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Birnessites with Different Average Manganese Oxidation States Synthesized, Characterized, and Transformed to Todorokite at Atmospheric Pressure

Published online by Cambridge University Press:  01 January 2024

Haojie Cui ,
Guohong Qiu ,
Xionghan Feng ,
Wenfeng Tan  and
Fan Liu
Haojie Cui
Affiliation:
Key Laboratory of Subtropical Agricultural Resources and Environment, Ministry of Agriculture, Huazhong Agricultural University, Wuhan 430070, China Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China
Guohong Qiu
Affiliation:
Key Laboratory of Subtropical Agricultural Resources and Environment, Ministry of Agriculture, Huazhong Agricultural University, Wuhan 430070, China
Xionghan Feng
Affiliation:
Key Laboratory of Subtropical Agricultural Resources and Environment, Ministry of Agriculture, Huazhong Agricultural University, Wuhan 430070, China
Wenfeng Tan
Affiliation:
Key Laboratory of Subtropical Agricultural Resources and Environment, Ministry of Agriculture, Huazhong Agricultural University, Wuhan 430070, China
Fan Liu*
Affiliation:
Key Laboratory of Subtropical Agricultural Resources and Environment, Ministry of Agriculture, Huazhong Agricultural University, Wuhan 430070, China
*
* E-mail address of corresponding author: [email protected]
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Abstract

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Todorokite is a common manganese oxide mineral, with a tunnel structure, found in Earth surface environments, and is easily synthesized from layered birnessite. The aim of the current study was to prepare birnessites with different average manganese oxidation states (AOS) by controlling the MnO4−/Mn2+\$\end{document} ratio in concentrated NaOH or KOH. A series of (Na,K)-birnessites, Na-birnessites, and K-birnessites with different AOS was synthesized successfully in strongly alkaline media. The (Na,K)-birnessites and Na-birnessites prepared in NaOH clearly contained both large (500–1000 nm) and small (40–400 nm), plate-shaped crystallites. The K-birnessites prepared in KOH media consisted mostly of irregular (100–200 nm), plate-shaped crystallites. The degree of transformation of birnessite to todorokite at atmospheric pressure decreased as the AOS values of (Na,K)-birnessites and Na-birnessites increased from 3.51 to 3.80. No todorokite was present when a Na-birnessite with an AOS value of 3.87 was used as the precursor. Pyrophosphate, which is known to form strong complexes with Mn3+ at a pH range of 1–8, was added to a suspension of (Na,K)-birnessites in order to sequester the available Mn3+ in (Na,K)-birnessites. Removal of Mn3+ from birnessite MnO6 layers by pyrophosphate restricted transformation to todorokite — no (Na,K)-birnessite transformed to todorokite after pyrophosphate treatment. The interlayer K+ initially within (Na,K)-birnessites could not be completely ion-exchanged with Mg2+ to form todorokite at atmospheric pressure. No todorokite was forthcoming from K-birnessites even from those with small AOS values (3.50).

Keywords

AOSAtmospheric PressureBirnessiteTodorokite
Type
Research Article
Information
Clays and Clay Minerals , Volume 57 , Issue 6 , December 2009 , pp. 715 - 724
Copyright
Copyright © The Clay Minerals Society 2009

