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Hydroxyl-stretching bands ‘A’ and ‘Z’ in Raman and infrared spectra of kaolinites

Published online by Cambridge University Press:  09 July 2018

S. Shoval ,
S. Yariv ,
K. H. Michaelian ,
M. Boudeulle  and
G. Panczer
S. Shoval
Affiliation:
Geology Group, The Open University of Israel, 16, Klausner St. Tel-Aviv 61392, Israel
S. Yariv
Affiliation:
Department of Inorganic and Analytical Chemistry, The Hebrew University of Jerusalem, Jerusalem 91904, Israel
K. H. Michaelian
Affiliation:
Natural Resources Canada, CANMET Western Research Centre, Devon, Alberta, Canada T9G 1A8
M. Boudeulle
Affiliation:
LPCML, UMR 5620 CNRS, Université Claude Bernard Lyon 1, France
G. Panczer
Affiliation:
LPCML, UMR 5620 CNRS, Université Claude Bernard Lyon 1, France
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Abstract

The high frequency OH-stretching band in micro-Raman spectra of kaolinites consistently exhibits two partly overlapping components with varying relative intensities. These bands, labelled A and Z, are located at ~3700–3690 and 3690–3680 cm-1, respectively. Band Z displays greater intensity in Raman spectra of highly crystallized kaolinites which have large coherent domains. Both components are also observed in the curve fitted infrared (IR) spectra of kaolinites; band Z is stronger in IR spectra of highly crystallized samples. Data for kaolinites with different particle size support the idea that bands A and Z are the longitudinal optic and transverse optic modes of the high frequency OH-stretching band.

Type
Research Article
Information
Clay Minerals , Volume 34 , Issue 4 , December 1999 , pp. 551 - 563
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1999

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