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Synthesis of an NaY zeolite molecular sieve from a kaolin/dimethyl sulfoxide intercalation composite

Published online by Cambridge University Press:  11 June 2021

Shu-Qin Zheng ,
Ou Chen ,
Si-Cheng Liu ,
An Li ,
Li-Jun Li ,
Yong-Bing Yuan  and
Ceng Zhang
Shu-Qin Zheng*
Affiliation:
Department of Chemistry and Chemical Engineering, Hunan Institute of Science and Technology, Yueyang414006, Hunan, China Hunan Province Key Laboratory of Speciality Petrochemicals Catalysis and Separation, Yueyang414006, Hunan, China
Ou Chen
Affiliation:
Department of Chemistry and Chemical Engineering, Hunan Institute of Science and Technology, Yueyang414006, Hunan, China
Si-Cheng Liu
Affiliation:
Department of Chemistry and Chemical Engineering, Hunan Institute of Science and Technology, Yueyang414006, Hunan, China
An Li
Affiliation:
Department of Chemistry and Chemical Engineering, Hunan Institute of Science and Technology, Yueyang414006, Hunan, China Hunan Province Key Laboratory of Speciality Petrochemicals Catalysis and Separation, Yueyang414006, Hunan, China
Li-Jun Li
Affiliation:
Department of Chemistry and Chemical Engineering, Hunan Institute of Science and Technology, Yueyang414006, Hunan, China Hunan Province Key Laboratory of Speciality Petrochemicals Catalysis and Separation, Yueyang414006, Hunan, China
Yong-Bing Yuan
Affiliation:
Department of Chemistry and Chemical Engineering, Hunan Institute of Science and Technology, Yueyang414006, Hunan, China Hunan Province Key Laboratory of Speciality Petrochemicals Catalysis and Separation, Yueyang414006, Hunan, China
Ceng Zhang
Affiliation:
Department of Chemistry and Chemical Engineering, Hunan Institute of Science and Technology, Yueyang414006, Hunan, China Hunan Province Key Laboratory of Speciality Petrochemicals Catalysis and Separation, Yueyang414006, Hunan, China
*
*Email: [email protected]
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Abstract

NaY zeolite was synthesized from kaolin/dimethyl sulfoxide (DMSO) intercalation composites using an in situ crystallization technique. The effects of the intercalation ratios and the amounts of the kaolin/DMSO intercalation composite on the synthesis of an NaY zeolite molecular sieve were studied. The samples were characterized by X-ray diffraction, Fourier-transform infrared spectroscopy, differential thermal analysis, N2 adsorption–desorption and scanning electron microscopy. In the in situ synthesis system, when the kaolin/DMSO intercalation composite was added, pure NaY zeolite was formed. By increasing the amount of kaolin/DMSO intercalation composite added, the crystallinity of the samples increased, and after reaching the maximum amount of kaolin/DMSO intercalation composite added, the crystallinity decreased with further increases of the amount of kaolin/DMSO intercalation composite added. To higher intercalation ratio, the crystallinity can be greatly improved at the lower addition content. At an intercalation ratio of 84%, the added amount of kaolin/DMSO intercalation composite was 2.5% and the crystallinity of the NaY zeolite molecular sieve reached a maximum value of 45%. At intercalation ratios of 55% and 22%, the amount of kaolin/DMSO intercalation composite added was 15% and the crystallinities of the NaY zeolite molecular sieves were 44% and 47%, respectively. The NaY zeolite has good thermal stability and a particle diameter of ~0.5 μm. The Brunauer–Emmett–Teller (BET) specific surface area and pore volume of the sample were 519 m2 g–1 and 0.355 cm3 g–1, respectively.

