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Influence of potassium concentration on the swelling and compaction of mixed (Na,K) ion-exchanged montmorillonite

Published online by Cambridge University Press:  09 July 2018

J. H. Denis ,
M. J. Keall ,
P. L. Hall  and
G. H. Meeten
J. H. Denis
Affiliation:
Schlumberger Cambridge Research, PO Box 153, Cambridge, CB3 0HG, UK
M. J. Keall
Affiliation:
Schlumberger Cambridge Research, PO Box 153, Cambridge, CB3 0HG, UK
P. L. Hall
Affiliation:
Schlumberger Cambridge Research, PO Box 153, Cambridge, CB3 0HG, UK
G. H. Meeten
Affiliation:
Schlumberger Cambridge Research, PO Box 153, Cambridge, CB3 0HG, UK
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Abstract

Oedometer swelling and compaction tests up to a maximum pressure of 32 bars were made on the Wyoming montmorillonite SWy-1 with a range of mixed (Na,K) exchange ion compositions. The permeabilities and water diffusivities of the compacted clays were calculated using soil physics theory. Significant inhibition of swelling from that of the Na-montmorillonite is developed for K fractions in the range 0·30 < K+ < 0·56. However, the water diffusivity increases by a factor of approximately six as the K exchange fraction increases from 0 to 0·7. Permeabilities to water flow show a power-law dependence on the void ratio e.

XRD measurements at controlled humidity yield equilibrium interlayer spacings which in general increase with both increasing relative humidity and increasing Na exchange fraction. The extent of swelling is strongly inhibited in clays having Na exchange fractions of 0·44 or less, in good agreement with the oedometer studies.

Type
Research Article
Information
Clay Minerals , Volume 26 , Issue 2 , June 1991 , pp. 255 - 268
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1991

