Hostname: page-component-cd9895bd7-hc48f Total loading time: 0 Render date: 2024-12-26T08:11:48.047Z Has data issue: false hasContentIssue false
  • English
  • Français

Synthesis of linear alkylbenzene sulphonate intercalated iron(II) iron(III) hydroxide sulphate (green rust) and adsorption of carbon tetrachloride

Published online by Cambridge University Press:  09 July 2018

K. B. Ayala-Luis ,
D. K. Kaldor ,
C. Bender Koch ,
B. W. Strobel  and
H. C. B. Hansen
K. B. Ayala-Luis*
Affiliation:
Department of Natural Sciences, Faculty of Life Sciences, University of Copenhagen, Thorvaldsensvej 40, DK-1871 Frederiksberg C, Denmark
D. K. Kaldor
Affiliation:
Department of Natural Sciences, Faculty of Life Sciences, University of Copenhagen, Thorvaldsensvej 40, DK-1871 Frederiksberg C, Denmark
C. Bender Koch
Affiliation:
Department of Natural Sciences, Faculty of Life Sciences, University of Copenhagen, Thorvaldsensvej 40, DK-1871 Frederiksberg C, Denmark
B. W. Strobel
Affiliation:
Department of Natural Sciences, Faculty of Life Sciences, University of Copenhagen, Thorvaldsensvej 40, DK-1871 Frederiksberg C, Denmark
H. C. B. Hansen
Affiliation:
Department of Natural Sciences, Faculty of Life Sciences, University of Copenhagen, Thorvaldsensvej 40, DK-1871 Frederiksberg C, Denmark
*
*E-mail: [email protected]
Get access Rights & Permissions [Opens in a new window]

Abstract

Green rusts, GRs, can act as both sorbents and reductants towards selected pollutants. Organo-GRs are expected to combine these properties with a high affinity for hydrophobic substances. A novel organo-GR, GRLAS, was synthesized by incorporating a mixture of linear alkylbenzenesulphonates (LAS) into the interlayer space of synthetic sulphate green rust, GRSO4 . Mössbauer analysis of GRLAS indicates that the structure of the organo-GR is very similar to that of the initial GRSO4 with regard to the FeII/FeIII ratio and local coordination of Fe atoms. X-ray diffraction demonstrates that the GRLAS formed was well ordered, although a mixture of surfactant was used for intercalation. The basal spacings of the GRLAS and the kinetics of the ion-exchange process were dependent on the initial surfactant loading; basal spacings of ~2.85 nm were obtained at LAS solution concentrations >10 mM. The ratio LASadsorbed/SO42–desorbed significantly exceeded the stoichiometric ratio of 2 during the initial part of the ion-exchange process (t = 5 h). However, this ratio was reached progressively with time. GRSO4 preferentially sorbed LAS homologues with long alkyl chains over short ones. Carbon tetrachloride was successfully adsorbed into GRLAS. The adsorption isotherm was linear with a distribution coefficient, Kd, of 505±19 litre kg–1.

Keywords

green rustphyllosilicateslayered double hydroxidesreactivitycarbonatessynthesisorganic contaminants
Type
Research Article
Information
Clay Minerals , Volume 42 , Issue 3 , September 2007 , pp. 307 - 317
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2007

