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Mineralogy and geochemical affinities of bentonites from Kapıkaya (Eskişehir, western Turkey)

Published online by Cambridge University Press:  09 July 2018

A. Yildiz  and
İ. Dumlupunar
A. Yildiz*
Affiliation:
Engineering Faculty, Afyon Kocatepe University, Afyonkarahisar, Turkey
İ. Dumlupunar
Affiliation:
Engineering Faculty, Afyon Kocatepe University, Afyonkarahisar, Turkey
*
*E-mail: [email protected]
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Abstract

There are numerous bentonite deposits, formed by the alteration of volcanic rocks, in the Kapıkaya area (Eskişehir, western Turkey). These deposits can be classified into three groups according to their stratigraphical levels. X-ray diffraction (XRD), scanning electron microscope (SEM), major, rare-earth and trace-element analyses of bentonites and their parent rocks from the Kapıkaya area were used to evaluate the mineralogical and geochemical properties of bentonites and their parental affinities. Mineral assemblages resulting from bentonite deposits consist mostly of clay minerals, gypsum, cristobalite/opal-CT, quartz, feldspar, calcite and dolomite. The clay minerals are represented mainly by dioctahedral smectite and lesser amounts of illite and chlorite. The enrichment and depletion of the elements indicates open-system alteration conditions. The enrichments in MgO, Fe2O3, TiO2, Co, Pb, Zn, and Ni are related to the precipitation of hydrothermal solutions channelled throughout ultramafic sources. The main differences in mineralogy and geochemistry of bentonites from the Kapıkaya area are in the smectite composition and the contents of major, rare-earth and other trace elements. The data obtained show that the types of parent rock the influenced the mineralogical and geochemical compositions of the bentonites.

Keywords

EskişehirTurkeybentonitemontmorillonitesmectitehydrothermal alterationelement mobilizationparental affinity
Type
Research Article
Information
Clay Minerals , Volume 44 , Issue 3 , September 2009 , pp. 339 - 360
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2009

