Hostname: page-component-cd9895bd7-dzt6s Total loading time: 0 Render date: 2024-12-19T00:25:57.416Z Has data issue: false hasContentIssue false
  • English
  • Français

Atomic Force Microscopy Study of Hydrothermal Illite in Izumiyama Pottery Stone from Arita, Saga Prefecture, Japan

Published online by Cambridge University Press:  28 February 2024

Yoshihiro Kuwahara ,
Seiichiro Uehara  and
Yoshikazu Aoki
Yoshihiro Kuwahara
Affiliation:
Department of Evolution of Earth Environments, Graduate School of Social and Cultural Studies, Kyushu University, Ropponmatsu, Fukuoka 810-8560, Japan
Seiichiro Uehara
Affiliation:
Department of Earth and Planetary Sciences, Faculty of Science, Kyushu University, Hakozaki, Fukuoka 812-8581, Japan
Yoshikazu Aoki
Affiliation:
Department of Earth and Planetary Sciences, Faculty of Science, Kyushu University, Hakozaki, Fukuoka 812-8581, Japan
Rights & Permissions [Opens in a new window]

Abstract

Core share and HTML view are not available for this content. However, as you have access to this content, a full PDF is available via the ‘Save PDF’ action button.

The surface microtopographic observations and analyses of Izumiyama hydrothermal illite particles were made by utilizing tapping-mode atomic force microscopy (TMAFM). The Izumiyama illite particles showed platy to lath shapes. Platy particles exhibited various spiral growth patterns, i.e. circular, malformed circular, or polygonal single unit-cell layer spirals, polygonal parallel step spiral, or interlaced spiral patterns. The polygonal parallel step spiral and interlaced spiral patterns are formed by two single unit-cell layers rotated by 180° and 120° arising from a single screw dislocation point, respectively. The spiral patterns indicate that the illite particles have 1M, 2O and 2M1 polytypes. Lath-shaped particles show only interlacing patterns supporting the formation of 2M1 structures.

Particles showing circular or malformed circular spirals were found to be thinner and to have narrower step separations than particles showing polygonal spirals. Polygonal platy and lath-shaped particles showing interlaced patterns tended to be thicker and to have wider step separations than the other polygonal platy particles.

These results suggest that the Izumiyama illites crystallize as the result of a mechanism involving solution-mediated polytypes and spiral-type transformations of illite. The mechanism involves the Ostwald ripening process, i.e. a transformation of the polytype and spiral shape. The sequence of crystallization of the Izumiyama illite is: 1M circular spirals → 1M, 2O polygonal spirals → 2M1 polygonal spirals occurring during crystal growth and sequentially overgrowing on the initial particle surfaces. The super-saturation of the hydrothermal solution probably decreases gradually during the transformation, and this decrease may cause not only the transformation from a circular to a polygonal crystal morphology but also the development of a lath habit due to the inhibition of the growth rate in the [010] direction of the particle.

Keywords

Atomic Force Microscopy (AFM)Hydrothermal IlliteMicrotopographyMorphologyPolytypeSpiral Growth2O Polytype
Type
Research Article
Information
Clays and Clay Minerals , Volume 49 , Issue 4 , August 2001 , pp. 300 - 309
Copyright
Copyright © 2001, The Clay Minerals Society