Keywords

DMSOin situ techniqueintercalation compositekaolinNaY zeolite
Type
Article
Information
Clay Minerals , Volume 56 , Issue 1 , March 2021 , pp. 28 - 36
Copyright
Copyright © The Author(s), 2021. Published by Cambridge University Press on behalf of The Mineralogical Society of Great Britain and Ireland

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Footnotes

Associate Editor: Saverio Fiore

References

Adams, J.M. (1978) Differential scanning calorimetric study of the kaolinite: N-methylformamide intercalate. Clay and Clay Minerals, 26, 169–172.CrossRefGoogle Scholar
Castrillo, P.D., Olmos, D. & González-Benito, J. (2015) Kinetic study of the intercalation process of dimethylsulfoxide in kaolinite. International Journal of Mineral Processing, 144, 70–74.CrossRefGoogle Scholar
Chen, N.Y. & Garwood, W.E. (1986) Industrial application of shape-selective catalysis. Catalysis Reviews – Science and Engineering, 28, 185–264.CrossRefGoogle Scholar
Chen, Y., Han, D., Zhang, Q. & Cui, H. (2020) In-situ synthesis of hierarchical lamellar ZSM-5 zeolite with enhanced MTP catalytic performance by a facile seed-assisted method. Journal of Porous Materials, 27, 1265–1275.CrossRefGoogle Scholar
Cheng, H., Hou, X., Liu, Q., Li, X, & Frost, R.L. (2015) New insights into the molecular structure of kaolinite–methanol intercalation complexes. Applied Clay Science, 109–110, 55–63.CrossRefGoogle Scholar
Cheng, H., Liu, Q., Cui, X., Zhang, Q., Zhang, Z. & Frost, R.L. (2012) The thermal behavior of kaolinite intercalation complexes-a review, Thermochim Acta, 545, 1–13.CrossRefGoogle Scholar
Cheng, H., Liu, Q., Xu, P. & Hao, R. (2018) A comparison of molecular structure and deintercalation kinetics of kaolinite/quaternary ammonium salt and alkylamine intercalation compounds. Journal of Solid State Chemistry, 268, 36–44.CrossRefGoogle Scholar
Cheng, H., Liu, Q., Yang, J., Du, X. & Frost, R.L. (2010) Influencing factors on kaolinite potassium acetate intercalation complexes. Applied Clay Science, 50, 476–480.CrossRefGoogle Scholar
Frost, R.L., Kristof, J. & Paroz, G.N. (1998) Modification of the kaolinite hydroxyl surfaces through intercalation with potassium acetate under pressure. Journal of Colloid and Interface Science, 208, 478–486.CrossRefGoogle ScholarPubMed
Harding, R.H., Peters, A.W. & Nee, J.R.D. (2001) New developments in FCC catalyst technology. Applied Catalysis A: General, 221, 389–396.CrossRefGoogle Scholar
Itagaki, T., Komori, Y., Sugahara, Y. & Kuroda, K. (2001) Synthesis of a kaolinite–poly(β-alanine) intercalation compound, Journal of Materials Chemistry, 11, 3291–3295.CrossRefGoogle Scholar
Kovács, A. & Makó, É. (2016) Cooling as the key parameter in formation of kaolinite–ammonium acetate and halloysite–ammonium acetate complexes using homogenization method. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 508, 70–78.CrossRefGoogle Scholar
Kristóf, T., Sarkadi, Zs., Ható, Z. & Rutkai, G. (2018) Simulation study of intercalation complexes of kaolinite with simple amides as primary intercalation reagents. Computation Materials Science, 143, 118–125.CrossRefGoogle Scholar
Kuroda, K., Hiraguri, K., Komori, Y., Sugahara, Y., Kuroda, K., Komori, Y. et al. (1999) An acentric arrangement of p-nitroaniline molecules between the layers of kaolinite. Chemical Communications, 22, 2253–2254.CrossRefGoogle Scholar
