Hostname: page-component-cd9895bd7-dzt6s Total loading time: 0 Render date: 2024-12-29T05:29:31.116Z Has data issue: false hasContentIssue false

The formation of a hydrotalcite coating on the aluminium alloy 6060 using a spray system

Published online by Cambridge University Press:  02 January 2018

Lingli Zhou*
Affiliation:
Department of Geoscience, Aarhus University, Høegh-Guldbergs Gade 2, DK-8000 Aarhus C, Denmark Key Laboratory of Mineral Resources, Institute of Geology and Geophysics, Chinese Academy of Sciences, 19 Beituchen Western Road, Chaoyang District, Beijing 100029, China
Henrik Friis
Affiliation:
Department of Geoscience, Aarhus University, Høegh-Guldbergs Gade 2, DK-8000 Aarhus C, Denmark
Melanie Roefzaad
Affiliation:
Siemens Corporate Technology, Borupvang 9, 2750 Ballerup, Denmark
Kasper Bondo Hansen
Affiliation:
Siemens Corporate Technology, Borupvang 9, 2750 Ballerup, Denmark
Sara Eisenhardt
Affiliation:
Siemens Corporate Technology, Borupvang 9, 2750 Ballerup, Denmark
Asger Andersen
Affiliation:
Siemens Corporate Technology, Borupvang 9, 2750 Ballerup, Denmark
Nikolaj Zangenberg
Affiliation:
Danish Technological Institute, Kongsvang Allé 29, 8000 Aarhus C, Denmark

Abstract

Coatings with the composition of Li-Al-NO3 hydrotalcite were formed on the Al alloy 6060 using a spray system. The coatings consist of crystals with a typical hydrotalcite structure. Dense, uniform and blade-like flakes cover completely the surface of the Al substrate. The coatings display a multi-layer structure with average thickness of ∼1000 nm. The hydrotalcite-coated samples performed better than those without coatings in salt-spray and filiform-corrosion tests, and further treatment involving sealing with a Mg acetate solution and dipping in a H2O2 + Ce-based solution improved the corrosion resistance ability.

