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Adsorption and Photo-reactivity of Bensulfuron-Methyl On Homoionic Clays

Published online by Cambridge University Press:  01 January 2024

Youbin Si ,
Shenqiang Wang ,
Dongmei Zhou  and
Huaiman Chen
Youbin Si*
Affiliation:
College of Resource and Environmental Science, Anhui Agricultural University, Hefei 230036, China
Shenqiang Wang
Affiliation:
Institute of Soil Science, Chinese Academy of Sciences, Nanjing 210008, China
Dongmei Zhou
Affiliation:
Institute of Soil Science, Chinese Academy of Sciences, Nanjing 210008, China
Huaiman Chen
Affiliation:
Institute of Soil Science, Chinese Academy of Sciences, Nanjing 210008, China
*
*E-mail address of corresponding author: [email protected]
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Abstract

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The adsorption and photolysis of the herbicide bensulfuron-methyl [2-(4, 6-dimethoxypyrimidm-2-carbamoylsulfamoyl)-o-toluic acid methyl ester] on homoionic Na+-, Ca2+- and Fe3+-montmorillonite and kaolinite clays were studied. The Freundlich adsorption coefficient, Kf, measured from isotherms on clays followed the order Na+ < Ca2+ < Fe3+. Montmorillonite showed a greater adsorptive capacity than kaolinite. Analysis of Fourier transform infrared spectra of bensulfuron-methyl adsorbed on clay suggested probable bonding interactions between bensulfuron-methyl and homoionic clays. The photolysis rate of herbicide adsorbed on homoionic clay surfaces was quite slow to its free state and decreased in the order Na+ > Ca2+ > Fe3+, indicating that adsorption may have prevented photolysis.

Keywords

AdsorptionBensulfuron-methylInfrared SpectroscopyKaoliniteMontmorillonitePhotolysis
Type
Research Article
Information
Clays and Clay Minerals , Volume 52 , Issue 6 , December 2004 , pp. 742 - 748
Copyright
Copyright © 2004, The Clay Minerals Society

