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Sorption of Congo Red anionic dye on natural hydrotalcite and stichtite: kinetics and equilibrium

Published online by Cambridge University Press:  06 October 2022

Olga V. Nestroinaia ,
Irina G. Ryltsova Open the ORCID record for Irina G. Ryltsova [Opens in a new window] ,
Maksim N. Yaprintsev Open the ORCID record for Maksim N. Yaprintsev [Opens in a new window] ,
Evgeniya Yu. Nakisko ,
Evgeniy S. Seliverstov Open the ORCID record for Evgeniy S. Seliverstov [Opens in a new window]  and
Olga E. Lebedeva Open the ORCID record for Olga E. Lebedeva [Opens in a new window]
Olga V. Nestroinaia
Affiliation:
Belgorod State National Research University, Belgorod, 308015, Russia
Irina G. Ryltsova
Affiliation:
Belgorod State National Research University, Belgorod, 308015, Russia
Maksim N. Yaprintsev
Affiliation:
Belgorod State National Research University, Belgorod, 308015, Russia
Evgeniya Yu. Nakisko
Affiliation:
Belgorod State National Research University, Belgorod, 308015, Russia
Evgeniy S. Seliverstov
Affiliation:
Belgorod State National Research University, Belgorod, 308015, Russia
Olga E. Lebedeva*
Affiliation:
Belgorod State National Research University, Belgorod, 308015, Russia
*
*Email: [email protected]
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Abstract

The sorption properties of two layered minerals of the hydrotalcite supergroup – hydrotalcite and stichtite – were investigated with the aim of determining their kinetic parameters of sorption and their adsorption isotherm type. Pristine hydrotalcite and stichtite were characterized using X-ray diffraction, Fourier-transform infrared spectroscopy, scanning electron microscopy, energy-dispersive Х-ray analysis and laser diffraction analysis of the particle-size distribution. The ‘memory effect’ of the sorbents was examined after calcination at 650°C. Slight indications of reconstructed hydrotalcite were observed, while the stichtite dehydration–rehydration cycle was irreversible. The hydrotalcite and stichtite were used to remove Congo Red from the aqueous solution. The pseudo-second order kinetic model described the process adequately. Mixed external and internal diffusion was confirmed for both minerals. The sorption of Congo Red on stichtite fits the Langmuir model. Stichtite demonstrated a maximum adsorption capacity of 2.5 mmol g–1 at 35°C. Increasing temperature increased the adsorption rate of Congo Red on stichtite but did not affect the adsorption rate constant for hydrotalcite.

Keywords

Сongo Redhydrotalcitenatural layered double hydroxidesstichtitesorption isothermssorption kinetics
Type
Article
Information
Clay Minerals , Volume 57 , Issue 2 , June 2022 , pp. 105 - 113
Copyright
Copyright © The Author(s), 2022. Published by Cambridge University Press on behalf of The Mineralogical Society of Great Britain and Ireland

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Footnotes

Associate Editor: M. Pospíšil

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