References

Baronnet, A., 1972 Growth mechanisms and polytypism in synthetic hydroxyl-bearing phlogopite American Mineralogist 57 1272–1293.Google Scholar
Baronnet, A. and Kaldis, E., 1980 Polytypism in micas: A survey with emphasis on the crystal growth aspect Current Topics in Material Science 447–548.Google Scholar
Baronnet, A. and Buseck, P. R., 1992 Polytypism and stacking disorder Minerals and Reactions at the Atomic Scale: Transmission Electron Microscopy 231–238 10.1515/9781501509735-011.CrossRefGoogle Scholar
Blum, A. E., Nagy, K. L. and Blum, A. E., 1994 Determination of illite/smectite particle morphology using scanning force microscopy Scanning Probe Microscopy of Clay Minerals 172–202.Google Scholar
Blum, A. E. Lasaga, A. C. and Stumm, W., 1987 Monte Carlo simulations of surface reaction rate laws Aquatic Surface Chemistry, Chemical Processes at the Particle-Water Interface 255–292.Google Scholar
Frank, F.C., 1949 The influence of dislocations on crystal growth Discussions of the Faraday Society 5 48–54 10.1039/df9490500048.CrossRefGoogle Scholar
van Giese, R. F. Oss, C. J., Guthrie, G. D. and Mossman, B. T., 1993 The surface thermodynamic properties of silicates and their interactions with biological materials Health Effects of Mineral Dusts 327–346 10.1515/9781501509711-013.CrossRefGoogle Scholar
Griffen, D. T. and Griffen, D. T., 1992 Micas Silicate Crystal Chemistry 101–149.CrossRefGoogle Scholar
Gritsaenko, G. S. Samotoyin, N. D., Heller, L. and Weiss, A., 1966 The decoration method applied to the study of clay minerals Proceedings of the International Clay Conference, Jerusalem, Israel 391–400.Google Scholar
Hirasawa, K. and Uehara, S., 1999 Hydrothermal history of the Izumiyama pottery stone deposit inferred from micro-texture and microstructure analysis of illite by SEM and TEM Resource Geology 20 113–122.Google Scholar
Inoue, A. Kohyama, N. Kitagawa, R. and Watanabe, T., 1987 Chemical and morphological evidence for the conversion of smectite to illite Clays and Clay Minerals 35 111–120 10.1346/CCMN.1987.0350203.CrossRefGoogle Scholar
Inoue, A. Velde, B. Meunier, A. and Touchard, G., 1988 Mechanism of illite formation during smectite-to-illite conversion in a hydrothermal system American Mineralogist 73 1325–1334.Google Scholar
Kantorowicz, J. D., 1990 The influence of variations in illite morphology on the permeability of Middle Jurassic Brent Group sandstones, Cormorant Field, UK North Sea Marine and Petroleum Geology 7 66–74 10.1016/0264-8172(90)90057-N.CrossRefGoogle Scholar
Kitagawa, R., 1998 Surface microtopography of illite crystals from different modes of occurrence Canadian Mineralogist 36 1559–1567.Google Scholar
Kitagawa, R. Takeno, S. and Sunagawa, I., 1983 Surface microtopographies of sericite crystals formed in different environmental conditions Mineralogical Journal 11 282–296 10.2465/minerj.11.282.CrossRefGoogle Scholar
Komatsu, H. and Sunagawa, I., 1965 Surface structures of sphalerite crystals American Mineralogist 50 1046–1057.Google Scholar
Kuroda, T., 1984 Kesshou-ha-ikiteiru (Crystal lives): The Mechanism of its Growth and Transformation of Morphology. .Google Scholar
Kuwahara, Y. Uehara, S. and Aoki, Y., 1998 Surface micro-topography of lath-shaped hydrothermal illite by Tapping Mode® and Contact Mode AFM Clays and Clay Minerals 46 547–582 10.1346/CCMN.1998.0460511.CrossRefGoogle Scholar
Lindgreen, H. Garnaes, J. Hansen, P. L. Besenbacher, F. Laegsgaard, E. Stensgaard, I. Gould, S A C and Hansma, P. K., 1991 Ultrafine particles of North Sea illite/smectite clay minerals investigated by STM and AFM American Mineralogist 76 1218–1222.Google Scholar
Lindgreen, H. Garnaes, J. Besenbacher, F. Laegsgaard, E. and Stensgaard, I., 1992 Illite-smectite from the North Sea investigated by scanning tunnelling microscopy Clay Minerals 27 331–342 10.1180/claymin.1992.027.3.06.CrossRefGoogle Scholar
Maeda, K. Watanabe, K. Izawa, E. Itaya, T. and Takeuchi, K., 1996 K-Ar ages of gold mineralization and argilliza-tion in the Arita-Hasami area, western Kyushu, Japan Resource Geology 46 25–31.Google Scholar
McHardy, W. J. Wilson, M. J. and Tait, J. M., 1982 Electron microscope and X-ray diffraction studies of filamentous il-litic clay from sandstones of the Magnus field Clay Minerals 17 23–39 10.1180/claymin.1982.017.1.04.CrossRefGoogle Scholar
Mukhamet-Galeyev, A. P. Pokrovskiy, V. A. Zotov, A. V. Iva-nov, I. P. and Samotoin, N. D., 1985 Kinetics and mechanism of hydrothermal crystallization of 2M 1, muscovite: an experimental study International Geology Review 27 1352–1364 10.1080/00206818509466511.CrossRefGoogle Scholar
Nadeau, P. H. Wilson, M. J. McHardy, W. J. and Tait, J. M., 1987 Fundamental nature of illite/smectite Clays and Clay Minerals 35 77–79 10.1346/CCMN.1987.0350111.CrossRefGoogle Scholar
Nagy, K. L., Nagy, K. L. and Blum, A. E., 1994 Application of morphological data obtained using scanning force microscopy to quantification of fibrous illite growth rates Scanning Probe Microscopy of Clay Minerals 204–239.CrossRefGoogle Scholar
Nakagawa, M. Nakamoto, J. and Yoshihara, T., 1995 Hydrothermal alteration at the Izumiyama pottery stone deposit, Saga prefecture—Mineralogical properties of quartz and NH4-bearing sericite Journal of Clay Science Society of Japan 35 1–14.Google Scholar
Robie, R. A. Hemingway, B. S. and Fisher, J. R., 1978 Thermodynamic properties of minerals and related substances at 298.15 K and 1 bar pressure and higher temperatures U.S. Geological Survey Bulletin 1452 .Google Scholar
Środoń, J. Eberl, D. D. and Bailey, S. W., 1984 Illite Micas 495–544 10.1515/9781501508820-016.CrossRefGoogle Scholar
Sunagawa, I., 1960 Mechanism of crystal growth, etching and twin formation of hematite Mineralogical Journal 3 59–89 10.2465/minerj1953.3.59.CrossRefGoogle Scholar
Sunagawa, I., 1961 Step height of spirals on natural hematite crystals American Mineralogist 46 1216–1226.Google Scholar
Sunagawa, I., 1962 Mechanism of growth of hematite American Mineralogist 47 1139–1155.Google Scholar
Sunagawa, I., 1964 Growth spirals on phlogopite crystals American Mineralogist 49 1427–1434.Google Scholar
Sunagawa, I. and Koshino, Y., 1975 Growth spirals on kaolin group minerals American Mineralogist 60 407–412.Google Scholar
Tomura, S. Kitamura, M. and Sunagawa, I., 1979 Surface microtopography of metamorphic white micas Physics and Chemistry of Minerals 5 65–81 10.1007/BF00308169.CrossRefGoogle Scholar
Velde, B., 1965 Experimental determination of muscovite polymorph stabilities American Mineralogist 50 436–449.Google Scholar
Verma, A. R., 1956 A phase contrast microscopic study of the surface structure of blende crystals Mineralogical Magazine 31 136 10.1180/minmag.1956.031.233.03.CrossRefGoogle Scholar
Walton, A. G., 1967 The Formation and Properties of Precipitates, Chemical Analysis .Google Scholar