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Primary aliphatic alcohol-homoionic montmorillonite interactions

Published online by Cambridge University Press:  09 July 2018

W. L. German  and
D. A. Harding
W. L. German
Affiliation:
Ceramics Department, North Staffordshire Polytechnic, College Road, Stoke-on-Trent
D. A. Harding
Affiliation:
Physieal Chemistry Laboratories, Chemistry Department, Imperial College, London S.W.7
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Abstract

Complexes formed by straight chain, primary, aliphatic alcohols from methanol to n-decanol with Ca- and Na-montmorillonite from the liquid and vapour phases, have been investigated by X-ray techniques. Satisfactory complexes are formed more readily by the Ca-mineral and from the liquid phase rather than from the vapour phase. Molecular configurations of the adsorbed molecules are suggested consistent with the experimental data. The importance of cation-dipole interactions for the lower members of the series is stressed.

Type
Research Article
Information
Clay Minerals , Volume 9 , Issue 2 , December 1971 , pp. 167 - 175
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1971

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