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Order-disorder in clay mineral structures

Published online by Cambridge University Press:  09 July 2018

A. Plançon
A. Plançon*
Affiliation:
ISTO, CNRS-Université d'Orléans, 1A rue de la Férollerie, 45071 Orléans, Cedex 2, France
*
*E-mail: [email protected]
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Abstract

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Some recent works dealing with the concept of order-disorder in clay minerals are considered, including those aspects of order-disorder which appeared in the Brindley & Brown (1980) monograph, i.e. disorder in the distribution of cations, disorder in layer stacking, orderdisorder in mixed-layer systems and finite crystal size as a lattice disorder. Heterogeneity of samples and polymorphous transformations are also considered as other types of disorder. Most of these works emphasize that accurate structural characterization can only be obtained if several techniques are combined (e.g. XRD and IR, EXAFS and Mo¨ssbauer spectroscopies, etc.). Another conclusion is that accurate structural determination provides the key to the genesis of clays.

Keywords

orderdisorderphyllosilicatesclay mineralscation distributionheterogeneitymixed layer
Type
Research Article
Information
Clay Minerals , Volume 36 , Issue 1 , March 2001 , pp. 1 - 14
Creative Commons
Creative Common License - CCCreative Common License - BY
Copyright © The Mineralogical Society of Great Britain and Ireland 2001 This is an Open Access article, distributed under the terms of the Creative Commons Attribution license. (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted re-use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2001

