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Molecular orientation of methylene blue cations adsorbed on clay surfaces

Published online by Cambridge University Press:  09 July 2018

J . Bujdák ,
N. Iyi ,
Y. Kaneko  and
R. Sasai
J . Bujdák*
Affiliation:
National InstituteforMaterialsScience, Namiki 1-1, Tsukuba, Ibaraki305-0044
N. Iyi
Affiliation:
National InstituteforMaterialsScience, Namiki 1-1, Tsukuba, Ibaraki305-0044
Y. Kaneko
Affiliation:
National InstituteforMaterialsScience, Namiki 1-1, Tsukuba, Ibaraki305-0044
R. Sasai
Affiliation:
ResearchCenter forAdvanced Waste and Emission Management (ResCWE), Nagoya University, Furo-cho, Chikusa-ku, Nagoya464-8603, Japan
*
*E-mail: [email protected]
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Abstract

Cationic dye, methylene blue (MB), was intercalated into films of expandable clay minerals with low, moderate and high layer charges (saponite, montmorillonite and synthetic expandable mica-fluorohectorite, respectively) . Tilted orientation of the dye cations on the silicate surface was observed by polarized ultraviolet-visible (UV-Vis) transmission spectroscopy. The tilting angle of the dye cations increased with the formation of high-order H-aggregates that absorb light at 525 nm. These dye species were formed only on the surface of fluorohectorite, which has the highest layer charge, and exhibited dichroism. Models for the orientation of MB cations on a clay surface were proposed based on MB orientation models previously reported, and compared with the basal spacings determined by X-ray diffraction.

Keywords

clay mineralH-aggregatesmethylene bluemolecular aggregationmolecular orientationpolarized spectroscopy
Type
Research Article
Information
Clay Minerals , Volume 38 , Issue 4 , December 2003 , pp. 561 - 572
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2003

