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Characterization of Colloidal Solids from Athabasca Fine Tails

Published online by Cambridge University Press:  28 February 2024

L. S. Kotlyar ,
Y. Deslandes ,
B. D. Sparks ,
H. Kodama  and
R. Schutte
L. S. Kotlyar*
Affiliation:
National Research Council of Canada, Institute for Environmental Chemistry, M-12, Montreal Road, Ottawa, Ontario, Canada K1A OR9
Y. Deslandes
Affiliation:
National Research Council of Canada, Institute for Environmental Chemistry, M-12, Montreal Road, Ottawa, Ontario, Canada K1A OR9
B. D. Sparks
Affiliation:
National Research Council of Canada, Institute for Environmental Chemistry, M-12, Montreal Road, Ottawa, Ontario, Canada K1A OR9
H. Kodama
Affiliation:
Centre for Land and Biological Resources Research
R. Schutte
Affiliation:
Research Department of Syncrude Ltd.
*
2To whom correspondence should be addressed.
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Abstract

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During processing of Athabasca oil sands, the finely divided solids form an aqueous suspension, which ultimately stabilizes as a gel-like structure retaining up to 90% of the process water. This gelling phenomenon is believed to be caused by colloidal inorganic components. Kaolinite and mica are the main crystalline minerals in these colloidal solids; swelling clays are present in only trace amounts. Non-crystalline components are more concentrated in the finer fraction of the solids. Although the surfaces of the colloidal solids are virtually free of Fe, some contamination with polar organic matter is observed.

Keywords

Fine tailsHydrophilicColloidal solids
Type
Research Article
Information
Clays and Clay Minerals , Volume 41 , Issue 3 , June 1993 , pp. 341 - 345
Copyright
Copyright © 1993, The Clay Minerals Society

Footnotes

1

Issued as NRC #32959.

References

Bhatia, Q. S., Pan, D. H. and Koberstein, J. T., 1988 Preferential surface adsorption in miscible blends of polystyrene and polyvinylmethylether Macromolecules 21 2166 10.1021/ma00185a049.CrossRefGoogle Scholar
Camp, F. W., 1977 Processing Athabasca tar sand tailings disposal Proc. Symp. on Tar Sands, 26th Can. Chem. Eng. Conf., Toronto, Paper 9a .CrossRefGoogle Scholar
Kodama, H., Jaakkimainen, M., van Olphen, H. and Veniale, F., 1982 A comparative study of selective chemical dissolution methods for separating non-crystalline components produced by grinding of silicates Proc. Int. Clay Conf., Bologna, Pavia, 1981 Amsterdam Elsevier 399 – 410.Google Scholar
Kodama, H., Kotlyar, L. S. and Ripmeester, J. A., 1989 Quantification of crystalline and non-crystalline material in ground kaolinite by X-ray powder diffraction, infrared, solid-state nuclear magnetic resonance and chemical dissolution analysis Clays & Clay Minerals 4 364 – 370 10.1346/CCMN.1989.0370410.CrossRefGoogle Scholar
Kotlyar, L. S., Majid, A. and Sparks, B. D., 1991 A study of factors affecting the stability of tailings sludge produced by the hot water bitumen extraction process Alberta, Canada Petroleum Society of CIM and AOSTRA, Banff 91 – 117.Google Scholar
Kotlyar, L. S., Lynds, M. M., Sparks, B. D., Schutte, R. and Woods, J. R., 1992 Colloidal solids from sludge: Effect of particle size on gel forming propensity in distilled and pond water Sludge Fundamentals Consortium Internal NRC Report No. EC-1243-92S, Ottawa, Ontario, Canada .Google Scholar
Maciel, G. and Sindorf, D., 1980 Silicon-29 nuclear magnetic resonance study of the surface silica gel by cross polarization and magic angle spinning J. Am. Chem. Soc. 102 7606 07 10.1021/ja00545a056.CrossRefGoogle Scholar
Muilenberg, G. E., 1979 Handbook of X-ray Photoelectron Spectroscopy Eden Prairie, Minnesota Perkin-Elmer Corporation.Google Scholar
Ripmeester, J. A. Kotlyar, L. S. and Sparks, B. D., 1992 2H NMR and the sol-gel transition in suspensions of colloidal clays Colloids and Surfaces .CrossRefGoogle Scholar