References

Altaner, S.P. & Ylagan, R.F. (1997) Comparison of structural models of mixed-layer illite/smectite and reaction mechanisms of smectite. Clays Clay Miner. 45, 517–533.CrossRefGoogle Scholar
Amouric, M. & Olives, J. (1998) Transformation mechanisms and interstratification in conversion of smectite to kaolinite: an HRTEM study. Clays Clay Miner. 46, 521–527.CrossRefGoogle Scholar
Bailey, S.W., editor (1988) Hydrous Phyllosilicates (Exclusive of Micas). Reviews in Mineralogy, 19. Mineralogical Society of America, Washington, D.C.CrossRefGoogle Scholar
Bailey, S.W., Banfield, J.F., Barker, W.W. & Katchan, G. (1995) Dozyite, a 1:1 regular interstratification of serpentine and chlorite. Am. Miner. 80, 65–77.Google Scholar
Banfield, J.F. & Bailey, S.W. (1996) Formation of regularly interstratified serpentine-chlorite minerals by tetrahedral inversion in long-period serpentine polytypes. Am. Miner. 81, 79–91.Google Scholar
Banfield, J.F., Bailey, S.W. & Barker, W.W. (1994) Polysomatism, polytypism, microstructures and reaction mechanisms in serpentine and chlorite. Contrib. Mineral. Petrol. 117, 137–150.Google Scholar
Ben Haj Amara, A., Ben Brahim, J., Plançon, A. & Ben Rhaiem, H. (1998) Etude de la structure d’une nacrite hydratée et dehydratée. J. Appl. Crystallogr. 31, 654–662.CrossRefGoogle Scholar
Ben Haj Amara, A., Plançon, A., Ben Brahim, J. & Ben Rhaiem, H. (1999) Intercalation of organic molecules and water in nacrite. P. 63 in: Abst. Conf. Eur. Clay Groups Assoc., Kraków.Google Scholar
Besson, G. & Drits, V.A. (1997a) Refined relationships between chemical composition of dioctahedral fine dispersed mica minerals and their infrared spectra in the OH-stretching region. Part I: Identification of the stretching bands. Clays Clay Miner. 45, 158–169.CrossRefGoogle Scholar
Besson, G. & Drits, V.A. (1997b) Refined relationships between chemical composition of dioctahedral fine dispersed mica minerals and their infrared spectra in the OH-stretching region. Part II: The main factors affecting OH vibration and quantitative analysis. Clays Clay Miner. 45, 170–183.Google Scholar
Bish, D.L. & Chipera, S.J. (1998) Variation of kaolinite defect structure with particle size. Abst. Ann. Meet. Clay Miner. Soc., Cleveland.Google Scholar
Bookin, A.S., Drits, V.A. & Tcherkachin, V.I. (1992) Structural modifications of kaolinite and dickite by intercalation. Izv. Acad. Nauk, Ser. Geol. 4, 106–118.(in Russian).Google Scholar
Brindley, G.W. & Brown, G., editors (1980) Crystal Structures of Clay Minerals and their X-ray Identi fication. Monograph, 5. Minera logical Society, London.Google Scholar
Costanzo, P.M., Giese, R.F. & Lipsicas, M. (1984) Static and dynamic structure water in hydrated kaolinite. I – The static structure. Clays Clay Miner. 32, 549–551.CrossRefGoogle Scholar
Cuadros, J. & Altaner, S.P. (1998) Compositional and structural features of the octahedral sheet in mixedlayer illite/smectites from bentonites. Eur. J. Mineral. 10, 111–124.Google Scholar
Dainyak, L.G., Drits, V.A. & Heifits, L.M. (1992) Computer simulation of cation distribution in dioctahedral 2:1 layer silicates using IR-data: Application to Mössbauer spectroscopy of a glauconite sample. Clays Clay Miner. 40, 470–479.CrossRefGoogle Scholar
Deconinck, J.F. & Chamley, H. (1995) Diversity of smectite origins in Late Cretaceous sediments: Examples of chalks from Northern France. Clay Miner. 30, 365–379.CrossRefGoogle Scholar
Drits, V.A. (1966) Some structural features of layer silicates with long periodicity along c axis. Pp. 35–45 in: Physic al Methods for Study of Sedimentary Rock Minerals (Kossovskaya, A.G., editor). Nauka, Moscow (in Russian).Google Scholar
Drits, V.A. & McCarty, D.K. (1996) The nature of diffraction effects from I and I-S consisting of interstratified tv and cv layers. Am. Miner. 81, 852–863.CrossRefGoogle Scholar
Drits, V.A. & Sakharov, B.A. (1976) X-ray Analysis of Mixed-Layer Minerals. Nauka, Moscow (in Russian).Google Scholar