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References

Bodenheimer, W. & Heller, L. (1968) Sorption of methylene blue by montmorillonite saturated with different cations. Israel Journal of Chemistry, 6, 307–314.Google Scholar
Breen, C. & Loughlin, H. (1994) The competitive adsorption of methylene blue on to Na-montmorillonite from binary solution with n-alkylammonium surfactants. Clay Minerals, 29, 775–783.CrossRefGoogle Scholar
Breen, C. & Rock, B. (1994) The competitive adsorption of methylene blue on to montmorillonite from binary solution with thioflavin T, proflavine and acridine yellow, steady state and dynamic studies. Clay Minerals, 29, 179–189.Google Scholar
Brindley, G.W. & Thompson, T.D. (1970) Methylene blue absorption by montmorillonites. Determinations of surface areas and exchange capacities with different initial cation saturations (Clay-organic studies XIX. Israel Journal of Chemistry, 8, 409–415.CrossRefGoogle Scholar
Bujdák, J. & Komadel, P. (1997) Interaction of methylene blue with reduced charge montmorillonite. Journal of Physical Chemistry B, 101, 9065– 9068.Google Scholar
Bujdák, J., Janek, M., Madejová, J. & Komadel, P. (1998) Influence of the layer charge density of smectites on the interaction with methylene blue. Journal of the Chemical Society, Faraday Transactio ns, 94, 3487–3492.Google Scholar
Bujdák, J., Janek, M., Madejová, J. & Komadel, P. (2001) Methylene blue interactions with reduced-charge smectites. Clays and Clay Minerals, 49, 244–254.Google Scholar
Bujdák, J., Iyi, N., Hrobáriková, J. & Fujita, T. (2002a) Aggregation and decomposition of a pseudoisocyanine dye in dispersions of layered silicates. Journal of Colloid and Interface Science, 247, 494–503.Google Scholar
Bujdák, J., Iyi, N. & Fujita, T. (2002b) The aggregation of methylene blue in montmorillonite dispersions. Clay Minerals, 37, 121– 133.Google Scholar
Campbell, D.J., Higgins, D.A. & Corn, R.M. (1990) Molecular second harmonic generation studies of methylene blue chemisorbed onto a sulfur-modified polycrystalli ne platinum electrode. Journal of Physical Chemistry, 94, 3681– 3689.Google Scholar
Cčapková, P., Pospísčil, M. & Lerf, A. (2002) Molecular simulations in structure analysis of tantalum sulfide intercalated with methylene blue. Solid State Sciences, 4, 671–676.CrossRefGoogle Scholar
Cenens, J. & Schoonheydt, R.A. (1988) Visible spectroscopy of methylene blue on hectorite, Laponite B and Barasym in aqueous suspensions. Clays and Clay Minerals, 36, 214–224.CrossRefGoogle Scholar
Chen, G., Pan, J., Han, B. & Yan, H. (1999) Adsorption of methylene blue on montmorillonite. Journal of Dispersion Science and Technology, 20, 1179–1187.Google Scholar
Chen, G.M., Iyi, N.B., Sasai, R., Fujita, T. & Kitamura, K. (2002) Intercalation of rhodamine 6G and oxazine 4 into oriented clay films and their alignment. Journal of Materials Research, 17, 1035–1040.CrossRefGoogle Scholar
Chen, W.X., Xu, Q.H., Jiang, H. & Xu, Z.D. (2000) Study on adsorption states by Surface-enhanced Raman Spectroscopy. Spectroscopy Letters, 33, 69–81.Google Scholar
Eisfeld, A. & Briggs, J.S. (2002) The J-band of organic dyes: lineshape and coherence length. Chemical Physics, 281, 61–70.Google Scholar
Fujita, T., Iyi, N., Kosugi, T., Ando, A., Deguchi, T. & Sota, T. (1997) Intercalation characteristics of rhodamine 6G in fluor-taeniolite: Orientation in the gallery. Clays and Clay Minerals, 45, 77– 84.CrossRefGoogle Scholar
Ghanadzadeh, A., Zanjanchi, M.A. & Tirbandpay, R. (2002) The role of host environment on the aggregative properties of some ionic dye materials. Journal of Molecular Structure, 616, 167–174.Google Scholar
Ha¨hner, G., Marti, A., Spencer, N.D. & Caseri, W.R. (1996) Orientation and electronic structure of methylene blue on mica: A near edge X-ray absorption structure spectroscopic study. Journal of Chemical Physics, 104, 7749–7757.Google Scholar
Hang, P.T. & Brindley, G.W. (1970) Methylene blue adsorption by clay minerals. Determination of surface areas and cation exchange capacities (Clay- Organic Studies XVIII). Clays and Clay Minerals, 18, 203–212.Google Scholar
Higgins, D.A., Byerly, S.K., Abrams, M.B. & Corn, R.M. (1991) Second harmonic generation studies of methylene blue orientation at silica surfaces. Journal of Physical Chemistry, 95, 6984 –6990.Google Scholar
Imamura, K., Ikeda, E., Nagayasu, T., Sakiyama, T. & Nakanishi, K. (2002) Adsorption behaviour of methylene blue and its congeners on a stainless steel surface. Journal of Colloid and Interface Science, 245, 50–57.Google Scholar
Iyi, N., Sasai, R., Fujita, T., Deguchi, T., Sota, T., Arbeloa, F.L. & Kitamura, K. (2002) Orientation and aggregation of cationic laser dyes in a fluoromica: polarized spectrometry studies. Applied Clay Science 22, 125–136.Google Scholar
Kahr, G. and Madsen, F.T. (1995) Determination of the cation exchange capacity and the surface area of bentonite, illite and kaolinite by methylene blue adsorption. Applied Clay Science, 9, 327–336.CrossRefGoogle Scholar
Kobayashi, T. (1996) J-aggregates. World Scientific. Singapore.Google Scholar
Kobayashi, H., Takahashi, M. & Kotani, M. (2001) Spontaneous formation of an ordered structure during dip-coating of methylene blue on fused quartz. Chemical Physics Letters, 349, 376–382.CrossRefGoogle Scholar
Kobayashi, M., Tokunaga, H., Okubo, J., Hoshi, T. & Tanizaki, Y. (1988) Measurements of the polarized ATR spectra for adsorbed dye layers by using a stack of thin glass plates. Bulletin of the Chemical Society of Japan, 61, 4171–4176.CrossRefGoogle Scholar
Lezna, R.O., Detacconi, N.R., Hahn, F. & Arvia, A.J. (1991) In situ spectroelectrochemistry of adsorbed methylene blue on a sulphur-modified gold electrode. Journal of Electroanalytical Chemistry, 306, 259–269.CrossRefGoogle Scholar
Nakato, T., Iwata, Y., Kuroda, K. & Kato, C. (1992) Preparation of an intercalation compound of layered titanic acid H2Ti4 O9 with methylene blue. Journal of Inclusion Phenomena and Molecular Recognition in Chemistry, 13, 249–256.CrossRefGoogle Scholar
Ogawa, M. & Kuroda, K. (1995) Photofunctions of intercalation compounds. Chemical Reviews, 95, 399– 438.Google Scholar
Sagara, T., Nomaguchi, H. & Nakashima, N. (1996) Surface anisotropic electroreflectance response at an edge-plane pyrolytic graphite electrode. Journal of Physical Chemistry, 100, 6393–6396.Google Scholar
Sasai, R., Shichi, T., Gekko, K. & Takagi, K. (2000) Continuously changing the conformational dependence of saponite hybrid materials on the intercalation degree: Electric linear dichroism of stilbazolium derivatives intercalated in saponite clay. Bulletin of the Chemical Society of Japan, 73, 1925–1931.Google Scholar
Sasai, R., Fujita, T., Iyi, N., Itoh, H. & Takagi, K. (2002) Aggregated structures of rhodamine 6G intercalated in a fluor-taeniolit e thin film. Langmuir, 18, 6578–6583.Google Scholar
Schoonheydt, R.A. & Heughebaert, L. (1992) Clay adsorbed dyes: Methylene blue on laponite. Clay Minerals, 27, 91–100.CrossRefGoogle Scholar
Shichi, T. & Takagi, K. (2000) Clay minerals as photochemica l reac tion f ields. Journ al of Photochemistry and Photobiology C: Photo-chemistry Reviews, 1, 113– 130.Google Scholar
Yamaoka, K., Sasai, R. & Takata, N. (2000) Electric linear dichroism. A powerful method for the ionic chromophore-colloid system as exemplified by dye and montmorillonite suspensions. Colloids and Surfaces A – Physicochemical and Engineering Aspects, 175, 23–39.Google Scholar
Yariv, S. (2002) Staining of clay minerals and visible absorption spectroscopy of dye-clay complexes. Pp. 463– 566.in. Organo -Clay Complex es and Interactions (Yariv, S. and Cross, H., editors). Marcel Dekker Inc., New York. Google Scholar
Yu, C.H., Newton, S.Q., Norman, M.A., Miller, D.M., Schafer, L. & Teppen, B.J. (2000) Molecular dynamics simulations of the adsorption of methylene blue at clay mineral surfaces. Clays and Clay Minerals, 48, 665– 681.Google Scholar