References

Banerjee, K. and Dureja, P., (1995) Photostabilization of quinalphos by crystal violet on the surface of kaolinite and palygorskite Pesticide Science 43 333–337 10.1002/ps.2780430413.CrossRefGoogle Scholar
Beyer, E.M. Jr. Duffy, M.J. Hay, J.V. and Schlueter, D.D., (1988) Sulfonylureas Herbicides: Chemistry Degradation and Mode of Action 3 117–190.Google Scholar
Calamai, L. Pantani, O. Pusino, A. Gessa, C. and Fusi, P., (1997) Interaction of rimsulfuron with smectites Clays and Clay Minerals 45 23–27 10.1346/CCMN.1997.0450103.CrossRefGoogle Scholar
Cavanna, S. Garatti, E. Rastelli, E. and Molinari, G.P., (1998) Adsorption and desorption of bensulfuron-methyl on Italian paddy field soils Chemosphere 37 1547–1555 10.1016/S0045-6535(98)00149-0.CrossRefGoogle Scholar
Cox, L. Koskinen, W.C. Celis, R. Yen, P.Y. Hermosin, M.C. and Cornejo, J., (1998) Sorption of imidacloprid on soil clay mineral and organic components Soil Science Society of America Journal 62 911–915 10.2136/sssaj1998.03615995006200040009x.CrossRefGoogle Scholar
El-Nahhal, Y. Undabeytia, T. Polubesova, T. Mishael, Y.G. Nir, S. and Rubin, B., (2001) Organo-clay formulations of pesticides: reduced leaching and photodegradation Applied Clay Science 18 309–326 10.1016/S0169-1317(01)00028-X.CrossRefGoogle Scholar
Hebert, V.R. and Miller, G.C., (1990) Depth dependence of direct and indirect photolysis on soil surfaces Journal of Agricultural and Food Chemistry 38 913–918 10.1021/jf00093a069.CrossRefGoogle Scholar
Katagi, T., (1990) Photoinduced oxidation of the organophosphorus fungicide tolclofos-methyl on clay minerals Journal of Agricultural and Food Chemistry 38 1595–1600 10.1021/jf00097a035.CrossRefGoogle Scholar
Kowalska, M. Guler, H. and Cocke, D.L., (1994) Interactions of clay minerals with organic pollutants The Science of the Total Environment 141 223–240 10.1016/0048-9697(94)90030-2.CrossRefGoogle Scholar
Laird, D.A. Yen, P.Y. Koskinen, W.C. Steinheimer, T.R. and Dowdy, R.H., (1994) Sorption of atrazine on soil clay components Environmental Science and Technology 28 1054–1061 10.1021/es00055a014.CrossRefGoogle ScholarPubMed
Langeland, K.A. and Laroche, F.B., (1994) Persistence of bensulfuron-methyl and control of Hydrilla in shallow ponds Journal of Aquatic and Plant Management 32 12–14.Google Scholar
Liu, W.P. Gan, J.Y. Papiernik, S.K. and Yates, S.R., (2000) Sorption and catalytic hydrolysis of diethatyl- ethyl on homoionic clays Journal of Agricultural and Food Chemistry 48 1935–1940 10.1021/jf990378k.CrossRefGoogle ScholarPubMed
Margulies, L. Stern, T. Rubin, B. and Ruzo, L.O., (1992) Photostabilization of trifluralin adsorbed on a clay matrix Journal of Agricultural and Food Chemistry 40 152–155 10.1021/jf00013a030.CrossRefGoogle Scholar
Margulies, L. Rozen, H. Stern, T. Rytwo, G. Rubin, B. Ruzo, L.O. Nir, S. and Cohen, E., (1993) Photostabilization of pesticides by clays and chromophores Archives of Insect Biochemistry and Physiology 22 467–486 10.1002/arch.940220313.CrossRefGoogle Scholar
Misra, B. Graebing, P.W. and Chib, J.S., (1997) Photodegradation of chloramben on a soil surface: a laboratory-controlled study Journal of Agricultural and Food Chemistry 45 1464–1467 10.1021/jf960778x.CrossRefGoogle Scholar
Nicosia, S. Collison, C. and Lee, P., (1991) Bensulfuron-methyl dissipation in California rice fields and residue levels in agricultural drains and the Sacramento River Bulletin of Environmental Contamination and Toxicology 47 131–137 10.1007/BF01689464.CrossRefGoogle ScholarPubMed
Pantani, O. Calamai, L. and Fusi, P., (1994) Influence of clay minerals on adsorption and degradation of a sulfonylurea herbicide (Cinosulfuron) Applied Clay Science 8 373–387 10.1016/0169-1317(94)90026-4.CrossRefGoogle Scholar
Pantani, O. Pusino, A. Calamai, L. Gessa, C. and Fusi, P., (1996) Adsorption and degradation of rimsulfuron on Al hectorite Journal of Agricultural and Food Chemistry 44 617–621 10.1021/jf950107j.CrossRefGoogle Scholar
Pantani, O. Dousset, S. Schiavon, M. and Fusi, P., (1997) Adsorption of isoproturon on homoionic clays Chemosphere 35 2619–2626 10.1016/S0045-6535(97)00335-4.CrossRefGoogle Scholar
Pusino, A. Liu, W. and Gessa, C., (1993) Dimepiperate adsorption and hydrolysis on Al3+-, Fe3+-, Ca2+, and Na+-montmorillonite Clays and Clay Minerals 41 335–340 10.1346/CCMN.1993.0410308.CrossRefGoogle Scholar
Pusino, A. Gelsomino, A. and Gessa, C., (1995) Adsorption mechanisms of Imazamethabenz-methyl on homoionic montmorillonite Clays and Clay Minerals 43 346–352 10.1346/CCMN.1995.0430309.CrossRefGoogle Scholar
Pusino, A. Petretto, S. and Gessa, C., (1996) Montmorillonite surface-catalyzed hydrolysis of fenoxaprop- ethyl Journal of Agricultural and Food Chemistry 44 1150–1154 10.1021/jf950252x.CrossRefGoogle Scholar
Pusino, A. Braschi, I. and Gessa, C., (2000) Adsorption and degradation of triasulfuron on homoionic montmorillonites Clays and Clay Minerals 48 19–25 10.1346/CCMN.2000.0480103.CrossRefGoogle Scholar
Pusino, A. Gelsomino, A. Fiori, M.G. and Gessa, C., (2003) Adsorption of two quinolinecarboxylic acid herbicides on homoionic montmorillonites Clays and Clay Minerals 51 143–149 10.1346/CCMN.2003.0510203.CrossRefGoogle Scholar
Rozen, H. and Margulies, L., (1991) Photostabilization of tetrahydro-2-(nitromethylene)-2H-1, 3-thiazine adsorbed on clays Journal of Agricultural and Food Chemistry 39 1320–1325 10.1021/jf00007a025.CrossRefGoogle Scholar
Sengnil, K. Usur, K. and Ishizuka, K., (1992) Recovery from growth inhibition and acetolactate synthase activity in rice suspension-cultured cells treated with bensulfuron-methyl Weed Research of Japan 37 28–34.Google Scholar
Sheppard, M.I. Thibault, D.H. and Mitchell, J.H., (1987) Element leaching and capillary rise in sandy soil cores Journal of Environmental Quality 16 273–284 10.2134/jeq1987.00472425001600030016x.CrossRefGoogle Scholar
Si, Y.B. Yue, Y.D. Chen, H.M. and Zhou, D.M., (2004) Photodegradation of bensulfuron-methyl on soil surface Pest Management Science 60 286–290 10.1002/ps.803.CrossRefGoogle ScholarPubMed
Si, Y.B. Zhou, J. Chen, H.M. and Zhou, D.M., (2004) Photostabilization of the herbicide bensulfuron-methyl by using organoclays Chemosphere 54 943–950 10.1016/j.chemosphere.2003.09.033.CrossRefGoogle ScholarPubMed
Strek, H.J., (1998) Fate of chlorsulfuron in the environment. 2. Field evaluations Pesticide Science 53 52–70 10.1002/(SICI)1096-9063(199805)53:1<52::AID-PS750>3.0.CO;2-Y.3.0.CO;2-Y>CrossRefGoogle Scholar
Ukrainzyk, L. and Rashid, N., (1995) Irreversible sorption of nicosulfuron on clay minerals Journal of Agricultural and Food Chemistry 43 855–857 10.1021/jf00052a001.CrossRefGoogle Scholar
Ukrainzyk, L. and Ajwa, H.A., (1996) Primisulfuron sorption on minerals and soils Soil Science Society of America Journal 60 460–467 10.2136/sssaj1996.03615995006000020017x.CrossRefGoogle Scholar