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Abdelmoula, M., Trolard, F., Bourrié, G. & Génin, J.M.R. (1998) Evidence for the Fe(II)-Fe(III) green rust ‘fougerite’ mineral occurrence in a hydromorphic soil and its transformation with depth. Hyperfine Interactions, 112, 235–238.Google Scholar
Allmann, R. (1968) The crystal structure of pyroaurite. Acta Crystallographica, 24, 972–977.CrossRefGoogle Scholar
Barriga, C., Gaitán, M., Pavlovic, I., Ulibarri, M.A., Hermosín, M.C. & Cornejo, J. (2002) Hydrotalcites as sorbent for 2,4,6-trinitrophenol: influence of the layer composition and interlayer anion. Journal of Materials Chemistry, 12, 1027–1034.Google Scholar
Bergaya, F. & Lagaly, G. (2001) Surface modification of clay minerals. Applied Clay Science, 19, 1–3.CrossRefGoogle Scholar
Bernal, J.D., Dasgupta, D.R. & Mackay, A.L. (1959) The oxides and hydroxides of iron and their structural inter-relationships. Clay Minerals Bulletin, 4, 15–30.Google Scholar
Bojemueller, E., Nennemann, A. & Lagaly, G. (2001) Enhanced pesticide adsorption by thermally modified bentonites. Applied Clay Science, 18, 277–284.CrossRefGoogle Scholar
Carrado, K.A. & Kostapapas, A. (1988) Layered double hydroxides (LDHs). Solid State Ionics, 26, 77–86.Google Scholar
Cases, J.M., Villiéras, F., Michot, L.J. & Bersillon, J.L. (2002) Long chain ionic surfactants: the understanding of absorption mechanisms from the resolution of absorption isotherms. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 205, 85–89.Google Scholar
Chiou, C.T., Peters, L.J. & Freed, V.H. (1979) Physical concept of soil-water equilibria for non-ionic organic-compounds. Science, 206, 831–832.Google Scholar
Clearfield, A., Kieke, M., Kwan, J., Colon, J.L. & Wang, R.C. (1991) Intercalation of dodecyl-sulfate into layered double hydroxides. Journal of Inclusion Phenomena and Molecular Recognition in Chemistry, 11, 361–378.CrossRefGoogle Scholar
Deitsch, J.J., Smith, J.A., Arnold, M.B. & Bolus, J. (1998) Sorption and desorption rates of carbon tetrachloride and 1,2-dichloorobenzene to three organobentonites and a natural peat soil. Environmental Science and Technology, 32, 3169–3177.Google Scholar
Dékány, I. & Haraszti, T. (1997) Layered solid particles as self-assembled films. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 123, 391–401.Google Scholar
Domka, L. (1993) Surface modified precipitated calcium carbonates at a high-degree of dispersion. Colloid and Polymer Science, 271, 1091–1099.Google Scholar
Duan, X. & Evans, D.G. (2006) Layered Double Hydroxides, pp. 195–217. Springer, Berlin, Heidelberg.Google Scholar
El-Nahhal, Y., Nir, S., Serban, C., Rabinovitz, O. & Rubin, B. (2001) Organo-clay formulation of acetochlor for reduced movement in soil. Journal of Agricultural and Food Chemistry, 49, 5364–5371.Google Scholar
Erbs, M., Hansen, H.C.B. & Olsen, C.E. (1999) Reductive dechlorination of carbon tetrachloride using iron(II) iron(III) hydroxide sulfate (green rust). Environmental Science and Technology, 33, 307–311.Google Scholar
Esumi, K. & Yamamoto, S. (1998) Adsorption of sodium dodecyl sulfate on hydrotalcite and adsolubilization of 2-naphthol. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 137, 385–388.CrossRefGoogle Scholar
Fadrus, H. & Maly, J. (1975) Suppression of iron(III) interference in determination of iron(II) in water by 1,10-phenanthroline method. Analyst, 100, 549–554.Google Scholar
Génin, J.R., Refait, P., Bourrié, G., Abdelmoula, M. & Trolard, F. (2001) Structure and stability of Fe(II)- Fe(III) green rust “fougerite” mineral and its potential for reducing pollutants in soil solutions. Applied Geochemistry, 16, 559–570.CrossRefGoogle Scholar
Gitipour, S., Bowers, M.T., Huff, W. & Bodocsi, A. (1997) The efficiency of modified bentonite clays for removal of aromatic organics from oily liquid wastes. Spill Science & Technology Bulletin, 4, 155–164.Google Scholar
Hamby, D.M. (1996) Site remediation techniques supporting environmental restoration activities - A review. Science of the Total Environment, 191, 203–224.CrossRefGoogle Scholar
Hansen, H.C.B. (1989) Composition, stabilization, and light absorption of Fe(II)Fe(III) hydroxy carbonate (“Green rust”). Clay Minerals, 24, 663–669.Google Scholar
Hansen, H.C.B. & Koch, C.B. (1997) A comparison of nitrate reduction by carbonate and sulphate forms of green rust. Pp. 295–302 in: Clays for our Future (Kodama, H., Mermut, A.R. & Terrance, J.K., editors). Mineralogical Association of Canada.Google Scholar
Hansen, H.C.B., Borggaard, O.K. & Sørensen, J. (1994) Evaluation of the free energy of formation of Fe(II)- Fe(III) hydroxy-sulphate (green rust) and its reduction of nitrate. Geochimica et Cosmochimica Acta, 58, 2599–2608.CrossRefGoogle Scholar