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References

Akbulut, A. (1996) Bentonit. Maden Tetkik Arama Genel Müdurlüğu Yayinlan, Egitim Serisi, 32, 78pp. Ankara, Turkey (in Turkish).Google Scholar
Altmli, E.İ. (1973) Orta Sakarya jeolojisi. Cumhuriyetin 50. Yili Yerbilimleri Kongresi, Maden Tetkik Arama Genel Müdurlüğu Yayinlan, 159-191. Ankara, Turkey (in Turkish).Google Scholar
Berry, R.W. (1999) Eocene and Oligocene Otay-type waxy bentonites of San Diego County and Baja California: chemistry, mineralogy, petrology and plate tectonic implications. Clays and Clay Minerals, 47, 70–83.Google Scholar
Brooking, D.G. (1989) Aqueous geochemistry of trace earth elements. Pp. 201–225 in: Geochemistry and Mineralogy of Rare Elements (Lipin, B.R. & McKay, G.A., editors. Reviews in Mineralogy, 21, Mineralogical Society of America.CrossRefGoogle Scholar
Brown, G. (1972) Montmorillonites. Pp. 143–206 in: X-ray Identification and Crystal Structures of Clay Minerals. Mineralogical Society, London.Google Scholar
Brown, G. & Brindley, G.W. (1980) X-ray diffraction procedures for clay mineral identification. Pp. 305–360 in: Crystal Structure of Clay Minerals and their X-ray Identification (Brindley, G.W. & Brown, G., editors). Monograph 5, Mineralogical Society, London.Google Scholar
Brusewitz, A.M. (1986) Chemical and physical properties of Paleozoic potassium bentonites from Kinnekule, Sweden. Clays and Clay Minerals, 34, 442–454.Google Scholar
Caballero, E., Jimenez De Cisneros, C., Huertas, F.J., Huertas, F., Pozzuoli, A. & Linares, J. (2005) Bentonites from Cabo de Gata, Almeria, Spain: a mineralogical and geochemical overview. Clay Minerals, 40, 463–480.Google Scholar
Calarge, L.M., Meunier, A. & Formoso, M.L.L. (2003) A bentonite bed in the Acegua (RS, Brazil) and Melo (Uruguay) areas: a highly crystallized montmorillonite. Journal of South American Earth Sciences, 16, 187–198.Google Scholar
Çelik, M., Karakaya, N. & Temel, A. (1999) Clay minerals in hydrothermally altered volcanic rocks, Eastern Pontides, Turkey. Clays and Clay Minerals, 47, 708–717.Google Scholar
Christidis, G.E. (1998) Comparative study of the mobility of major and trace elements during alteration of an andecite and a rhyolite to bentonite, in the islands of Milos and Kimolos, Aegean, Greece. Clays and Clay Minerals, 46, 379–399.Google Scholar
Christidis, G. & Dunham, A.C. (1993) Compositional variations in smectites: Part I. Alteration of intermediate volcanic rocks. A case study from Milos island, Greece. Clay Minerals, 28, 255–273.Google Scholar
Christidis, G. & Dunham, A.C. (1997) Compositional variations in smectites: Part II. Alteration of acidic precursors. A case study from Milos island, Greece. Clay Minerals, 32, 253–270.Google Scholar
Christidis, G., Scott, P.W. & Marcopoulos, T. (1995) Origin of the bentonite deposits of eastern Milos and Kimalos, Greece: Geology, geological, mineralogical and geochemical evidence. Clays and Clay Minerals, 43, 63–77.Google Scholar
Çoban, F. (1994) Mihalgazi (Eskişehir) bentonitinin mineralojik özellikleri ve oluşumu. T.J.K. Kurultay Bülteni, 9, 297–303. Ankara, Turkey (in Turkish).Google Scholar
çoban, F. (2001) çayirlik Tepe (Başören-Kütahya) bentonitlerinin alterasyon sirasmda majör, eser ve toprak elementlerinin mobilizasyonu. 10 Ulusal Kil sempozyumu, 282-304. Konya, Turkey (in Turkish).Google Scholar
Delano, J.W., Schirnick, C., Bock, W., Kidd, W.S.F., Heizler, M.T., Putman, G.W., De Long, S.E. & Onr, M. (1990) Petrology and geochemistry of Ordovician K-bentonites in New York State: Constraints on the nature of a volcanic arc. The Journal of Geology, 98, 157–170.CrossRefGoogle Scholar
Demirkol, C. (1977) Üzümlü-Tuzakli (Bilecik) dolayinin Jeolojisi. T.J.K. Bülteni, 20, 9–16. Ankara, Turkey (in Turkish).Google Scholar
Ece, O.I. & çoban, F. (1993) Comparison of hydrothermal alteration of two different parent rocks for the occurrence of Ca-bentonite deposits in western Turkey. 2nd International Meeting on ‘Red Mediterranean Soils’, Short Paper and Abstracts, 91-93. Adana, Turkey.Google Scholar
Foreman, B.Z., Rogers, R.R., Deino, A.L., Wirth, K.R. & Thole, J.T. (2008) Geochemical characterization of bentonite beds in the Two Medicine Formation (Campanian, Montana), including a new 40Ar/39Ar age. Cretaceous Research, 29, 373–385.Google Scholar
Garcia-Romero, E., Vegas, J., Baldonedo, J.L. & Marfil, R. (2005) Clay minerals as alteration products in basaltic volcanoclastic deposits of La Palma (Canary Islands, Spain). Sedimentary Geology, 174, 237–253.Google Scholar
