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Beidellite in E Horizons of Northern Idaho Spodosols Formed in Volcanic Ash

Published online by Cambridge University Press:  28 February 2024

P. A. McDaniel ,
A. L. Falen ,
K. R. Tice ,
R. C. Graham  and
S. E. Fendorf
P. A. McDaniel
Affiliation:
Soil Science Division, University of Idaho, Moscow, Idaho 83844-2339
A. L. Falen
Affiliation:
Soil Science Division, University of Idaho, Moscow, Idaho 83844-2339
K. R. Tice
Affiliation:
Dep. of Soil and Environmental Sciences, University of California, Riverside, California 92521-0424
R. C. Graham
Affiliation:
Dep. of Soil and Environmental Sciences, University of California, Riverside, California 92521-0424
S. E. Fendorf
Affiliation:
Soil Science Division, University of Idaho, Moscow, Idaho 83844-2339
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Abstract

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While soils formed in tephra are typically dominated by poorly crystalline clay minerals, the occurrence of smectite in E horizons of podzolized soils (Spodosols) has been well-documented. We have observed a well-crystallized smectite mineral dominating the clay fraction of E horizons in tephra-derived soils of northern Idaho. This study was initiated to examine properties and distribution of this mineral along a developmental sequence of high-elevation, forested Spodosols formed in 6800-yr-old Mazama tephra. Three soils exhibiting strong, moderate, and weak E horizon development were sampled along an elevational and climatic gradient. The smectite mineral was identified as beidellite based on expansion and layer charge characteristics. Heated, Li-saturated samples from the most strongly developed E horizon exhibited relatively complete expansion to 1.8 nm with glycerol solvation and mean layer charge was calculated to be 0.44 molc/formula unit using sorption characteristics of alkylammonium ions. Apparent crystallinity and relative abundance of the beidellite in clay fractions decrease with decreasing E horizon development. The more poorly crystalline beidellite is associated with a non-expansive 1.4-nm mineral with considerable Al-hydroxy interlayering. Beidellite was not detected in underlying glacial drift or in a thin layer of 200-yr-old ash that mantles these soils, suggesting it is not inherited from these materials. Rather, our results indicate that beidellite forms in these soils in an environment characterized by low pH and a large flux of organic metal-complexing agents.

Keywords

Northern IdahoPodzolizationSmectiteSoil genesisTephra
Type
Research Article
Information
Clays and Clay Minerals , Volume 43 , Issue 5 , October 1995 , pp. 525 - 532
Copyright
Copyright © 1995, The Clay Minerals Society

