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Overview of radionuclide migration experiments in the HADES Underground Research Facility at Mol (Belgium)

Published online by Cambridge University Press:  09 July 2018

M. Aertsens ,
N. Maes ,
L. Van Ravestyn  and
S. Brassinnes
M. Aertsens*
Affiliation:
Expert Group Waste & Disposal, Belgian Nuclear Research Centre, SCK – CEN - Boeretang 200, B-2400 Mol, Belgium
N. Maes
Affiliation:
Expert Group Waste & Disposal, Belgian Nuclear Research Centre, SCK – CEN - Boeretang 200, B-2400 Mol, Belgium
L. Van Ravestyn
Affiliation:
Expert Group Waste & Disposal, Belgian Nuclear Research Centre, SCK – CEN - Boeretang 200, B-2400 Mol, Belgium
S. Brassinnes
Affiliation:
ONDRAF/NIRAS, Kunstlaan 14, B-1210 Brussels, Belgium
*
*E-mail: [email protected]
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Abstract

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In situ migration experiments using different radiotracers have been performed in the HADES Underground Research Facility (URF), built at a depth of 225 m in the Boom Clay formation below the SCK–CEN nuclear site at Mol (Belgium). Small-scale experiments, mimicking laboratory experiments, were carried out with strongly retarded tracers (strontium, caesium, europium, americium and technetium). Contrary to europium, americium and technetium which are subjected to colloid mediated transport, the transport of strontium and caesium can be described by the classic diffusion retardation formalism. For these last two tracers, the transport parameters derived from the in situ experiments can be compared with the laboratory-derived values. For both tracers, the apparent diffusion coefficients measured in the in situ experiments agree well with the laboratory-derived values.

In the large-scale experiments (of the order of metres) performed in the URF, non-retarded or slightly retarded tracers (HTO, iodide and H14CO3–) were used. The migration behaviour of these tracers was predicted based on models applied in performance assessment calculations (classic diffusion retardation) using migration parameter values measured in laboratory experiments. These blind predictions of large-scale experiments agree well in general with the experimental measurements. Fitting the experimental in situ data leads to apparent diffusion coefficients close to those determined by the laboratory experiments. The iodide and H14CO3– data were fitted with a simple analytical expression, and the HTO data were additionally fitted numerically with COMSOL multiphysics, leading to about the same optimal values.

Keywords

in situ experimentsmigrationvalidationapparent diffusion coefficientURLHADESBoom ClayHTOiodideH14CO3–strontiumcaesiumeuropiumamericiumtechnetium
Type
Research Article
Information
Clay Minerals , Volume 48 , Issue 2 , May 2013 , pp. 153 - 166
Creative Commons
Creative Common License - CCCreative Common License - BY
Copyright © The Mineralogical Society of Great Britain and Ireland 2013 This is an Open Access article, distributed under the terms of the Creative Commons Attribution license. (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted re-use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2013

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