Greene-Kelly, R. (1953) The identification of montmorillonoide in clays. Journal of Soil Science, 4, 233–237.Google Scholar
Gresens, R.L. (1967) Composition-volume relationships of metasomatism. Chemical Geology, 2, 47-65.Google Scholar
Grim, R.E. (1968) Clay Mineralogy, 2 nd edition. International Series in Earth Sciences. McGraw-Hill Book Co. Inc., 595pp., New York, USA.Google Scholar
Grim, R.E. & Guven, N. (1978) Bentonites; Geology, Mineralogy, Properties and Uses.. Pp. 13–137. Elsevier, Amsterdam, The Netherlands.Google Scholar
Guilbert, J.M. & Sloane, R.L. (1968) Electron-optical study of hydrothermal fringe alteration of plagioclase in quartz monzonite, Butte District, Montana. Clays and Clay Minerals. 16, 215–221.Google Scholar
Hemley, J.J. & Jones, W.R. (1964) Chemical aspects of hydrothermal alteration with emphasis on hydrogen metasomatism. Economic Geology, 59, 538–569.Google Scholar
Honty, M., Clauer, N. & Šucha, V. (2008) Rare-earth elemental systematics of mixed-layered illite-smectite from sedimentary and hydrothermal environments of the Western Carpathians (Slovakia). Chemical Geology, 249, 167–190.Google Scholar
Huff, W.D. & Tiirkmenoglu, A.G. (1981) Chemical characteristics and origin of Ordovician K-bentonites along the Cincinnati Arch. Clays and Clay Minerals, 29, 113–123.Google Scholar
Huff, W.D., Merriman, R.J., Morgan, D.J. & Roberts, B. (1993) Distribution and tectonic setting of Ordovician K-bentonites in the United Kingdom. Geological Magazine, 130, 93–100.Google Scholar
Humphris, S.E. (1984) The mobility of the rare earth elements in the crust. Pp. 317–342 in: Rare Earth Element Geochemistry (Henderson, P., editor), Elsevier, Amsterdam, The Netherlands.Google Scholar
Kibici, Y. (1990) Saricakaya (Eskişehir) volkanitlerinin petrolojisi ve kökensel yorumu. Türkiye Jeoloji Bülteni, 33, 69-11. Ankara, Turkey (in Turkish).Google Scholar
Kibici, Y. (1991) Orta Saricakaya (Eskişehir) havzasmdaki başkalaşim kayaçlarmm petrografik özellikleri ve kökensel yorumu. Akdeniz Üniversitesi Isparta Mühlendislik Fakültesi Dergisi, 5, 1–31. Isparta, Turkey (in Turkish).Google Scholar
Laviano, R. & Mongelli, G. (1996) Geochemistry and mineralogy as indicators of parental affinity for Cenozoic bentonites: a case study from S. Croce Di Magliano (southern Appennines, Italy). Clay Minerals, 31, 391–401.Google Scholar
Leat, P.T., Jackson, S.E., Thorpe, R.S. & Stillman, C.J. (1986) Geochemistry of bimodal basalt-subalkaline/peralkaline rhyolite provinces within the Southern British Caledonides. Journal of the Geological Society, 143, 259–73.CrossRefGoogle Scholar
Lim, C.H. & Jackson, M.L. (1986) Expandable phyllosilicate reactions with lithium on heating. Clays and Clay Minerals, 34, 346–352.Google Scholar
Martinez-Ruiz, F., Ortega-Huertas, M. & Rivas, P. (2006) Rare earth element composition as evidence of the precursor material of Cretaceous—Tertiary boundary sediments at distal sections. Chemical Geology, 232, 1–11.Google Scholar
Munch, P., Duplay, J. & Cocheme, J.-J. (1996). Alteration of silicic vitric tuffs interbedded in volcanolastic deposits of the Southern Basin and Range Province, Mexico. Evidences for Hyrothermal Reactions. Clays and Clay Minerals, 44, 49–67.Google Scholar
Munchangos, A.C. (2006) The mobility of rare-earth and other elements in the process of alteration of rhyolitic rocks to bentonite (Lebombo Volcanic Mountainous Chain, Mozambique. Journal of Geochemical Exploration, 88, 300–303.Google Scholar
Noble, D.C. (1967) Sodium, potassium and ferrous iron contents of some secondary hydrated natural silicic glasses. American Mineraogilst, 52, 280–286.Google Scholar
Pandarinath, K., Dulski, P., Torres-Alvarado, I.S. & Verma, S.P. (2008) Element mobility during the hydrothermal alteration of rhyolitic rocks of the Los Azufres geothermal field, Mexico. Geothermics, 37, 53–72.Google Scholar
Pearce, J.A., Harris, N.B. & Tindle, A.G. (1984) Trace elements discrimination diagrams for the tectonic interpretation of granitic rocks. Journal of Petrology, 25, 956–983.Google Scholar
Reyes, E., Caballero, E., Huertes, F. & Linares, J. (1987) Bentonite deposits from Caba de Gata Region Almeria, SE Spain. Pp. 9–31 in: Guidebook, the 6th Meeting of the European Clay Groups (Huertas, M.O., editor) Seville, Spain.Google Scholar
Roberts, B. & Merriman, R.J. (1990) Cambrian and Ordovician metabentonites and their relevance to the origins of associated mudrocks in the northern sector of the Lower Paleozoic Welsh marginal basin. Geological Magazine, 127, 31–43.Google Scholar