References

Al-Sagheer, F.A. and Zaki, M.L., 2004 Synthesis and surface characterization of todorokite-type microporous manganese oxides: implications for shape-selective oxidation catalysts Microporous and Mesoporous Materials 67 43–52 10.1016/j.micromeso.2003.10.005.CrossRefGoogle Scholar
Cui, H.J. Feng, X.H. Liu, F. Tan, W.F. and He, J.Z., 2005 Factors governing formation of todorokite at atmospheric pressure Science in China Series D — Earth Sciences 48 1678–1689 10.1360/01YD0550.CrossRefGoogle Scholar
Cui, H.J. Feng, X.H. He, J.Z. Liu, F. and Tan, W.F., 2006 Effects of reaction conditions on the formation of todorokite at atmospheric pressure Clays and Clay Minerals 54 605–615 10.1346/CCMN.2006.0540507.CrossRefGoogle Scholar
Cui, H.J. Liu, X.W. Tan, W.F. Feng, X.H. Liu, F. and Ruan, H.D., 2008 Influence of Mn(III) availability on the phase transformation from layered buserite to tunnel-structured todorokite Clays and Clay Minerals 56 397–403 10.1346/CCMN.2008.0560401.CrossRefGoogle Scholar
Cui, H. Feng, X. Tan, W. He, J. Hu, R. and Liu, F., 2009 Synthesis of todorokite-type manganese oxide from Cu-buserite by controlling the pH at atmospheric pressure Microporous and Mesoporous Materials 117 41–47 10.1016/j.micromeso.2008.06.006.CrossRefGoogle Scholar
Feng, X.H. Tan, W.F. Liu, F. Wang, J.B. and Ruan, H.D., 2004 Synthesis of todorokite at atmospheric pressure Chemistry of Materials 16 4330–4336 10.1021/cm0499545.CrossRefGoogle Scholar
Feng, X.H. Tan, W.F. Liu, F. Huang, Q.Y. and Liu, X.W., 2005 Pathways of birnessite formation in alkali medium Science in China Series D — Earth Sciences 48 1438–1451 10.1360/03yd0280.CrossRefGoogle Scholar
Golden, D.C. Chen, C.C. and Dixon, J.B., 1986 Synthesis of todorokite Science 231 717–719 10.1126/science.231.4739.717.CrossRefGoogle ScholarPubMed
Golden, D.C. Chen, C.C. and Dixon, J.B., 1987 Transformation of birnessite to buserite, todorokite, and manganite under mild hydrothermal treatment Clays and Clay Minerals 35 271–280 10.1346/CCMN.1987.0350404.CrossRefGoogle Scholar
Kang, L.P. Zhang, M.M. Liu, Z.H. and Ooi, K., 2007 IR spectra of manganese oxides with either layered or tunnel structures Spectrochimica Acta Part A 67 864–869 10.1016/j.saa.2006.09.001.CrossRefGoogle ScholarPubMed
Klewicki, J.K. and Morgan, J.J., 1998 Kinetic behavior of Mn(III) complexes of pyrophosphate, EDTA, and citrate Environmental Science & Technology 32 2916–2922 10.1021/es980308e.CrossRefGoogle Scholar
Kostka, J.E. Luther, GW III and Nealson, K.H., 1995 Chemical and biological reduction of Mn(III)-pyrophosphate complexes: Potential importance of dissolved Mn(III) as an environmental oxidant Geochimica et Cosmochimica Acta 59 885–894.Google Scholar
Kumagai, N. Komaba, S. Sakai, H. and Kumagai, N., 2001 Preparation of todorokite-type manganese-based oxide and its application as lithium and magnesium rechargeable battery cathode Journal of Power Sources 97–98 515–517 10.1016/S0378-7753(01)00726-1.CrossRefGoogle Scholar
Liu, J. Cai, J. Son, Y.C. Gao, Q. Suib, S.L. and Aindow, M., 2002 Magnesium manganese oxide nanoribbons: synthesis, characterization, and catalytic application The Journal of Physical Chemistry B 106 9761–9768 10.1021/jp0208586.CrossRefGoogle Scholar
Liu, Z.H. Kang, L. Ooi, K. Makita, Y. and Feng, Q., 2005 Studies on the formation of todorokite-type manganese oxide with different crystalline birnessite by Mg2+-templating reaction Journal of Colloid and Interface Science 285 239–246 10.1016/j.jcis.2004.11.021.CrossRefGoogle ScholarPubMed
Luo, J. Zhang, Q. Huang, A. Giraldo, O. and Suib, S.L., 1999 Double-aging method for preparation of stabilized Na-buserite and transformations to todorokites incorporated with various metals Inorganic Chemistry 38 6106–6113 10.1021/ic980675r.CrossRefGoogle ScholarPubMed
Meilin, T.A. and Lei, G., 1993 Stabilization of 10 Å-manganates by interlayer cations and hydrothermal treatment: Implications for the mineralogy of marine manganese concretions Marine Geology 115 67–83 10.1016/0025-3227(93)90075-7.CrossRefGoogle Scholar
Nguyen, M. Quemard, A. Broussy, S. Bernadou, J. and Meunier, B., 2002 Mn(III) pyrophosphate as an efficient tool for studying the mode of action of Isoniazid on the InhA protein of Mycobacterium tuberculosis Antimicrobial Agents and Chemotherapy 46 2137–2144 10.1128/AAC.46.7.2137-2144.2002.CrossRefGoogle ScholarPubMed
Post, J.E., 1999 Manganese oxide minerals: Crystal structures and economic and environmental significance Proceedings of the National Academy of Sciences of the United States of America 96 3447–3454 10.1073/pnas.96.7.3447.CrossRefGoogle ScholarPubMed
Potter, R.M. and Rossman, G.R., 1979 The tetravalent manganese oxides: identification, hydration, and structural relationships by infrared spectroscopy American Mineralogist 64 1199–1218.Google Scholar
Shen, Y.F. Zerger, R.P. DeGuzman, R.N. Suib, S.L. McCurdy, L. Potter, D.I. and O’Young, C.L., 1993 Manganese oxide octahedral molecular sieves: preparation, characterization, and applications Science 260 511–515 10.1126/science.260.5107.511.CrossRefGoogle ScholarPubMed
Shen, Y.F. Suib, S.L. and O’Young, C.L., 1994 Effects of inorganic cation templates on octahedral molecular sieves of manganese oxide Journal of the American Chemical Society 116 11020–11029 10.1021/ja00103a018.CrossRefGoogle Scholar
Turner, S. Siegel, M.D. and Buseck, P.R., 1982 Structural features of todorokite intergrowths in manganese nodules Nature 296 841–842 10.1038/296841a0.CrossRefGoogle Scholar
Webb, S.M. Dick, G.J. Bargar, J.R. and Tebo, B.M., 2005 Evidence for the presence of Mn(III) intermediates in the bacterial oxidation of Mn((II) Proceedings of the National Academy of Sciences of the United States of America 102 5558–5563 10.1073/pnas.0409119102.CrossRefGoogle ScholarPubMed
Zhou, H. Wang, J.Y. Chen, X. O’Young, C.L. and Suib, S.L., 1998 Studies of oxidative dehydrogenation of ethanol over manganese oxide octahedral molecular sieve catalysts Microporous and Mesoporous Materials 21 315–324 10.1016/S1387-1811(98)00034-1.CrossRefGoogle Scholar