eberl  and
Michael R. Karlinger
Jan Środoń
Affiliation:
Institute of Geological Sciences, Polish Academy of Sciences, 31-002 Krakow, Senacka 3, Poland
David J. Morgan
Affiliation:
British Geological Survey, 64 Gray's Inn Road, London WC1X 8NG, United Kingdom
Eric V. Eslinger
Affiliation:
Cities Service Oil and Gas Corporation, P.O. Box 3908, Tulsa, Oklahoma 74102
Dennis D. Eberl
Affiliation:
U.S. Geological Survey, MS 404, Federal Center, Denver, Colorado 80225
Michael R. Karlinger
Affiliation:
U.S. Geological Survey, MS 404, Federal Center, Denver, Colorado 80225
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Abstract

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Chemical data from three different series of diagenetic illite/smectites (I/S), analyzed statistically by two regresion techniques, indicate that the content of fixed-K per illite layer is not constant, but ranges from ~0.55 per O10(OH)2 for illite layers in randomly interstratified I/S (R=0; >50% smectite layers) to ~ 1.0 per O10(OH)2 for illite layers formed in ordered I/S (R>0; <50% smectite layers). By extrapolation of the experimental data, the following chemical characteristics were obtained for end-member illite derived from the alteration of smectite in bentonite: average fixed-K per illite layer = 0.75 per O10(OH)2; total charge = about -0.8; cation-exchange capacity = 15 meq/100 g; surface area (EGME) = 150 m2/g.

Keywords

BentoniteChemical compositionDiagenesisIlliteIllite/smectiteSmectite
Type
Research Article
Information
Clays and Clay Minerals , Volume 34 , Issue 4 , August 1986 , pp. 368 - 378
Copyright
Copyright © 1986, The Clay Minerals Society

Footnotes

1

Visiting exchange scientist at the Water Resources Division, U.S. Geological Survey, Denver, Colorado.

References

Carter, D. L., Heilman, M. D. and Gonzalez, C. L., 1965 Ethylene glycol monoethyl ether for determining surface area of silicate minerals Soil Sci. 100 356–360.CrossRefGoogle Scholar
Cooper, J. E. and Abedin, K. Z., 1981 The relationship between fixed ammonium-nitrogen and potassium in clays from a deep well on the Texas Gulf Coast Texas J. Sci. 34 103–111.Google Scholar
Eslinger, E., Highsmith, P., Albers, D. and de Mayo, B., 1979 Role of iron reduction in the conversion of smectite to illite in bentonites in the disturbed belt, Montana Clays & Clay Minerals 27 327–338.CrossRefGoogle Scholar
Grim, R. E., Bray, R. H. and Bradley, W. F., 1937 The mica in argillaceous sediments Amer. Mineral. 22 813–829.Google Scholar
Hoffman, J. and Hower, J., 1979 Clay mineral assemblages as low grade metamorphic geothermometers—application to the thrust faulted disturbed belt of Montana, USA Sac. Econ. Paleontol. Mineral. Spec. Publ. 26 55–79.Google Scholar
Hower, J. and Mowatt, T. C., 1966 The mineralogy of illites and mixed-layer illite/montmorillonites Amer. Mineral. 51 825–854.Google Scholar
Hower, J., Schmittroth, L. A., Perry, E. C. and Mowatt, T. C., 1964 X-ray spectrographic major constituent analysis of undiluted silicate rocks and minerals Geol. Soc. America Program 1964 Ann. Meeting, Miami, Florida .Google Scholar
Inoue, A. and Utada, M., 1983 Further investigations of a conversion series of dioctahedral mica/smectites in the Shinzan hydrothermal alteration area, northeast Japan Clays & Clay Minerals 31 401–412.CrossRefGoogle Scholar
Mackenzie, R. C., 1951 A micromethod for determination of cation-exchange capacity of clay J. Colloid Sci. 6 219–222.Google Scholar
Medlin, J. H., Suhr, N. N. and Bodkin, J. B., 1969 Atomic absorption analysis of silicates employing LiBO3 fusion At. Absorpt. Newsletter 8 25–29.Google Scholar
Parachoniak, W. and Środoń, J., 1973 The formation of kaolinite, montmorillonite, and mixed-layer montmorillonite-illites during the alteration of Carboniferous tuff (the Upper Silesian Coal Basin) Mineral. Polonica 4 37–56.Google Scholar
Sawhney, B. L. and Bailey, S. W., 1967 Interstratification in vermiculite Clays and Clay Minerals, Proc. 15th Natl. Conf., Pittsburgh, Pennsylvania, 1966 New York Pergamon Press 75–84.Google Scholar
Środoń, J., 1976 Mixed-layer smectite/illites in the bentonites and tonsteins of the Upper Silesian Coal Basin Prace Mineral. 49 1–84.Google Scholar
Środoń, J., 1980 Precise identification of illite/smectite interstratifications by X-ray powder diffraction Clays & Clay Minerals 28 401–411.CrossRefGoogle Scholar
Środoń, J., 1984 X-ray powder diffraction identification of illitic materials Clays & Clay Minerals 32 337–349.CrossRefGoogle Scholar
Środoń, J. and Eberl, D. D., 1984 Illite Micas 13 495–544.CrossRefGoogle Scholar
Środoń, J. and Eberl, D. D., 1984 Pre-burial and post-burial illitization of smectite Program with Abstracts, 21st Annual Meeting Clay Minerals Society Louisiana Baton Rouge 111.Google Scholar
Thompson, G. R. and Hower, J., 1975 The mineralogy of glauconite Clays & Clay Minerals 23 289–300.CrossRefGoogle Scholar
Weaver, C. E., 1965 Potassium content of illite Science 147 603–605.CrossRefGoogle ScholarPubMed
Weaver, C. E. and Pollard, L. D., 1963 The Chemistry of Clay Minerals Amsterdam Elsevier.Google Scholar