Senkayi, A.L., Dixon, J.B., Hossner, L.R., Abder-Ruhman, M. & Fanning, D.S. (1984) Mineralogy and genetic relationship of tonstein, bentonite and lignitic strata in the Eocene Yegna Formation of East-Central Texas. Clays and Clay Minerals, 32, 259–271.Google Scholar
Şentürk, K. & Karaköse, C. (1979) Orta Sakarya Dolayimn Jeolojisi. Maden Tetkik ve Arama Genel Müdurlüğu Raporu, 6642, 85 pp, Ankara, Turkey (in Turkish).Google Scholar
Setti, M., Marinoni, L. & Lopez-Galindo, A. (2004) Mineralogical and geochemical characteristics (major, minor, trace elements and REE) of detrital and authigenic clay minerals in a Cenozoic sequence from Ross Sea, Antartica. Clay Minerals, 39, 405–421.Google Scholar
Spears, D.A., Kaneris-Satiriou, R., Riley, N. & Krause, P. (1999) Namurian bentonites in the Pennine basin, UK — Origin and magmatic affmites. Sedimentology, 46, 385–401.Google Scholar
Starke, R. (1991) Trace elements of clay minerals. Proceeding of the 7th Euroclay Conference, 989-994, Dresden, Germany.Google Scholar
Takagi, T., Koh, S.M., Song, M.S., Itoh, M. & Mogi, K. (2005) Geology and properties of the Kawasaki and Dobuyama bentonite deposits of Zao region in northeastern Japan. Clay Minerals, 40, 333–350.Google Scholar
Tamura, T. & Jackson, M.L. (1953) Structural and energy relationships in the formation of iron and aluminum oxides, hydroxides and silicates. Science, 117, 381–383.CrossRefGoogle ScholarPubMed
Taylor, S.R. & McLennan, S.M. (1985) The Continental Crust: Its Composition and Evolution. 311 pp, Blackwell Scientific Publications, Oxford, UK.Google Scholar
Teale, C.T. & Spears, D.A. (1986) The mineralogy and origin of some Silurian bentonites, Welsh Borderland, U.K. Sedimentology, 33, 757–765.Google Scholar
Türkmenoğlu, A.G. & Aker, S. (1990) Origin of sedimentary bentonite deposits of Çankiri basin, Turkey. Pp. 63–72 in: Proceedings of the 5th International Clay Conference, Strasbourg, France.Google Scholar
White, A.F. & Claassen, H.S. (1979) Dissolution kinetics of silicate rocks — application to solute modelling in aqueaus systems. American Chemical Society Symposium Series, 93, 447–473.Google Scholar
Wilson, M. (1989) Igneous Petrogenesis: A Global Tectonic Approach. Unwin Hyman, London.Google Scholar
Winchester, J.A. & Floyd, P.A. (1977) Geoehemieal discrimination of different magma series and their differentiation products using immobile elements. Chemical Geology, 20, 325–343.Google Scholar
Wintsch, R.P. & Kvale, C.M., (1994) Differential mobility of elements in burial diagenesis of siliciclastic rocks. Journal of Sedimentary Research, A64, 349–361.Google Scholar
Wood, S.A. (1990a) The aqueous geochemistry of rare-earth elements and yttrium; Part 1. Review of available low-temperature data for inorganic complexes and the inorganic REE speciation of natural waters. Chemical Geology, 82, 159–186.Google Scholar
Wood, S.A. (1990b) The aqueous geochemistry of the rare-earth elements and yttrium; Part 2. Theoretical prediction of speciation in hydrothermal solutions to 350°C at saturation water vapor pressure. Chemical Geology, 88, 99–125.Google Scholar
Wray, D.S. & Wood, C.J. (1998) Distinction between detrital and volcanogenic clay-rich beds in Turonian-Coniacian chalks of eastern England. Proceedings of the Yorkshire Geological Society, 52, 95–105.Google Scholar
Yalçın, H. & Gümüşer, G. (2000) Mineralogical and geoehemieal characteristics of late Cretaceous bentonite deposits of the Kelkit Valley region, northern Turkey. Clay Minerals, 35, 807–825.Google Scholar
Yıldız, A. & Kuşcu, M. (2004) The origin of Başören (Kütahya, W Turkey) bentonite deposits. Clay Minerals, 39, 219–231.Google Scholar
Yıldız, A. & Kuşcu, M. (2006) Başören (Kutahya) bentonit yataklarmm jeokimyasal özellikleri. Kibited Kil Bilimi ve Teknolojisi Dergisi, 1, 27–41. Istanbul, Turkey (in Turkish).Google Scholar
Yıldız, A., Kibici, Y., öoban, F., Bağci, M., Dumlupunar, I., Kocabaş, C., Aritan, E. & Bilge, Y. (2008) Mihalgazi (Eskişehir) bentonit yatağının jeolojisi ve bentonitin endüstriyel hammadde olarak değerlendirilmesi. The Project Report of The Scientific and Technical Research Council of Turkey (TÜBİTAK) 104Y160, 263 pp. (in Turkish).Google Scholar
Zielinski, R.A. (1982) The mobility of uranium and other elements during alteration of rhyolite ash to montmorillonite: a case study in the Troublesome Formation, Colorado, U.S.A. Chemical Geology, 35, 185–204.Google Scholar