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Flow supercritical synthesis of brucite and magnesian T-O, T-O-T phyllosilicates: an opportunity to tune the structure with the solvent composition

Published online by Cambridge University Press:  04 September 2018

Marie Claverie ,
François Martin ,
Christel Careme ,
Christophe Le Roux ,
Pierre Micoud ,
Olivier Grauby  and
Cyril Aymonier
Marie Claverie
Affiliation:
Imerys, 2 Place Édouard Bouillères, Toulouse, 31100, France
François Martin*
Affiliation:
Géosciences Environnement Toulouse (GET, UMR 5563, UPS-CNRS-IRD-CNES, ERT 1074 Géomatériaux), 14 Avenue Édouard Belin, Toulouse, 31400, France
Christel Careme
Affiliation:
Imerys, 2 Place Édouard Bouillères, Toulouse, 31100, France
Christophe Le Roux
Affiliation:
Géosciences Environnement Toulouse (GET, UMR 5563, UPS-CNRS-IRD-CNES, ERT 1074 Géomatériaux), 14 Avenue Édouard Belin, Toulouse, 31400, France
Pierre Micoud
Affiliation:
Géosciences Environnement Toulouse (GET, UMR 5563, UPS-CNRS-IRD-CNES, ERT 1074 Géomatériaux), 14 Avenue Édouard Belin, Toulouse, 31400, France
Olivier Grauby
Affiliation:
Aix Marseille Université, CNRS, CINaM UMR 7325, Campus de Luminy, Marseille, 13288, France
Cyril Aymonier*
Affiliation:
CNRS, Univ. Bordeaux, ICMCB, UPR 9048, Pessac, 33600, France
*
*E-mail: [email protected]; [email protected]
*E-mail: [email protected]; [email protected]
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Abstract

This work presents the synthesis of minerals with a layered structure in supercritical water/ethanol mixtures to decrease the critical coordinates of the solvent regarding water. Depending on the water/ethanol ratio of the solvent, we obtained three different minerals adopting an octahedral brucitic sheet: (1) without a Si-tetrahedral sheet (O); (2) associated with one Si-tetrahedral sheet (T-O); or (3) intercalated between two Si-tetrahedral sheets (T-O-T). We have thus shown that ethanol in a supercritical water/ethanol mixture changes the solubility of silicon with a direct consequence on the formation of the tetrahedral silicon sheets and thus makes it possible to control the structure of the synthesized layered material.

Keywords

phyllosilicatesbrucitecontinuous-flow synthesissupercritical water/ethanol mixtures
Type
Article
Information
Clay Minerals , Volume 53 , Issue 3 , September 2018 , pp. 497 - 503
Copyright
Copyright © Mineralogical Society of Great Britain and Ireland 2018 

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Footnotes

This paper was originally presented during the session: ‘NT-10 Recent advances in applications of industrial clays’ of the International Clay Conference 2017.