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References

Atkinson, J.H. & Bransby, P.L. (1978) The Mechanics of Soils. McGraw-Hill, London.Google Scholar
Atsumi, K. & Akiyama, T. (1975) A study of cake filtration-formulation as a Stefan problem. J. Chem. Eng. Japan, 8, 487–492.Google Scholar
Barclay, L.M. & Ottewill, R.H. (1970) Interparticle forces in montmorillonite gels. Spec. Disc. Faraday Soc., 1, 138–147.Google Scholar
Ben Rhaiem, H., Tessier, D. & Pons, C.H. (1986) Comportement hydrique et evolution structurale et texturale des montmorillonites au cours d^n cycle de dessication-humectation: partie I. Clay Miner., 21, 9–29.Google Scholar
Ben Rhaiem, H., Pons, C.H. & Tessier, D. (1987) Factors affecting the microstructure of smectites: role of cation and history of applied stresses. Proc. Int. Clay Conf. Denver,, 292–297. Google Scholar
Bol, G.M. (1986) The effect of various polymers and salts on borehole and cutting stability in water-base shale drilling fluids. Int. Drilling ContractorsISoc. Petrol. Engineers, Paper No. 14802.CrossRefGoogle Scholar
Brindley, G.W. (1980) Order-disorder in clay mineral structures. Pp. 125-195 in: Crystal Structures of Clay Minerals and their X-ray Identification(Brindley, G.W. & G. Brown, editors). Mineralogical Society, London.Google Scholar
Cebula, D.J., Thomas, R.K. & White, J.W. (1980) Small-angle scattering from dilute aqueous dispersions of clay. J. Chem. Soc. Faraday Trans. I,, 76, 314–321.Google Scholar
Chapman, R.E. (1981) Geology and Water. Martinus Nijhoff, The Hague.Google Scholar
Chilingar, G.V. & Knight, L. (1960) Relationship between pressure and moisture content of kaolinite, illite and montmorillonite clays. Am. Ass. Petrol. Geol. Bull., 44, 101–106.Google Scholar
Clark, R.K., Scheuerman, R.F., Rath, H. & Van Laar, H.G. (1976) Polyacrylamide/potassium chloride mud for drilling water sensitive shales. J. Petrol. Tech. June 1976, 719–727.CrossRefGoogle Scholar
Farmer, V.C. (1978) Water on particle surfaces. Pp. 405^448 in: The Chemistry of Soil Constituents(Greenland, D.J. & M.H.B., Hayes, editors). John Wiley & Sons, Chichester.Google Scholar
Fletcher, P. & Sposito, G. (1989) The chemical modelling of clay/electrolyte interactions for montmorillonite. Clay Miner., 24, 375–391.Google Scholar
Fripiait, J.J. (1980) The application of NMR to the study of clay minerals. Pp. 245-315 in: Advance Chemical Methoids for Soil and Clay Mineral Research (Stucki, J.W. & Banwart, W., editors). D. Riede Publishing, Dordrecht.Google Scholar
Glaeser, R. & Mering, J. (1968) Homogeneous hydration zones of the smectites. C. R. Acad. Sci. Paris,, 267, 436–466.Google Scholar
Gray, G.R., Darley, H.C.H. & Rogers, W.F. (1980) Composition and Properties of Oil Well Drilling Fluids ?, 4 th ed. Gulf, Houston.Google Scholar
Hall, P.L. (1981) Neutron scattering techniques for the study of clay minerals. Pp. 51-75 in: Advanced Techniques for Clay Mineral Analysis(Fripiat, J.J., editor). Elsevier, Amsterdam.Google Scholar
Hall, P.L. & Astill, D.M. (1989) Adsorption of water by homo-ionic exchange forms of Wyoming montmorillonite (SWy-1). Clays Clay Miner., 37, 355–363.CrossRefGoogle Scholar
Kaye, G.W.C. & Laby, T.H. (1973) Tables of Physical and Chemical Constants,, 14th ed., Longman, London.Google Scholar
Keren, R. & Shainberg, I. (1975) Water vapor isotherms and heat of immersion of Na/Ca-montmorillonite systems. I; Homoionic clay. Clays Clay Miner., 23, 193–200 Google Scholar
Kefen, R. & Shainberg, I. (1979) Water vapor isotherms and heat of immersion of Na/Ca-montmorillonite systems. II: Mixed systems. Clays Clay Miner., 27, 145–151.Google Scholar
Lubetkin, S.D., Middleton, S.R. & Ottewill, R.H. (1984) Some properties of clay-water dispersions. Phil. Trans. Roy. Soc. London., A311, 353–368.Google Scholar
MacEwan, D.M.C. & Wilson, M J. (1980) Interlayer and intercalation complexes of clay minerals. Pp. 197-248 in: Crystal Structures of Clay Minerals and their X-ray Identification(G.W. Brindley & G. Brown, editors). Mineralogical Society, London.Google Scholar
Marshall, C.H. & Krinbill, C.A. (1942) The clays as colloidal electrolytes. J. Phys. Chem., 46, 1077.Google Scholar
Mesri, G. & Olson, R.E. (1971) Consolidation characteristics of montmorillonite. Geotechnique,, 21, 341–352.Google Scholar
Mooney, R.W., Keenan, A.C. & Wood, L.A. (1952) Adsorption ofwater by montmorillonite. 7. Am. Chem. Soc., 74, 1367–1374.Google Scholar
