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Synthesis of impregnated bentonite using ultrasound waves for application in the Fenton process

Published online by Cambridge University Press:  14 June 2018

M. Bečelić-Tomin ,
A. Kulić ,
Đ. Kerkez ,
D. Tomašević Pilipović ,
V. Pešić  and
B. Dalmacija
M. Bečelić-Tomin
Affiliation:
Faculty of Science, Department of Chemistry, Biochemistry and Environmental Protection, 21000 Novi Sad, Serbia
A. Kulić*
Affiliation:
Faculty of Science, Department of Chemistry, Biochemistry and Environmental Protection, 21000 Novi Sad, Serbia
Đ. Kerkez
Affiliation:
Faculty of Science, Department of Chemistry, Biochemistry and Environmental Protection, 21000 Novi Sad, Serbia
D. Tomašević Pilipović
Affiliation:
Faculty of Science, Department of Chemistry, Biochemistry and Environmental Protection, 21000 Novi Sad, Serbia
V. Pešić
Affiliation:
Faculty of Science, Department of Chemistry, Biochemistry and Environmental Protection, 21000 Novi Sad, Serbia
B. Dalmacija
Affiliation:
Faculty of Science, Department of Chemistry, Biochemistry and Environmental Protection, 21000 Novi Sad, Serbia
*
*E-mail: [email protected]
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Abstract

The use of clays as industrial catalysts requires optimization of modification methods during their preparation. The objective of this paper was to improve the traditional method of bentonite impregnation using ultrasound. For this purpose, three series of samples with Fe3+/clay molar ratios of 0.6–11 mmol/g were prepared, which differed in terms of preparation procedure. The first batch of samples was subjected to the conventional method of impregnation, where total synthesis of catalysts took 4 h. The other two series of samples were prepared with impregnation improved by ultrasound: preparation of Fe-polycation (5 min) and then its incorporation with a clay suspension for 5 and 10 min. The effect of clay preparation method on the catalyst stability and efficiency in a heterogeneous Fenton process was studied on aqueous solutions of synthetic Reactive Blue 4 dye. The catalysts prepared by the conventional method and the improved ultrasound method achieved high efficacy (91–97%, respectively), but their stability was different in the Fenton process. The catalysts prepared using ultrasound for 10 min exhibited greatest stability in the Fenton process. The catalysts synthesized with different Fe loadings displayed an increase in specific surface area and mesoporosity. Samples prepared by the improved impregnation method are comparable in terms of their characteristics with their counterparts prepared by the conventional method. It is thus possible to reduce the time taken by traditional catalyst synthesis by using optimized exposure time to ultrasonic waves.

Keywords

Na-bentoniteimpregnationFeultrasoundFentondecolourization
Type
Article
Information
Clay Minerals , Volume 53 , Issue 2 , June 2018 , pp. 203 - 212
Copyright
Copyright © Mineralogical Society of Great Britain and Ireland 2018 

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Footnotes

This paper was presented during the session: “ES-02: Environmental applications of clay minerals” of the International Clay Conference 2017.

