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Mineralogical characterization of fibrous zeolites from the Kahrizak volcanic suite, south Tehran, Iran

Published online by Cambridge University Press:  09 July 2018

M. Kusehlar
Affiliation:
School of Geology, College of Science, University of Tehran, Tehran, Iran 14155-64155
F. Tutti*
Affiliation:
School of Geology, College of Science, University of Tehran, Tehran, Iran 14155-64155
H. Mirnejad
Affiliation:
School of Geology, College of Science, University of Tehran, Tehran, Iran 14155-64155
A. E. Lalonde
Affiliation:
Department of Earth Sciences, University of Ottawa, Ottawa, Ontario, Canada K1N 6N5
*

Abstract

Selected samples of large cavity filling and vein-type fibrous zeolites from Eocene volcanic rocks in the Kahrizak region, northern Iran, have been studied for their mineralogical and chemical characteristics. X-ray powder diffraction and electron microprobe analyses confirmed the presence of natrolite, mesolite and scolecite with compositions of [Na14.922Ca0.202K0.015Ba0.002] [Al15.697Si24.267O80nH2O, [Ca15.714Na14.224][Al46.431Si73.398O240nH2O and [Ca7.804Na0.142K0.024 Ba0.012Mg0.006][Al15.320Si24.437O80nH2O, respectively. In addition, examination of textural relationships in thin sections and back-scattered electron images reveals a paragenetic order in which the Ca-rich zeolites crystallized first. It is most probable that the fibrous zeolites of Kahrizak were formed during two pulses of hydrothermal activity in the area. Scolecite and mesolite were precipitated from Ca-rich solution, whereas the second stage Na-rich, low-temperature fluid crystallized natrolite and reacted with Ca-species.

