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Modelling pedogenization of zeolitized tuff: effects of water and phenolic substances on weathering rates of the Campanian Ignimbrite (yellow facies)

Published online by Cambridge University Press:  09 July 2018

E. Grilli ,
A. Colella ,
E. Coppola ,
A. Langella  and
A. Buondonno
E. Grilli*
Affiliation:
Seconda Università degli Studi di Napoli, Caserta, Italy
A. Colella
Affiliation:
Università di Napoli Federico II, Napoli, Italy
E. Coppola
Affiliation:
Seconda Università degli Studi di Napoli, Caserta, Italy
A. Langella
Affiliation:
Università del Sannio, Benevento, Italy
A. Buondonno
Affiliation:
Seconda Università degli Studi di Napoli, Caserta, Italy
*
*E-mail: [email protected]
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Abstract

An experimental pedology research project, based on a “process-system” pedogenetic model, was initiated to investigate the weathering of Phlegraean Yellow Tuff (PYT) – the yellow facies of the Campanian Ignimbrite with phillipsite > chabazite – as representative of the parent rock material as the soil-forming factor. PYT was weathered by water (W) and tannic acid solutions (TA) at concentrations ranging from 3 × 101 to 3 × 104 μmol l–1. The most concentrated TA solution (3 × 104 μmol l–1) showed the greatest extracting efficiency. Na and K were continually solubilized by W; Al, Ca and Mg contributed to the ionic composition of all the TA supernatants. A significant dissolution of the amorphous component and an associated decrease of the zeolite content, especially phillipsite, were noted. The features of PYT weathered outcomes fitted the “process-system” model very well. PYT showed a pedogenic potential, in being prone to weathering, as well as in releasing elements of importance for plant settlement and development, such as K, Ca, Mg and Fe.

Keywords

zeolitized tufftannic acidphenolic substancesweatheringpedogenetic modelpedogenic potential
Type
Research Article
Information
Clay Minerals , Volume 46 , Issue 2 , June 2011 , pp. 311 - 327
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2011

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