Ledoux, R.L. & White, J.L. (1966) Infrared studies of hydrogen bonding interaction between kaolinite surfaces and intercalated potassium acetate, hydrazine, formamide, and urea. Journal of Colloid and Interface Science, 21, 127–152.CrossRefGoogle Scholar
Li, X., Cui, X., Wang, S., Wang, D., Li, K., Liu, Q. & Komareni, S. (2017) Methoxy-grafted kaolinite preparation by intercalation of methanol: mechanism of its structural variability. Applied Clay Science, 137, 241–248.CrossRefGoogle Scholar
Li, Z.J., Zhang, X.R. & Xu, Z. (2007) Novel method for preparation of kaolinite intercalation composite. Materials Technology, 22, 205–208.CrossRefGoogle Scholar
Makó, É., Kovács, A., Ható, Z., Zsirka, B. & Kristóf, T. (2014) Characterization of kaoliniteammonium acetate complexes prepared by one-step homogenization method. Journal of Colloid and Interface Science, 431, 125–131.CrossRefGoogle ScholarPubMed
Makó, É., Kovács, A., Katona, R. & Kristóf, T. (2016) Characterization of kaolinite–cetyltrimethylammonium chloride intercalation complex synthesized through eco-friend kaolinite–urea pre-intercalation complex. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 508, 265–273.CrossRefGoogle Scholar
Matsumura, A., Komori, Y., Itagaki, T., Sugahara, Y. & Kuroda, K. (2001) Preparation of a kaolinite–nylon 6 intercalation compound. Bulletin of the Chemical Society of Japan, 74, 1153–1158.CrossRefGoogle Scholar
Matusik, J. & Kłapyta, Z. (2013) Characterization of kaolinite intercalation compounds with benzylalkylammonium chlorides using XRD, TGA/DTA and CHNS elemental analysis. Applied Clay Science, 83–84, 433–440.CrossRefGoogle Scholar
Olejnik, S., Aylmore, L.A.G., Posner, A.M. & Quirk, J.P. (1968). Infrared spectra of kaolin mineral–dimethyl sulfoxide complexes. Journal of Physical Chemistry, 72, 241–249.CrossRefGoogle Scholar
Qiu, B., Jiang, F., Lu, W., Yan, B., Li, W.-C., Zhao, Z.-C. & Lu, A.-H. (2020) Oxidative dehydrogenation of propane using layered borosilicate zeolite as the active and selective catalyst. Journal of Catalysis, 385, 176–182.CrossRefGoogle Scholar
Sang, Y. & Li, H. (2019) Effect of phosphorus and mesopore modification on the HZSM-5 zeolites for n-decane cracking. Journal of Solid State Chemistry, 271, 326–333.CrossRefGoogle Scholar
Tsunematsu, K. & Tateyama, H. (1999) Delamination of urea–kaolinite complex by using intercalation procedures. Journal of the American Ceramic Society, 82, 1589–1591.CrossRefGoogle Scholar
Valaskova, M., Rieder, M., Matejka, V., Capkova, P. & Sliva, A. (2006) Exfoliation/delamination of kaolinite by low-temperature washing of kaolinite–urea intercalates. Applied Clay Science, 35, 108–118.CrossRefGoogle Scholar
Wang, P., Shen, B.J. & Gao, J.S. (2007) Synthesis of MAZ/ZSM-5 composite zeolite and its catalytic performance in FCC gasoline aromatization. Catalysis Communications, 8, 1161–1166.CrossRefGoogle Scholar
Xiong, K., Lu, C., Wang, Z. & Gao, X. (2015) Kinetic study of catalytic cracking of heavy oil over an in-situ crystallized FCC catalyst. Fuel, 142, 65–72.CrossRefGoogle Scholar
Yue, Y., Guo, X., Liu, T., Liu, H., Wang, T., Yuan, P. et al. (2020) Template free synthesis of hierarchical porous zeolite Beta with natural kaolin clay as alumina source. Microporous and Mesoporous Materials, 293, 109772.CrossRefGoogle Scholar
Zhang, Y., Kang, W., Han, H., Wang, H., Chen, Y., Gong, X. et al. (2019) In-situ synthesis of NaP zeolite doped with transition metals using fly ash. Journal of the American Ceramic Society, 102, 7665–7677.CrossRefGoogle Scholar