Drits, V.A. & Tchoubar, C. (1990) X-ray Diffraction by Disordered Lamellar Structures. Springer Verlag, Berlin.CrossRefGoogle Scholar
Drits, V.A., Varaxina, T.V., Sakharov, B.A. & Plançon, A. (1994) A simple technique for identification of onedimensional powder X-ray diffraction patterns for mixed-layer illites-smectites and other interstratified minerals. Clays Clay Miner. 42, 382–390.Google Scholar
Drits, V.A., Lindgreen, H. & Salyn, A. (1997a) Determination of the content and distribution of fixed NH4 in illite-smectite by X-ray diffraction: Application to North Sea illite-smectite. Am. Miner. 82, 79–87.Google Scholar
Drits, V.A., Środoń, J. & Eberl, D.D. (1997b) XRD measurement of mean crystallite thickness of illite/ smectite: reappraisal of the Kubler index and the Scherrer equation. Clays Clay Miner. 45, 461–475.Google Scholar
Drits, V.A., Sakharov, B.A., Lindgreen, H. & Salyn, A. (1997c) Sequential structure transformation of illitesmectite- vermiculite of Upper Jurassic shales from the North Sea and Denmark. Clay Miner. 32, 351–371.Google Scholar
Drits, V.A., Dainyak, L.G., Muller, F., Besson, G. & Manceau, A. (1997d) Isomorphous cation distribution in celadonites, glauconites and Fe-illites determined by infrared, Mössbauer and EXAFS spectroscopies. Clay Miner. 32, 153–179.Google Scholar
Drits, V.A., Lindgreen, H., Salyn, A., Ylagan, R. & McCarty, D.K. (1998) Semiquantitative determination of trans-vacant and cis-vacant 2:1 layers in illites and illite-smectites by thermal analysis and X-ray diffraction. Am. Miner. 83, 1188–1198.Google Scholar
Frost, R.L., Van der Gaast, S.J., Paroz, G.N., Zbik, M. & Kloproge, J.T. (1999) Why Birdwood kaolinite (South Australia) does not intercalate with acetamide and formamide? P. 85 in: Abst. Conf. Eur. Clay Groups Assoc., Kraków.Google Scholar
Gu¨ven, N. (1991) On the definition of illite/smectite mixed-layer. Clays Clay Miner. 39, 661–662.Google Scholar
Jakobsen, H.J., Nielsen, N.C. & Lindgreen, H. (1995) Sequences of charged sheets in rectorite. Am. Miner. 80, 247–252.Google Scholar
Lindgreen, H., Drits, V.A., Sakharov, B.A., Salyn, A.L., Wrang, P. & Dainyak, L.G. (2000) Illite-smectite structural changes during metamorphism in black Cambrian Alum shales from the Baltic Sea. Am. Miner. 85, 1223–1238.Google Scholar
Manceau, A., Bruno, B., Drits, V.A., Chategner, D., Gates, W.P., Wu, J., Huo, D. & Stucki, J.W. (2000) Oxidationreduction mechanism of iron in dioctahedral smectites: I Crystal chemistry of oxidized reference nontronite. Am. Miner. 85, 133–152.Google Scholar
Moore, D.M. & Reynolds, R.C. (1989) X-ray Diffraction and the Identification and Analysis of Clay Minerals. Oxford University Press, Oxford.Google Scholar
Muller, F., Besson, G., Manceau, A. & Drits, V.A. (1997) Distribution of isomorphous cations within octahedral sheets in montmorillonite from Camp-Berteaux. Phys. Chem. Miner. 24, 159–166.Google Scholar
Muller, F., Plançon, A. & Drits, V.A. (1999a) Structure of dehydroxylated and rehydroxylated dioctahedral 2:1 layer silicates. P. 114 in: Abst. Conf. Eur. Clay Groups Assoc., Kraków.Google Scholar
Muller, F., Plançon, A. & Drits, V.A. (1999b) Application of the structural models of heat-treated micas to the study of the dehydroxylation-rehydroxylation of smectites. Abst. Colloque RX99, Strasbourg.Google Scholar
Muller, F., Drits, V.A., Plançon, A. & Besson, G. (2000a) Dehydroxylation of Fe3+, Mg- rich dioctahedral micas: (I) Structural transformation. Clay Miner. 35, 491–504.Google Scholar
Muller, F., Drits, V.A., Tsipurski, S.I. & Plançon, A. (2000b) Dehydroxylation of Fe3+, Mg-rich dioctahedral micas: (II) Cation migration. Clay Miner. 35, 505–514.Google Scholar
Plançon, A. & Zacharie, C. (1990) An expert system for structural characterization of kaolinites. Clay Miner. 25, 249–260.Google Scholar
