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Order-disorder in clay mineral structures

Published online by Cambridge University Press:  09 July 2018

A. Plançon
A. Plançon*
Affiliation:
ISTO, CNRS-Université d'Orléans, 1A rue de la Férollerie, 45071 Orléans, Cedex 2, France
*
*E-mail: [email protected]
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Abstract

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Some recent works dealing with the concept of order-disorder in clay minerals are considered, including those aspects of order-disorder which appeared in the Brindley & Brown (1980) monograph, i.e. disorder in the distribution of cations, disorder in layer stacking, orderdisorder in mixed-layer systems and finite crystal size as a lattice disorder. Heterogeneity of samples and polymorphous transformations are also considered as other types of disorder. Most of these works emphasize that accurate structural characterization can only be obtained if several techniques are combined (e.g. XRD and IR, EXAFS and Mo¨ssbauer spectroscopies, etc.). Another conclusion is that accurate structural determination provides the key to the genesis of clays.

Keywords

orderdisorderphyllosilicatesclay mineralscation distributionheterogeneitymixed layer
Type
Research Article
Information
Clay Minerals , Volume 36 , Issue 1 , March 2001 , pp. 1 - 14
Creative Commons
Creative Common License - CCCreative Common License - BY
Copyright © The Mineralogical Society of Great Britain and Ireland 2001 This is an Open Access article, distributed under the terms of the Creative Commons Attribution license. (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted re-use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2001

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