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Study of the catalytic activity of Al-Fe pillared clays in the Baeyer–Villiger oxidation†

Published online by Cambridge University Press:  09 July 2018

L. S. Belaroui  and
A. Bengueddach
L. S. Belaroui*
Affiliation:
Département de Pharmacie, Faculté de Médecine, Université d'Oran, BP 1510 Oran, El M'Naouer, Algeria Laboratoire de Chimie des Matériaux (LCM), Faculté des Sciences, Université d'Oran, BP 1524Oran, El M'Naouer, Algeria
A. Bengueddach
Affiliation:
Laboratoire de Chimie des Matériaux (LCM), Faculté des Sciences, Université d'Oran, BP 1524Oran, El M'Naouer, Algeria
*
*E-mail: [email protected]
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Abstract

Three types of AlFePILCs pillared clays have been prepared from Algerian clay precursors. They have been characterized and tested in the Baeyer–Villiger oxidation of cyclohexanone to caprolactone using benzaldehyde and oxygen as oxidant at room temperature. The structural and textural properties of the catalyst have been determined by X-ray diffraction, nitrogen adsorption-desorption isotherms and Mössbauer spectroscopy.

The different activities of the clays have been related to their Fe contents and accessible surface areas. The induction period observed before the reaction started has been attributed to the dissolution of a portion of the Fe3+ cations, mediated by either the perbenzoic acid intermediate or the benzoic acid co-product. The reaction was indeed catalysed by a few ppm of dissolved iron cations and the catalysis of the Baeyer–Villiger oxidation reaction should mechanistically be considered as homogeneous.

Keywords

Lalithe Algerian clayAl-Fe pillared claysironBaeyer–Villiger oxidationcaprolactonehomogenous catalysis
Type
Research Papers
Information
Clay Minerals , Volume 47 , Issue 2 , June 2012 , pp. 275 - 284
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2012

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Footnotes

†

Presented at the Euroclay 2011 Conference at Antalya, Turkey

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