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Removal of Reactive Black 5 from wastewater using natural clinoptilolite modified with apolaccase

Published online by Cambridge University Press:  02 January 2018

Hayrunnisa Nadaroglu ,
Ekrem Kalkan ,
Neslihan Celebi  and
Esen Tasgin
Hayrunnisa Nadaroglu*
Affiliation:
Ataturk University, Erzurum Vocational Training School, 25240 Erzurum, Turkey
Ekrem Kalkan
Affiliation:
Bayburt University, Educational Faculty, 69000 Bayburt, Turkey
Neslihan Celebi
Affiliation:
Ataturk University, Erzurum Vocational Training School, 25240 Erzurum, Turkey
Esen Tasgin
Affiliation:
Ataturk University, Oltu Earth Sciences Faculty, Geological Engineering Department, 25400 Oltu-Erzurum, Turkey
*
*E-mail: [email protected]
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Abstract

In this study, a clinoptilolite modified with apolaccase was used to adsorb Reactive Black 5 (RB5) dye from aqueous solution using the batch procedure. The influences of pH, contact time, temperature and absorbent dosage on the adsorption were investigated. The optimum adsorption was obtained at pH = 6, contact time = 60 min, temperature = 25ºC and adsorbent dosages of 1.62 and 1.59 mg/50 mL per gram of clinoptilolite and of apolaccase-modified clinoptilolite (LMC), respectively). The adsorption experimental data fitted both the Langmuir and Freundlich isotherm models well. In addition, pseudo-first-order and pseudo-second-order kinetics were used to study the kinetics of RB5 dye adsorption onto natural clinoptilolite and LMC. Adsorption appears to follow pseudo-second-order kinetics with a high correlation coefficient. Thermodynamic parameters such as changes in the free energy (ΔG°), enthalpy (ΔH°) and entropy (ΔS°) of adsorption were calculated. The thermodynamic parameters indicate that the adsorption of RB5 dye onto LMC was less spontaneous, feasible and endothermic. The LMC can be used as an alternative low-cost adsorbent for the dye removal from aqueous solutions.

Keywords

Reactive Black 5 dye removalapolaccase-modified clinoptiloliteadsorption isothermsadsorption kinetics
Type
Research Article
Information
Clay Minerals , Volume 50 , Issue 1 , March 2015 , pp. 65 - 76
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2015

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