Type
Research Article
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2015

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Ardelean, H., Fiaud, C. & Marcus, P. (2001) Enhanced corrosion resistance of magnesium and its alloys though the formation of cerium (and aluminium) oxide surface films. Materials and Corrosion, 52, 889—895.3.0.CO;2-0>CrossRefGoogle Scholar
Barisone, E., Girard, G., Tschopp, G., Nelis, T., Roske, L., De Puydt, Y. & Raynaud, P. (2011) Glow discharge optical emission spectroscopy: GD-OES, rapid analytical assistance for plasma film deposition. 18th international colloquium on plasma processes (CIP 2011). Google Scholar
Basile, F. & Vaccari, A. (2001) Applications of hydro-talcite-type anionic clays (layered double hydroxides) in catalysis. Pp. 285-321 in: Layered Double Hydroxides: Present and Future (V Rives, editor). Nova Publishers, New York.Google Scholar
Brindley, G.W. & Kikkawa, S. (1980) Thermal behavior of hydrotalcite and of anion-exchanged forms of hydro-talcite. Clays and Clay Minerals, 28, 8791.CrossRefGoogle Scholar
Buchheit, R.G. & Guan, H. (2004) Formation and characteristics of Al-Zn hydrotalcite coatings on galvanized steel. Journal of Coatings Technology Research, 1, 277290.CrossRefGoogle Scholar
Buchheit, R.G., Mamidipally, S.B., Schmutz, P. & Guan, H. (2002) Active corrosion protection in Ce-modified hydrotalcite conversion coatings. Corrosion, 58, 314.CrossRefGoogle Scholar
Buchheit, R.G., Guan, H., Mahajanam, S. & Wong, F. (2003) Active corrosion protection and corrosion sensing in chromate-free organic coatings. Progress in Organic Coatings, 47, 174182.CrossRefGoogle Scholar
Cavani, F., Trifirò, F. & Vaccari, A. (1991) Hydrotalcite-type anionic clays: Preparation, properties and applications. Catalysis Today, 11, 173301.CrossRefGoogle Scholar
Chen, J., Song, Y., Shan, D. & Han, E.H. (2012) Study of the in situ growth mechanism of Mg-Al hydrotalcite conversion film on AZ31 magnesium alloy. Corrosion Science, 63, 148158.CrossRefGoogle Scholar
Dabalà, M., Armelao, L., Buchberger, A. & Calliari, I. (2001) Cerium-based conversion layers on aluminium alloys. Applied Surface Science, 172, 312322.CrossRefGoogle Scholar
Frost, R.L., Bahfenne, S., Graham, I. & Reddy, B.J. (2008) The structure of selected magnesium carbonate minerals - a near infrared and mid-infrared spectro-scopic study. Polyhedron, 27, 20692076.CrossRefGoogle Scholar
Hinton, B.R.W. & Wilson, L. (1989) The corrosion inhibition of zinc with cerous chloride. Corrosion Science, 29, 967975.CrossRefGoogle Scholar
Kannan, S. (2006) Catalytic applications of hydrotalcite-like materials and their derived forms. Catalysis Surveys from Asia, 10, 117137.CrossRefGoogle Scholar
Kiyota, S., Valdez, V., Stoytcheva, M., Zlatev, R. & Bastidas, J.M. (2011) Anticorrosion behavior of conversion coatings obtained from unbuffered cerium salts solutions on AA6061-T6. Journal of Rare Earth, 29, 961968.CrossRefGoogle Scholar
Lin, J.K. & Uan, J.Y. (2009) Formation of Mg, Al-hydrotalcite conversion coating on Mg alloy in aqueous HCO3/CO3” and corresponding protection against corrosion by the coating. Corrosion Science, 51, 11811188.CrossRefGoogle Scholar
Lin, J.K., Hsia, C.L. & Uan, J.Y. (2007) Characterization of Mg, Al-hydrotalcite conversion film on Mg alloy and Cl and anion-exchangeability of the film in a corrosive environment. Scripta Materialia, 56, 927—930.Google Scholar
Mansfeld, F. & Kendig, M.W. (1988) Evaluation of anodized aluminum surfaces with electrochemical impedance spectroscopy. Journal of the Electrochemistry Society, 135, 828.CrossRefGoogle Scholar
McMurray, H.N. & Williams, G. (2004) Inhibition of filiform corrosion on organic-coated aluminum alloy by hydrotalcite-like anion-exchange pigments. Corrosion, 60, 219228.CrossRefGoogle Scholar
Miyata, S. (1983) Anion-exchange properties of hydro-talcite-like compounds. Clays and Clay Minerals, 31, 305311.CrossRefGoogle Scholar
Orthman, J., Zhu, H.Y. & Lu, G.Q. (2003) Use of anion clay hydrotalcite to remove coloured organics from aqueous solutions. Separation and Purification Technology, 31, 5359.CrossRefGoogle Scholar
Reichle, W.T. (1986) Synthesis of anionic clay minerals (mixed metal hydroxides, hydrotalcite). Solid State Ionics, 22, 135141.CrossRefGoogle Scholar
Ruggeri, R.T. & Beck, T.R. (1983) An analysis of mass transfer in filiform corrosion. Corrosion, 39, 45265.CrossRefGoogle Scholar
Syu, J.H., Uan, J.Y., Lin, M.C. & Lin, Z.Y. (2013) Optically transparent Li—Al—CO3 layered double hydroxide thin films on an AZ31 Mg alloy formed by electrochemical deposition and their corrosion resistance in a dilute chloride environment. Corrosion Science, 68, 238248.CrossRefGoogle Scholar
Taylor, R.M. (1984) The rapid formation of crystalline double hydroxy salts and other compounds by controlled hydrolysis. Clay Minerals, 19, 591—603.CrossRefGoogle Scholar
Valdez, B., Kiyota, S., Stoytcheva, M., Zlatev, R. & Bastidas, J.M. (2014) Cerium-based conversion coatings to improve the corrosion resistance of aluminium alloy 6061-T6. Corrosion Science, 87, 141149.CrossRefGoogle Scholar
Valente, J.S., Rodriguez-Gattorno, G., Valle-Orta, M. & Torres-Garcia, E. (2012) Thermal decomposition kinetics of MgAl layered double hydroxides. Materials Chemistry and Physics, 133, 621629.CrossRefGoogle Scholar
Wang, C., Jiang, F. & Wang, F. (2004) Cerium chemical conversion for aluminium alloy 2024-T3 and its corrosion resistance. Corrosion, 60, 237—243.Google Scholar
Wang, J., Li, D., Yu, X., Jing, X., Zhang, M. & Jiang, Z. (2010) Hydrotalcite conversion coating on Mg alloy and its corrosion resistance. Journal of Alloys and Compounds, 494, 271274.CrossRefGoogle Scholar
Wernick, S., Pinner, R. & Sheasby, P.G. (1987) The Surface Treatment and Finishing of Aluminum and its Alloys. Finishing Publications Ltd., Teddington, Middlesex, UK.Google Scholar
Williams, G. & McMurray, H.N. (2003) Anion-exchange inhibition of filiform corrosion on organic coated AA2024-T3 aluminum alloy by hydrotalcite-like pigments. Electrochemical and Solid-State Letters, 6, B9-B11.CrossRefGoogle Scholar
Williams, G. & McMurray, H.N. (2004) Inhibition of filiform corrosion on polymer coated AA2024-T3 by hydrotalcite-like pigments incorporating organic anions. Electrochemical and Solid-State Letters, 7, B13-B15.CrossRefGoogle Scholar
Zhang, W. & Buchheit, R.G. (2002) Hydrotalcite coating formation on Al-Cu-Mg alloys from oxidizing bath chemistries. Corrosion, 58, 591600.CrossRefGoogle Scholar