Type
Research Article
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2010

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References

Alberti, A., Pongiluppi, D. & Vezzalini, G. (1982) The crystal chemistry of natrolite, mesolite, and scolecite. Neues Jahrbuch für Mineralogische Abhandlungen, 143, 231248.Google Scholar
Apps, J.A. (1983) Hydrothermal evolution of repository groundwater in basalt. Pp. 1451 in. NRC Nuclear Waste Geochemistry, 83. US Regulatory Commission Report NUREG/CP-0052.Google Scholar
Armbruster, T. & Gunter, M.E. (2001) Crystal structure of natural zeolites. Pp. 168 in: Natural Zeolites: Occurrence, Properties, Applications (Bish, D.L. & Ming, D.W., editors). Reviews in Mineralogy and Geochemistry, 45. Mineralogical Society of America.Google Scholar
Artioli, G., Smith, J. V., & Pluth, J.J. (1986) X-ray structure refinement of mesolite. Ada Crystallographica, C42, 937942.Google Scholar
Bazargani-Guilani, K. & Rabbani, M.S. (2004) Amygdaloidal and other cavity filling zeolites of Kuh-e-Aradeh, Central Iran. Journal of Sciences, Islamic Republic of Iran, 15, 149157.Google Scholar
Breck, D.W. (1974) Zeolite Molecular Sieves. John Wiley and Sons, New York, 771 pp.Google Scholar
Capitelli, F. & Derebe, M.G. (2007) Single crystal X-ray diffraction study of a pure natrolite sample. Journal of Chemical Crystallography, 37, 583586.CrossRefGoogle Scholar
Coombs, D.S., Alberti, A., Artioli, A., Armbruster, T., Artioli, G., Colella, C., Galli, E., Grice, J.D., Liebau, F., Liebau, F., Mandarino, J.A., Minato, H., Nickel, E.H., Passaglia, E., Peacor, D.R., Quartieri, S., Rinaldi, R., Ross, M., Sheppard, R.A., Tillmanns, E. & Vezzalini, G. (1998) Recommended nomenclature for zeolite minerals: report of the subcommittee on zeolites of the international mineralogical association, commission on new minerals and mineral names. Mineralogical Magazine, 62, 533571.CrossRefGoogle Scholar
Davoudzadeh, M. & Schmidt, K. (1984) A review of the Mesozoic paleogeography and paleotectonic evolution of Iran. Neues Jahrbuch für Geologie and Palaeontologie Abhundlungen, 168, 182207.CrossRefGoogle Scholar
Faith, L. & Hansen, S. (1979) Structure of scolecite from Poona, India. Ada Crystallographica, B35, 18771880.Google Scholar
Gottardi, G. & Galli, E. (1985) Pp. 3571 in: Natural Zeolites, Springer-Verlag, Berlin, Germany.Google Scholar
Graham, I.T., Pogson, R.E., Colchester, D.M. & Baines, A. (2003) Zeolite crystal habits, compositions, and paragenesis; Blackhead Quarry, Dunedin, New Zealand. Mineralogical Magazine, 67, 625637.Google Scholar
Gunter, M.E., Knowles, Ch.R. & Kateschalk, D. (1993) Composite natrolite-mesolite crystals from the Columbia River Basalt Group. Clarkston, Washington. The Canadian Mineralogist, 31, 467470.CrossRefGoogle Scholar
Haghipour, A., Taraz, H. & Vahdati Daneshmand, F. (1986) Geological map of Tehran (1:250000), Geological Survey of Iran.Google Scholar
Hassanzadeh, J., Ghazi, A.M., Axen, G. & Guest, B. (2002) Oligomioeene mafic alkaline magmatism in north and northwest of Iran: evidence for the separation of the Alborz from the Urumieh-Dokhtar magmatic arc. Geological Society of America, Abstracts with Programs, 34, 331.Google Scholar
Hay, R.L. (1978) Geologic occurrences of zeolites. Pp. 135144 in: Natural Zeolites: Occurrence, Properties, Use (Sand, L.B. & Mumpton, F.A., editors). Pergamon Press, Oxford, UK.Google Scholar
Iijima, A. (1978) Geological occurrences of zeolite in marine environments. Pp. 175198 in: Natural Zeolites: Occurrence Properties, Use (Sand, L.B. & Mumpton, F.A., editors). Pergamon Press, Oxford, UK.Google Scholar
Kristmannsdottir, H. & Tómasson, J. (1978) Zeolite zones in geothermal areas in Iceland. Pp. 277284 in: Natural Zeolites: Occurrence, Properties, Use (Sand, L.B. & Mumpton, F.A., editors). Pergamon Press, Oxford, UK.Google Scholar
Moiola, R. (1970) Authigenic zeolites and K-feldspar in the Esmeralda Formation, Nevada. American Mineralogist, 55, 16811691.Google Scholar
Neuhoff, P.S., Fridriksson, T. & Bird, D.K. (2000) Zeolite parageneses in the North Atlantic Igneous Provinces: implications for geotectonics and groundwater quality of basaltic crust. International Geology Review, 42, 1544.CrossRefGoogle Scholar
Neves, C. & Nunes, J.E.L. (1968) Zeolites from Corumana Mountan (Lebombo range, Mozambique, Portuguese East Africa). Revista de la Ciencias Geologicas, serie A, 1, Lourence Marques, 73-92.Google Scholar
Passaglia, E. (1970) The crystal chemistry of chabazites. American Mineralogist, 55, 12781299.Google Scholar
Passaglia, E. & Sheppard, R.A. (2001) Crystal chemistry of zeolites. Pp. 69116 in: Natural Zeolites Occurrence, Properties, Applications (Bish, D.L. & Ming, D.W., editors). Reviews in Mineralogy and Geochemistry, 45. Mineralogical Society of America.Google Scholar
Rieben, H. (1955) The geology of the Teheran plain. American Journal of Science, 253, 617639.CrossRefGoogle Scholar
Ross, M. & Flohr, H.J.K. (1992) Crystalline solution series and order-disorder within the natrolite mineral group. American Mineralogist, 77, 685703.Google Scholar
Sheppard, R.A. & Hay, R.L. (2001) Formation of zeolites in open hydrologic systems. Pp. 261275 in: Natural Zeolites: Occurrence, Properties, Applications (Bish, D.L., & Ming, D.W., editors). Reviews in Mineralogy and Geochemistry, 45. Mineralogical Society of America.Google Scholar
Staples, L.W. (1946) Origin of spheroidal clusters of analcime from Benton County, Oregon. American Mineralogist, 31, 574581.Google Scholar
Surdam, R.C. & Sheppard, R.A. (1978) Zeolites in saline, alkaline-lake deposits. Pp. 145175 in: Natural Zeolites: Occurrence, Properties, Use (Sand, L.B. & Mumpton, F.A., editors). Pergamon Press, Oxford, UK.Google Scholar
Tschernich, R.W. (1992) Zeolites of the World. Geoscience Press, Phoenix, Arizona, USA.Google Scholar
Verdel, Ch. (2009) Cenozoic geology of Iran: an integrated study of extensional tectonics and related volcanism. Ph.D. dissertation, California Institute of Technology, Pasadena, California, USA.Google Scholar
Vincent, S.J., Allen, M.B., Ismail-Zadeh, A.D., Flecker, R., Foland, K.A. & Simmons, M.D. (2005) Insights from the Talysh of Azerbaijan into the Paleogene evolution of the south Caspian region. Geological Society of America Bulletin, 117, 15131533.Google Scholar
Yazdani, S. (2005) Petrology and geochemistry of volcanic rocks of south Kahrizak (north Central Iran) and zeolite mineralization in them. M.Sc. Thesis, Department of Geology, University of Tehran, Iran (in Farsi).Google Scholar