Editor: G. E. Christidis

References

REFERENCES

Akerlof, G. (1932) Dielectric constants of some organic solvent–water mixtures at various temperatures. Journal of the American Chemical Society, 54, 4125–4139.Google Scholar
Akerlof, G. & Short, O.A. (1936) The dielectric constant of dioxane–water mixtures between 0 and 80°. Journal of the American Chemical Society, 58, 1241–1243.Google Scholar
Albright, P.S. & Gosting, L.J. (1946) Dielectric constants of the methanol–water system from 5 to 55°. Journal of the American Chemical Society, 68, 1061–1063.Google Scholar
Andreani, M., Grauby, O., Baronnet, A. & Muñoz, M. (2008) Occurrence, composition and growth of polyhedral serpentine. European Journal of Mineralogy, 20, 159–171.Google Scholar
Aymonier, C., Slostowski, C., Dumas, A., Micoud, P., Le Roux, C. & Martin, F. (2015) Process for the Continuous Preparation of Phyllomineral Synthetic Particles – WO 2015159006 Al.Google Scholar
Aymonier, C., Philippot, G., Erriguible, A. & Marre, S. (2018) Playing with chemistry in supercritical solvents and the associated technologies for advanced materials by design. The Journal of Supercritical Fluids, 134, 184–196.Google Scholar
Bandura, A.V. & Lvov, S.N. (2005) The ionization constant of water over wide ranges of temperature and density. Journal of Physical and Chemical Reference Data, 35, 15–30.Google Scholar
Barr-David, F. & Dodge, B.F. (1959) Vapor–liquid equilibrium at high pressures. The systems ethanol–water and 2-propanol–water. Journal of Chemical & Engineering Data, 4, 107–121.Google Scholar
Bazaev, A.R., Abdulagatov, I.M., Bazaev, E.A. & Abdurashidova, A. (2007) (p, v, T, x) Measurements of {(1 − x)H2O + xC2H5OH} mixtures in the near-critical and supercritical regions. The Journal of Chemical Thermodynamics, 39, 385–411.Google Scholar
Bergaya, F. & Lagaly, G. (2006) General introduction: clays, clay minerals, and clay science. Pp. 1–18 in: Handbook of Clay Science (Bergaya, F., Theng, B.K.G. & Lagaly, G., editors). Elsevier, New York, NY, USA.Google Scholar
Carretero, M.I. (2002) Clay minerals and their beneficial effects upon human health. A review. Applied Clay Science, 21, 155–163.Google Scholar
Cecilia, J.A., García-Sancho, C., Vilarrasa-García, E., Jiménez-Jiménez, J. & Rodriguez-Castellón, E. (2018) Synthesis, characterization, uses and applications of porous clays heterostructures: a review. The Chemical Record, 18, 1085–1104.Google Scholar
Cirillo, G., Kozlowski, M.A. & Spizzirri, U.G. (2018) Composite Materials for Food Packaging. John Wiley & Sons, Hoboken, NJ, USA.Google Scholar
Claverie, M., Dumas, A., Careme, C., Poirier, M., Le Roux, C., Micoud, P., Martin, F. & Aymonier, C. (2018) Synthetic talc and talc-like structures: preparation, features and applications. Chemistry – A European Journal, 24, 519–542.Google Scholar
Diez-Garcia, M., Gaitero, J.J., Dolado, J.S. & Aymonier, C. (2017) Ultra-fast supercritical hydrothermal synthesis of tobermorite under thermodynamically metastable conditions. Angewandte Chemie, 56, 3162–3167.Google Scholar
Ding, Z., Kloprogge, J.T., Frost, R.L., Lu, G.Q. & Zhu, H.Y. (2001) Porous clays and pillared clays-based catalysts. Part 2: a review of the catalytic and molecular sieve applications. Journal of Porous Materials, 8, 273–293.Google Scholar
Dumas, A., Claverie, M., Slostowski, C., Aubert, G., Careme, C., Le Roux, C., Micoud, P., Martin, F. & Aymonier, C. (2016) Fast-geomimicking using chemistry in supercritical water. Angewandte Chemie, 55, 9868–9871.Google Scholar
Fernández, D.P., Mulev, Y., Goodwin, A.R.H. & Sengers, J.M.H.L. (1995) A database for the static dielectric constant of water and steam. Journal of Physical and Chemical Reference Data, 24, 33–70.Google Scholar
Grauby, O., Baronnet, A., Devouard, B., Schoumacker, K. & Demirdjian, L. (1998) The chrysotile-polygonal serpentine lizardite suite synthesized from a 3MgO–2SiO2–excess H2O gel. Presented at: 7th International Symposium on Experimental Mineralogy, Petrology and Geochemistry.Google Scholar
Griswold, J., Haney, J.D. & Klein, V.A. (1943) Ethanol–water system – vapor–liquid properties at high pressure. Industrial & Engineering Chemistry, 35, 701–704.Google Scholar
Karaskova, E. & Mollin, U. (1993) Calculation of alkoxide and hydroxide ion activity ratios in the water–ethanol system 4. Chemical Papers, 37, 156–159.Google Scholar
Konta, J. (1995) Clay and man: clay raw materials in the service of man. Applied Clay Science, 10, 275–335.Google Scholar
Laaksonen, A., Kusalik, P.G. & Svishchev, I.M. (1997) Three-dimensional structure in water−methanol mixtures. The Journal of Physical Chemistry A, 101, 5910–5918.Google Scholar
Marshall, W.L. & Jones, E.V. (1974) Liquid–vapor critical temperatures of several aqueous–organic and organic–organic solution systems. Journal of Inorganic and Nuclear Chemistry, 36, 2319–2323.Google Scholar
Murray, H.H. (2000) Traditional and new applications for kaolin, smectite, and palygorskite: a general overview. Applied Clay Science, 17, 207–221.Google Scholar
Robert, J.-L. & Kodama, H. (1988) Generalization of the correlations between hydroxyl-stretching wavenumbers and composition of micas in the system K2O–MgO–Al2O3–SiO2–H2O: a single model for trioctahedral and dioctahedral micas. American Journal of Science, 288-A, 196–212.Google Scholar
Robert, J.-L., Beny, J.-M., Ventura, G.D. & Hardy, M. (1993) Fluorine in micas: crystal-chemical control of the OH-F distribution between trioctahedral and dioctahedral sites. European Journal of Mineralogy, 5, 7–18.Google Scholar
Rochester, C. (1972) The ionic products of water and methanol in methanol–water mixtures. Journal of the Chemical Society, Dalton Transactions, 1, 5–8.Google Scholar
Schaef, H.T., Loring, J.S., Glezakou, V.-A., Miller, Q.R.S., Chen, J., Owen, A.T., Lee, M.-S., Ilton, E.S., Felmy, A.R., McGrail, B.P. & Thompson, C.J. (2015) Competitive sorption of CO2 and H2O in 2:1 layer phyllosilicates. Geochimica et Cosmochimica Acta, 161, 248–257.Google Scholar
Zazenski, R., Ashton, W.H., Briggs, D., Chudkowski, M., Kelse, J.W., MacEachern, L., McCarthy, E.F., Nordhauser, M.A., Roddy, M.T. & Teetsel, N.M. (1995) Talc: occurrence, characterization, and consumer applications. Regulatory Toxicology and Pharmacology: RTP, 21, 218–229.Google Scholar