Hansen, H.C.B., Koch, C.B., Krogh, H.N., Borggaard, O.K. & Sørensen, J. (1996) Abiotic nitrate reduction to ammonium: key role of green rust. Environmental Science and Technology, 30, 2053–2056.CrossRefGoogle Scholar
Koch, C.B. (1998) Structures and properties of anionic clay minerals. Hyperfine Interactions, 117, 131–157.Google Scholar
Koch, C.B. & Hansen, H.C.B. (1997) Reduction of nitrate to ammonium by sulphate green rust. Advances in GeoEcology, 30, 373–393.Google Scholar
Lagaly, G. (1979) Crystalline silicic acids and their interface reactions. Advances in Colloid and Interface Science, 11, 105–148.Google Scholar
Lagaly, G. & Dékany, I. (2005) Adsorption on hydrophobized surfaces: Clusters and self organization. Advances in Colloid and Interface Science, 114-115, 189-204.Google Scholar
Lee, W. & Batchelor, B. (2002) Abiotic reductive dechlorination of chlorinated ethylenes by ironbearing soil minerals. 2. Green rust. Environmental Science and Technology, 36, 5348–5354.Google Scholar
Legrand, L., Figuigui, A.E., Mercier, F. & Chausse, A. (2004) Reduction of aqueous chromate by Fe(II)/Fe(III) carbonate green rust: kinetic and mechanistic studies. Environmental Science and Technology, 38, 4587–4595.Google Scholar
McLeod, N. (2001) Chemical immobilisation of chromium wastes using modified smectite clays (Eclays). Environmental Geochemistry and Health, 23, 273–279.Google Scholar
Meyn, M., Beneke, K. & Lagaly, G. (1990) Anion-exchange reactions of layered double hydroxides. Inorganic Chemistry, 29, 5201–5207.Google Scholar
Miyata, S. (1983) Anion-exchange properties of hydrotalcite-like compounds. Clays and Clay Minerals, 31, 305–311.CrossRefGoogle Scholar
Nennemann, A., Mishael, Y., Nir, S., Rubin, B., Polubesova, T., Bergaya, F., van Damme, H. & Lagaly, G. (2001) Clay-based formulations of metolachlor with reduced leaching. Applied Clay Science, 18, 265–275.Google Scholar
Newman, S.P. & Jones, W. (1998) Synthesis, characterization and applications of layered double hydroxides containing organic guests. New Journal of Chemistry, 22, 105–115.Google Scholar
O’Loughlin, E.J. & Burris, D.R. (2004) Reduction of halogenated ethanes by green rust. Environmental Toxicology and Chemistry, 23, 41–48.CrossRefGoogle ScholarPubMed
Park, M., Lee, C., Lee, Eu., Choy, J., Kim, J. & Choi, J. (2004) Layered double hydroxides as potential solid base for beneficial remediation of endosulfan-contaminated soils. Journal of Physics and Chemistry of Solids, 65, 513–516.Google Scholar
Pavan, P.C., Gomes, G.A. & Barros, J. (1998) Adsorption of sodium dodecyl sulfate on layered double hydroxides. Microporous and Mesoporous Materials, 21, 659–665.CrossRefGoogle Scholar
Pavan, P.C., Crepaldi, E.L. & Valim, J.B. (2000) Sorption of anionic surfactants on layered double hydroxides. Journal of Colloid and Interface Science, 229, 346–352.CrossRefGoogle ScholarPubMed
Rives, V. (2001) Layered Double Hydroxides: Present and Future, pp. 251–281, 420-421. Nova Science, New York.Google Scholar
Sabatini, D.A., Knox, R.C., Harwell, J.H. & Wu, B. (2000) Integrated design of surfactant enhanced DNAPL remediation: efficient supersolubilization and gradient systems. Journal of Contaminant Hydrology, 45, 99–121.Google Scholar
Somasundaran, P. & Fuersten, D.W. (1966) Mechanisms of alkyl sulfonate adsorption at alumina-water interface. Journal of Physical Chemistry, 70, 90–96.Google Scholar
Taylor, H.F.W. (1973) Crystal structures of some double hydroxide minerals. Mineralogical Magazine, 39, 377–389.Google Scholar
Vogt, C., Heinig, K., Langer, B., Mattusch, J. & Werner, G. (1995) Determination of linear alkylbenzenesulfonates by high-performance liquid-chromatography and capillary zone electrophoresis. Fresenius’ Journal of Analytical Chemistry, 352, 508–514.Google Scholar
Wang, B., Zhang, H., Evans, D.G. & Duan, X. (2005) Surface modification of layered double hydroxides and incorporation of hydrophobic organic compounds. Materials Chemistry and Physics, 92, 190–196.Google Scholar
Westergaard, B., Hansen, H.C.B. & Borggaard, O.K. (1998) Determination of anions in soil solutions by capillary electrophoresis. Analyst, 123, 721–724.Google Scholar
Yaron-Marcovich, D., Nir, S. & Chen, Y. (2004) Fluridone adsorption-desorption on organo-clays. Applied Clay Science, 24, 167–175.Google Scholar
You, Y., Zhao, H. & Vance, G.F. (2002) Surfactantenhanced adsorption of organic compounds by layered double hydroxides. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 205, 161–172.Google Scholar
Zhao, H. & Nagy, K.L. (2004) Dodecyl sulfate-hydrotalcite nanocomposites for trapping chlorinated organic pollutants in water. Journal of Colloid and Interface Science, 274, 613–624.Google Scholar