Morgenstern, N.R. & Tchalenko, J.S. (1967a) The optical determination of preferred orientation in clays and its application to the study of microstructure in consolidated kaolinite. I. Proc. Roy. Soc. A,, 300, 218–234.Google Scholar
Morgenstern, N.R. & Tchalenko, J.S. (1967b) The optical determination of preferred orientation in clays and its application to the study of microstructure in consolidated kaolinite. II. Proc. Roy. Soc. A,, 300, 235–250.Google Scholar
Norrish, K. (1954a) Manner of swelling of montmorillonite. Nature,, 173, 256–257.Google Scholar
Norrish, K. (1954b) The swelling of montmorillonite. Disc. Faraday Soc., 18, 120–134.Google Scholar
O'Brien, D.E. & Chenevert, M.E. (1973) Stabilizing sensitive shales with inhibited, potassium-based drilling fluids. J. Petrol. Tech. Sept. 1973, 1089–1100.Google Scholar
Ormerod, E.C. & Newman, A.C.D. (1983) Water sorption on Ca-saturated clays. II. Internal and external surfaces of montmorillonite. Clay Miner., 18, 289–299.Google Scholar
Philip, J.R. & Smiles, D.E. (1982) Macroscopic analysis of the behaviour of colloidal suspensions. Adv. Colloid Interf. Sci., 17, 83–103.Google Scholar
Roehl, E. A. & Hackett, J.L. (1982) A laboratory technique for screening shale inhibitors. 57th Ann. Fall Meet. Soc. Petr. Engrs., New Orleansy Louisiana, Paper No. SPE 11117.Google Scholar
Shainberg, I. & Kaiserman, A. (1969) Kinetics of the formation and breakdown of Ca-montmorillonite tactoids. Soil Sci. Soc. Am. Proc., 33, 547–551.CrossRefGoogle Scholar
Slade, R.C.T., Barker, J., Hirst, P.R., Halstead, T.K. & Reid, P.I. (1987) Conduction and diffusion in exchanged montmorillonite clays. Solid State Ionics,, 24, 289–295.Google Scholar
Smiles, D.E. & Harvey, E.G. (1973) Measurement of moisture diffusivity of wet swelling systems. Soil Sci., 116, 391–399.Google Scholar
Smiles, D.E. & Kirby, J.M. (1987) Aspects of one-dimensional filtration. Separation Sci. Tech., 22, 1405–1423.Google Scholar
Sposito, G. (1984) The Surface Chemistry of Soils. Oxford Univ. Press.Google Scholar
Sposito, G., Prost, R. & Gaultier, J.-P. (1983) Infrared spectroscopic study of adsorbed water on reduced-charge Na/Li-montmorillonites. Clays Clay Miner., 31, 9–16.Google Scholar
Steiger, R.P. (1984) Fundamentals and use of potassium/polymer drilling fluids to minimize drilling and completion problems associated with hydrateable days. J. Petrol. Tech. August 1982, 1661–1670.Google Scholar
Stokes, R J. & Robinson, R. A. (1949) Standard solutions for humidity control at 25°C. Ind. Eng. Chem. Sept. 1949, 2013.Google Scholar
Tessier, D. & Pedro, G. (1987) Mineralogical characterization of 2:1 clays in soils: Importance of the clay texture. Proc. Int. Clay Conf. Denver, 78–84.Google Scholar
Tettenhorst, R. & Roberson, H.E. (1973) X-ray diffraction aspects of montmorillonites. Am, Miner., 58, 73–80.Google Scholar
Touret, O., Pons, C.H., Tessier, D. & Tardy, Y. (1990) Etude de la repartition de Teau dans les argiles saturees Mg2+ aux fortes teneurs en eau. Clay Miner., 25, 217–233.CrossRefGoogle Scholar
Tuck, J.J., Hall, P. Hayes, M.H.B., Ross, D.K. & Hayter, J.B. (1985) Quasi-elastic scattering studies of the dynamics of intercalated molecules in charge-deficient layer silicates. II. High resolution measurements of the diffusion of water in montmorillonite and vermiculite. 7. Chem. Soc. Faraday Trans., 81, 833–846.Google Scholar
Van Olphen, H. (1977) An Introduction to Clay Colloid Chemistry, 2nd ed., Pergamon, Oxford.Google Scholar
Van Olphen, H. & Fripiat, J.J. (1979) Data Handbook for Clay Materials and other Non-Metallic Minerals. Pergamon Press, Oxford.Google Scholar
Viani, B.E., Low, P.F. & Roth, C.B. (1983) Direct measurement of the relation between interlayer force and interlayer distance in the swelling of montmorillonite. J. Colloid Interf. Sci., 93, 229–244.Google Scholar
Warkentin, B.P., BoltG.H. & Miller, R.D. (1957) Swelling pressure of montmorillonite. Soil Sci. Soc. Am. Proc., 22, 495–497.Google Scholar
Warkentin, B.P. & Schofield, R.K. (1960) Swelling pressures of dilute Na-montmorillonite pastes. Clays Clay Miner., 7, 343–349.Google Scholar
Wingrave, J.A., Kubena, E. Jr. , Douty, C.F., Whitfill, D.L. & Cords, D.P. (1987) New chemical package produces an improved shale inhibitive water based drilling fluid system. 45th Ann. Fall Meet. Soc. Petr. Engrs., Dallas, Texas, Paper No. SPE 16687.Google Scholar