Guest Associate Editor: Claudio Camesselle

References

REFERENCES

Acisli, O., Khataee, A., Darvishi, R., Soltani, C. & Karaca, S. (2017) Ultrasound-assisted Fenton process using siderite nanoparticles prepared via planetary ball milling for removal of reactive yellow 81 in aqueous phase. Ultrasonics Sonochemistry, 35, 210–218.Google Scholar
Alothman, Z.A. (2012) A review: Fundamental aspects of silicate mesoporous materials. Materials, 5, 2874–2902.Google Scholar
Ayodele, O.B. & Togunwa, O.S. (2014) Catalytic activity of copper modified bentonite supported ferrioxalate on the aqueous degradation and kinetics of mineralization of Direct Blue 71, Acid Green 25 and Reactive Blue 4 in photo-Fenton process. Applied Catalysis A: General, 470, 285–293.Google Scholar
Basturk, E. & Karatas, M. (2014) Advanced oxidation of Reactive Blue 181 solution: a comparison. Ultrasonics Sonochemistry, 21(5), 1881–1885.Google Scholar
Bounab, L., Draoui, K., Ahrouch, M., Hadri, M., Bouchta, D. & Barhoun, A. (2017) An effective functionalized Moroccan bentonite: Application for a green remediation of m-cresol. Journal of Materials and Environmental Sciences, 8, 244–256.Google Scholar
Caglar, B., Cubuk, O., Demir, E., Coldur, F., Catir, M., Topcu, C. & Tabak, A. (2015) Characterization of AlFe-pillared Unye bentonite: A study of the surface acidity and catalytic property. Journal of Molecular Structure, 1089, 59–65.Google Scholar
Dandia, A., Bhati, D.S., Jain, A.K. & Sharma, G.N. (2011) Ultrasound promoted clay catalyzed efficient and one pot synthesis of substituted oxindoles. Ultrasonics Sonochemistry, 18(5), 1143–1147.Google Scholar
Darvishi, Z. & Morsali, A. (2011) Synthesis and characterization of nano-bentonite by sonochemical method. Ultrasonics Sonochemistry, 18, 238–242.Google Scholar
Dhahri, M., Muñoz, M.A., Yeste, M.P., Cauqui, M.A. & Frini-Srasra, N. (2016) Preparation of manganese-impregnated alumina-pillared bentonite, characterization and catalytic oxidation of CO. Reaction Kinetics, Mechanisms and Catalysis, 118(2), 655–668.Google Scholar
Forss, J. & Welander, U. (2011) Biodegradation of azo and anthraquinone dyes in continuous systems. International Biodeterioration & Biodegradation, 65, 227–237.Google Scholar
Hajjaji, W., Ganiyu, S.O., Tobaldi, D.M., Andrejkovičová, S., Pullar, R.C., Rocha, F. & Labrincha, J.A. (2013) Natural Portuguese clay materials and derived TiO2-containing composites used for decoloring methylene blue (MB) and orange II (OII) solutions. Applied Clay Science, 83–84, 91–98.Google Scholar
Hajjaji, W., Andrejkovičová, S., Pullar, R.C., Tobaldi, D.M., Lopez-Galindo, A., Jammousi, F., Rocha, F. & Labrincha, J.A. (2016) Effective removal of anionic and cationic dyes by kaolinite and TiO2/kaolinite composites. Clay Minerals, 51, 19–27.Google Scholar
Hou, M.F., Ma, C.X., Zhang, W.D., Tang, X.Y., Fan, Y.N. & Wan, H.F. (2011) Removal of rhodamine B using iron-pillared bentonite. Journal of Hazardous Materials, 186, 1118–1123.Google Scholar
Idrissi, M., Miyah, Y., Benjelloun, Y. & Chaouch, M. (2016) Degradation of crystal violet by heterogeneous Fenton-like reaction using Fe/Clay catalyst with H2O2. Journal of Materials and Environmental Science, 7(1), 50–58.Google Scholar
Iurascu, B., Siminiceanu, I., Vione, D., Vicente, M.A. & Gil, A. (2009) Phenol degradation in water through a heterogeneous photo-Fenton process catalyzed by Fe-treated laponite. Water Research, 43, 1313–1322.Google Scholar
Kerkez, Đ., Bečelić-Tomin, M., Dalmacija, B., Agbaba, J., Tomašević-Pilipović, D., Slijepčević, N. & Kulić, A. (2015) Primena “zelenih” katalizatora u Fenton procesu razgradnje organskih molekula u vodi. Voda i sanitarna tehnika, 3–4/2015, 33–40.Google Scholar
Khatri, A., Peerzada, M.H., Mohsin, M. & White, M. (2015) A review on developments in dyeing cotton fabrics with reactive dyes for reducing effluent pollution. Journal of Cleaner Production, 87, 50–57.Google Scholar