Plançon, A. & Drits, V.A. (1999) Software for X-ray phase analysis of clays. P. 121 in: Abst. Conf. Eur. Clay Groups Assoc., Kraków.Google Scholar
Reynolds, R.C. (1980) Interstratified clay minerals. Pp. 249–304 in. Crystal Structures of Clay Minerals and their X-ray Identification (Brindley, G.W. & Brown, G., editors). Monograph, 5. Mineralogical Society, London.Google Scholar
Reynolds, R.C. (1985) NEWMOD a computer program for calculation of one-dimensional diffraction patterns of mixed-layer clays. Reynolds, R.C., 9 Brook Rd., Hanover, NH 03755, USA.Google Scholar
Reynolds, R.C. (1988) Mixed-layer chlorite minerals. Pp. 601–630 in. Hydrous Phyllosilicates (Exclusive of Micas ) (Bailey, S.W., editor ). Reviews in Mineralogy, 19. Mineralogical Society of America, Washington, D.C.Google Scholar
Reynolds, R.C. & Hower, J. (1970) The nature of interlayering in mixed-layer illite-montmorillonite. Clays Clay Miner. 18, 25–36.Google Scholar
Sakharov, B.A., Plançon, A. & Drits, V.A. (1999a) Influence of outer surface structure of crystals on X-ray diffraction. P. 129 in: Abst. Conf. Eur. Clay Groups Assoc., Kraków.Google Scholar
Sakharov, B.A., Lindgreen, H., Salyn, A. & Drits, V.A. (1999b) Determination of illite-smectite structures using multispecimen X-ray diffraction profile fitting. Clays Clay Miner. 47, 555–566.Google Scholar
Schultz, L.G., Shepard, A.O., Blackmon, P.D. & Starkey, H.C. (1971) Mixed-layer kaolinite-montmorillonite from the Yucatan Peninsula, Mexico. Clays Clay Miner. 19, 137–150.CrossRefGoogle Scholar
Slonimskaya, M.V., Besson, G., Dainyak, L.G., Tchoubar, C. & Drits, V.A. (1986) Interpretation of the IR spectra of celadonites and glauconites in the region of the OH–stretching frequencies. Clay Miner. 21, 377–388.Google Scholar
Środoń, J. (1980) Precise identification of illite/smectite in interstratifications by X-ray powder diffraction. Clays Clay Miner. 28, 401–411.Google Scholar
Środoń, J. (1981) X-ray identification of randomly interstratified illite/smectite in mixtures with discrete illite. Clay Miner. 16, 297–304.Google Scholar
Środoń, J. (1984) X-ray powder diffraction identification of illitic materials. Clays Clay Miner. 32, 337–349.CrossRefGoogle Scholar
Sudo, T. & Hayashi, H. (1956) A randomly interstratified kaolinite-montmorillonite in acid clay deposit in Japan. Nature 178, 1115–1116.CrossRefGoogle Scholar
Sudo, T., Hayashi, H. & Shimoda, S. (1962) Mineralogical problems of intermediate clay minerals. Clays Clay Miner. 9, 378–392.Google Scholar
Tettenhorst, R. & Johns, W.D. (1966) Interstratification in montmorillonite. Clays Clay Miner. 13, 85–93.Google Scholar
Thomas, A.R. (1989) A new mixed-layer clay mineral. Regular 1:1 mixed-layer kaolinite-smectite. P. 69 in: Abst. Ann. Meet. Clay Miner. Soc. Sacramento, California.Google Scholar
Thomson, J.G. & Cuff, C. (1985) Crystal structure of kaolinite dimethylsulfoxide intercalate. Clays Clay Miner. 33, 490–500.CrossRefGoogle Scholar
Tomita, K., Takahashi, H. & Watanabe, T. (1988) Quantification curves for mica/smectite interstratifications by X-ray powder diffraction. Clays Clay Miner. 36, 258–262.Google Scholar
Tsipurski, S.I. & Drits, V.A. (1984) The distribution of octahedral cations in the 2:1 layers of dioctahedral smectites studied by oblique-texture electron diffraction. Clay Miner. 19, 177–193.Google Scholar
Udagawa, S., Urabe, K. & Hasu, H. (1974) The crystal structure of muscovite dehydroxylate. Japan Ass. Miner. Petrol. Econ. Geol. 69, 381–389.CrossRefGoogle Scholar
Watanabe, T. (1981) Identification of interstratifications of illite and montmorillonite by X-ray powder diffraction. J. Miner. Soc. Japan, 15, 32–41.(in Japanese).Google Scholar
Watanabe, T. (1988) Structural model of illite/smectite interstratified minerals and the diagram for their interstratification. Clay Sci. 7, 97–114.Google Scholar
Wiewiora, A. (1971) A mixed-layer kaolinite-smectite from Lower Silesia, Poland. Clays Clay Miner. 19, 415–416.Google Scholar