References

Bacon, C. R., 1983. Eruptive history of Mount Mazama and Crater Lake caldera, Cascade Range, USA. J. Volcanol. Geotherm. Res. 18: 57–155.CrossRefGoogle Scholar
Barnhisel, R. I., and Bertsch, P. M. 1989. Chlorites and hydroxy-interlayered vermiculite and smectite. In Minerals in Soil Environments, 2nd ed. Dixon, J. B., and Weed, S. B., eds. Madison, Wisconsin: Soil Sci. Soc. Am., 729–788.Google Scholar
Borchardt, G., 1989. Smectites. In Minerals in Soil Environments, 2nd ed. Dixon, J. B., and Weed, S. B., eds. Madison, Wisconsin: Soil Sci. Soc. Am., 675–727.Google Scholar
Brown, G., and Brindley, G. W. 1980. X-ray diffraction procedures for clay mineral identification. In Crystal Structures of Clay Minerals and Their X-ray Identification. Brindley, G. W., and Brown, G., eds. London: Mineralogical Society, 305–360.CrossRefGoogle Scholar
Coen, G. M., and Arnold, R. W. 1972. Clay mineral genesis of some New York Spodosols. Soil Sci. Soc. Am. Proc. 36: 342–350.CrossRefGoogle Scholar
Chichester, F. W., Youngberg, C. T., and Harward, M. E. 1969. Clay mineralogy of soils formed on Mazama pumice. Soil Sci. Soc. Am. Proc. 33: 115–120.CrossRefGoogle Scholar
Cooper, S. V., Neiman, K. E., and Roberts, D. W. 1991. Forest Habitat Types of Northern Idaho: A Second Approximation. General Technical Report INT-236. Ogden, Utah: U.S. Dept. of Agric.-Forest Service, Intermountain Research Station, 143 pp.CrossRefGoogle Scholar
Dahlgren, R., Shoji, S., and Nanzyo, M. 1993. Mineralogical characteristics of volcanic ash soils. In Volcanic Ash Soils. Developments in soil science 21. Shoji, S., et al, eds. Amsterdam: Elsevier, 101–143.Google Scholar
Douglas, L. A., 1982. Smectites in acidic soils. In Proc. Int. Clay Conf. 1981. Olphen, H. van and Veniale, F., eds. Elsevier North New York: Holland, Inc., 635–644.Google Scholar
Dudas, M. J., and Harward, M. E. 1975. Weathering and authigenic halloysite in soil developed in Mazama ash. Soil Sci. Soc. Am. Proc. 39: 561–566.CrossRefGoogle Scholar
Fanning, D. S., and Fanning, M. C. B. 1989. Soil Morphology, Genesis, and Classification. New York: John Wiley and Sons, 395 pp.Google Scholar
Fryxell, R. H., 1965. Mazama and Glacier Peak volcanic ash layers: relative ages. Science 147: 1288–1290.CrossRefGoogle ScholarPubMed
Gee, G. W., and Bauder, J. W. 1986. Particle-size analysis. In Methods of Soil Analysis. Part I, 2nd ed. Physical and mineralogical methods. Klute, A., ed. Agronomy 9: 383–441.Google Scholar
Greene-Kelly, R., 1953. The identification of montmoril-lonoids in clays. J. Soil Sci. 4: 233–237.Google Scholar
Hartmann, H., Sposito, G., Yang, A., Manne, S., Gould, S. A. C., and Hansma, P. K. 1990. Molecular-scale imaging of clay mineral surfaces with the atomic force microscope. Clays & Clay Miner. 38: 337–342.CrossRefGoogle Scholar
Hunter, C. R., 1988. Pedogenesis in Mazama tephra along a bioclimatic gradient in the Blue Mountains of southeastern Washington. Ph.D. dissertation. Washington State University, Pullman, 128 pp.Google Scholar
Jackson, M. L., 1975. Soil Chemical Analysis—Advanced Course, 2nd ed., 10th printing. Madison, Wisconsin: Published by author, 895 pp.Google Scholar
Kowano, M., and Tomita, K. 1992. Formation of allophane and beidellite during hydrothermal alteration of volcanic glass below 200°C. Clays & Clay Miner. 40: 666–674.CrossRefGoogle Scholar
Lagaly, G., 1981. Characterization of clays by organic compounds. Clay Miner. 16: 1–21.CrossRefGoogle Scholar
Lagaly, G., and Weiss, A. 1969. Determination of the layer charge in mica-type layer silicates. Proc. Int. Clay Conf., Tokyo, Vol. 1. Heller, L., ed. Jerusalem: Israel University Press, 61–80.Google Scholar
Lim, C. H., and Jackson, M. L. 1986. Expandable phyllo-silicate reactions with lithium on heating. Clays & Clay Miner. 34: 346–352.CrossRefGoogle Scholar
McDaniel, P. A., Fosberg, M. A., and Falen, A. L. 1993. Expression of andic and spodic properties in tephra-influenced soils of northern Idaho, USA. Geoderma 58: 79–94.CrossRefGoogle Scholar
McDaniel, P. A., Houston, K. E., Fosberg, M. A., and Falen, A. L. 1994. Soil-plant community relationships in the Selkirk Mountains of northern Idaho. Northwest Sci. 68: 22–30.Google Scholar
Mullineaux, D. R., 1986. Summary of pre-1980 tephra-fall deposits erupted from Mount St. Helens, Washington State, USA. Bull. Volcanol. 48: 16–26.CrossRefGoogle Scholar
Nelson, D. W., and Sommers, L. E. 1982. Total carbon, organic carbon, and organic matter. In Methods of Soil Analysis, Part 2, 2nd ed. Page, A. L., et al, eds. Agronomy 9: 539–579.Google Scholar
Pevear, D. R., Dethier, D. P., and Frank, D. 1982. Clay minerals in the 1980 deposits from Mount St. Helens. Clays & Clay Miner. 30: 241–253.CrossRefGoogle Scholar
Ross, G. J., and Mortland, M. M. 1966. A soil beidellite. Soil Sci. Soc. Am. Proc. 30: 337–343.Google Scholar
Sarna-Wojcicki, A. M., Champion, D. E., and Davis, J. D. 1983. Holocene volcanism in the conterminous United States and the role of silicic volcanic ash layers in correlation of latest Pleistocene and Holocene deposits. In Quaternary Environments of the United States. 2. The Holocene. Wright, H. E. Jr., ed. Minneapolis, Minnesota: University of Minnesota, 52–77.Google Scholar
Smith, H. W., Okazaki, R., and Aarstad, J. 1968. Recent volcanic ash in soils of northwestern Washington and northern Idaho. Northwest Sci. 42: 150–160.Google Scholar
Soil Conservation Service. 1972. Procedures for collecting soil samples and methods of analysis for soil survey. Soil Survey Invest. Rep. 1. USDA-SCS. U.S. Gov. Print. Office, Washington, D.C.Google Scholar
Soil Conservation Service. 1984. Procedures for collecting soil samples and methods of analysis for soil survey. Soil Survey Invest. Rep. 1. USDA-SCS. U.S. Gov. Print. Office, Washington, DC.Google Scholar
Soil Survey Staff. 1992. Keys to Soil Taxonomy, 5th ed. SMSS Tech. Monograph no. 19. Blacksburg, Virginia: Pocahontas Press, Inc., 556 pp.Google Scholar
Tazaki, K., Fyfe, W. S., and van der Gaast, S. J. 1989. Growth of clay minerals in natural and synthetic glasses. Clays & Clay Miner. 37: 348–354.Google Scholar
Thomas, G. W., 1982. Exchangeable cations. In Methods of Soil Analysis. Part 2, 2nd ed. Page, A. L., et al, eds. Agronomy 9: 159–165.Google Scholar
Ugolini, F. C., Dahlgren, R., LaManna, J., Nuhn, W., and Zachara, J. 1991. Mineralogy and weathering processes in Recent and Holocene tephra deposits of the Pacific Northwest, USA. Geoderma 51: 277–299.Google Scholar
Whittig, L. D., and Allardice, W. R. 1986. X-ray diffraction techniques. In Methods of soil analysis. Part 1, 2nd ed. Klute, A., ed. Agronomy 9: 331–362.Google Scholar
Zabowski, D., and Ugolini, F. C. 1992. Seasonality in the mineral stability of a subalpine Spodosol. Soil Science 154: 497–507.CrossRefGoogle Scholar