Kulić, A., Kerkez, Đ., Bečelić-Tomin, M., Dalmacija, B. & Pucar, G. (2016) Ispitivanje uticaja procesnih parametara na obezbojavanje rastvora reaktivne boje pomoću Fenton procesa. Voda i sanitarna tehnika, 1/2016, 47–52.Google Scholar
Monteagudo, J.M., Durán, A., Aguirre, M. & San Martín, I. (2010) Photodegradation of Reactive Blue 4 solutions under ferrioxalate-assisted UV/solar photo-Fenton system with continuous addition of H2O2 and air injection. Chemical Engineering Journal, 162, 702–709.Google Scholar
Nidheesh, P.V. (2015) Heterogeneous Fenton catalysts for the abatement of organic pollutants from aqueous solution: A review. RCS Advances, 5, 40552–40577.Google Scholar
Nogueira, F.G.E., Lopes, J.H., Silva, A.C., Lago, R.M., Fabris, J.D. & Oliveira, L.C.A. (2011) Catalysts based on clay and iron oxide for oxidation of toluene. Applied Clay Science, 51, 385–389.Google Scholar
Olaya, A., Moreno, S. & Molina, R. (2009) Synthesis of pillared clays with Al13-Fe and Al13-Fe-Ce polymers in solid state assisted by microwave and ultrasound: Characterization and catalytic activity. Applied Catalysis A – General, 370, 7–15.Google Scholar
Pereira, M.C., Oliveira, L.C.A. & Murad, E. (2012) Iron oxide catalysts: Fenton and Fenton-like reactions – a review. Clay Minerals, 47, 285–302.Google Scholar
Pérez, A., Centeno, M.A., Odriozola, J.A., Molina, R. & Moreno, S. (2008) The effect of ultrasound in the synthesis of clays used as catalysts in oxidation reactions. Catalysis Today, 133–135, 526–529.Google Scholar
Ramirez, J.H., Costa, C.A., Madeira, L.M., Mata, G., Vicente, M.A., Rojas-Cervantes, M.L., López-Peinado, A.J. & Martín-Aranda, R.M. (2007) Fenton-like oxidation of Orange II solutions using heterogeneous catalysts based on saponite clay. Applied Catalysis B: Environmental, 71, 44–56.Google Scholar
Sanabria, N.R., Molina, R. & Moreno, S. (2012) Development of pillared clays for wet hydrogen peroxide oxidation of phenol and its application in the post-treatment of coffee wastewater. International Journal of Photoenergy, Article ID 864104.Google Scholar
Siddique, M., Farooq, R. & Price, G.J. (2014) Synergistic effects of combining ultrasound with the Fenton process in the degradation of Reactive Blue 19. Ultrasonics Sonochemistry, 21(3), 1206–1212.Google Scholar
Silva, R.G. & Andrade, A.R. (2016) Degradation of the dye Reactive Blue 4 by coupled photo-assisted electrochemistry at DSA-type electrode. Journal of Brazilian Chemical Society, 27, 857–865.Google Scholar
Verma, A.K., Raghukumar, C., Parvatkar, R.R. & Naik, C.G. (2012) A rapid two-step bioremediation of the anthraquinone dye, Reactive Blue 4 by a marine-derived fungus. Water, Air & Soil Pollution, 223, 3499–3509.Google Scholar
Vimonses, V., Jin, B., Chow, C.W.K. & Saint, C. (2009) Enhancing removal efficiency of anionic dye by combination and calcination of clay materials and calcium hydroxide. Journal of Hazardous Materials, 171, 941–947.Google Scholar
Weng, C.H., Lin, Y.T. & Yuan, H.M. (2013) Rapid decoloration of Reactive Black 5 by an advanced Fenton process in conjunction with ultrasound. Separation and Purification Technology, 117, 75–82.Google Scholar
Xue, B., Guo, H., Liu, L. & Chen, M. (2015) Preparation, characterization and catalytic properties of yttrium-zirconium-pillared montmorillonite and their application in supported Ce catalysts. Clay Minerals, 50, 211–219.Google Scholar
Yilmaz, G. (2011) The effects of temperature on the characteristics of kaolinite and bentonite. Scientific Research and Essays, 6(), 1928–1939.Google Scholar
Yuan, P., Annabi-Bergaya, F., Tao, Q., Fan, M., Liu, Z., Zhu, J., He, J. & Chen, T. (2008) A combined study by XRD, FTIR, TG and HRTEM on the structure of delaminated Fe-intercalated/pillared clay. Journal of Colloid and Interface Science, 324, 142–149.Google Scholar
Zhang, H., Fu, H. & Zhang, D. (2009) Degradation of C.I. Acid Orange 7 by ultrasound enhanced heterogeneous Fenton-like process. Journal of Hazardous Materials, 172(2–3), 654–660.Google Scholar