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Effect of mechanical activation on catalytic properties of Fe2O3-pillared bentonite for Fenton-like reaction

Published online by Cambridge University Press:  27 February 2018

G.T. Wei ,
Y.S. Li ,
L.Y. Zhang ,
Z.M. Li ,
Y. Deng ,
L.H. Shao  and
J .H. Mo
G.T. Wei
Affiliation:
School of Chemistry and Chemical Engineering, Guangxi University, Nanning, China, Ministry-Province Jointly-Constructed Cultivation Base for State Key Laboratory of Processing for Non-ferrous Metal and Featured Materials, Guangxi Zhuang Autonomous Region, Nanning, China
Y.S. Li
Affiliation:
School of Chemistry and Chemical Engineering, Guangxi University, Nanning, China, Ministry-Province Jointly-Constructed Cultivation Base for State Key Laboratory of Processing for Non-ferrous Metal and Featured Materials, Guangxi Zhuang Autonomous Region, Nanning, China
L.Y. Zhang*
Affiliation:
School of Chemistry and Chemical Engineering, Guangxi University, Nanning, China, Ministry-Province Jointly-Constructed Cultivation Base for State Key Laboratory of Processing for Non-ferrous Metal and Featured Materials, Guangxi Zhuang Autonomous Region, Nanning, China
Z.M. Li
Affiliation:
School of Chemistry and Chemical Engineering, Guangxi University, Nanning, China, Ministry-Province Jointly-Constructed Cultivation Base for State Key Laboratory of Processing for Non-ferrous Metal and Featured Materials, Guangxi Zhuang Autonomous Region, Nanning, China
Y. Deng
Affiliation:
School of Chemistry and Chemical Engineering, Guangxi University, Nanning, China, Ministry-Province Jointly-Constructed Cultivation Base for State Key Laboratory of Processing for Non-ferrous Metal and Featured Materials, Guangxi Zhuang Autonomous Region, Nanning, China
L.H. Shao
Affiliation:
School of Chemistry and Chemical Engineering, Guangxi University, Nanning, China, Ministry-Province Jointly-Constructed Cultivation Base for State Key Laboratory of Processing for Non-ferrous Metal and Featured Materials, Guangxi Zhuang Autonomous Region, Nanning, China
J .H. Mo
Affiliation:
School of Chemistry and Chemical Engineering, Guangxi University, Nanning, China, Ministry-Province Jointly-Constructed Cultivation Base for State Key Laboratory of Processing for Non-ferrous Metal and Featured Materials, Guangxi Zhuang Autonomous Region, Nanning, China
*
*E-mail: [email protected]
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Abstract

A layered composite of Fe2O3-pillared bentonite (Fe-P-Bet), used as a catalyst in a Fenton-like process, was prepared and then its mechanical activation was studied in detail. The optimum conditions for preparation of Fe-P-Bet and the effects of mechanical activation on the catalytic activity of Fe-P-Bet were investigated systematically. The impact of the mechanical activation on the catalytic activity was affected by the filling ratio of the grinding medium, by the combination of different sized milling balls, by the rotation speed of the planet carrier, by the milling time and by the powder-to-ball ratio. Compared with the removal ratio of orange II of 14.5%, catalysed by Fe-P-Bet, the removal ratio catalysed by activated Fe2O3-pillared bentonite (A-Fe-P-Bet) was as high as 93.6%, and A-Fe-P-Bet had the merit of good stability and only a small amount of Fe leaching during the Fenton-like process. The catalysts prepared were characterized by scanning electron microscopy, transmission electron microscopy, X-ray diffraction and by the BET method; A-Fe-P-Bet has a small particle size and a rough surface. The lattice distortion and decrease in the crystal size of α-Fe2O3, as well as damage to the layer structure of smectite in the bentonite, were the main reasons for the increase in the catalytic activity of A-Fe-P-Bet. The results indicated that mechanical activation was an easy and effective method for improving the catalytic activity of this bentonite-based layered composite and that A-Fe-P-Bet was a safe, ‘green’, catalyst material for use in Fenton-like oxidation during treatment of wastewater.

Keywords

mechanical activationbentoniteα-Fe2O3Fenton-likepowdercatalytic material
Type
Research Article
Information
Clay Minerals , Volume 52 , Issue 4 , December 2017 , pp. 439 - 451
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2017

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References

Ashrafizadeh, H. & Ashrafizaadeh, M. (2012) Influence of processing parameters on grinding mechanism in planetary mill by employing discrete element method. Advanced Powder Technology, 23, 708–716.Google Scholar
Babuponnusami, A. & Muthukumar, K. (2014) A review on Fenton and improvements to the Fenton process for wastewater treatment. Journal of Environmental Chemical Engineering, 2, 557–572.CrossRefGoogle Scholar
Barrett, E.P., Joyner, L.G. & Halenda, P.P. (1951) The determination of pore volume and area distributions in porous substances. 1. Computations from nitrogen isotherms. Journal of the American Chemical Society, 73, 373–380.Google Scholar
Benyounes, K. & Benmounah, A. (2016) Rheological and electrokinetic characterization of bentonite particles in aqueous phase in presence of KCl. Particulate Science and Technology, 34, 39–44.Google Scholar
Bokare, A.D. & Choi, W. (2014) Review of iron-free Fenton-like systems for activating H2O2 in advanced oxidation processes. Journal ofHazardous Materials, 275, 121–135.Google Scholar
Burmeister, C.F. & Kwade, A. (2013) Process engineering with planetary ball mills. Chemical Society Reviews, 42, 7660–7667.Google Scholar
Chen, J.X. & Zhu, L.Z. (2009) Comparative study of catalytic activity of different Fe-pillared bentonites in the presence of UV light and H2O2. Separation and Purification Technology, 67, 282–288.CrossRefGoogle Scholar
Chen, Q.Q., Wu, P.X., Li, Y.Y., Zhu, N.W. & Dang, Z. (2009) Heterogeneous photo-Fenton photodegradation of reactive brilliant orange X-GN over iron-pillared montmorillonite under visible irradiation. Journal of Hazardous Materials, 168, 901–908.Google Scholar
Choi, J., Han, Y., Kim, D., Park, S., Park, J., Park I & Kim, H. (2014) Synthesis and characterization of mesoporous silica from anorthite-clay mineral: role of mechanical activation. Materials Transactions, 55, 1895–1899.CrossRefGoogle Scholar
Cihanoglu, A., Gündüz, G. & Dükkancı M. (2015) Degradation of acetic acid by heterogeneous Fenton-like oxidation over iron containing ZSM-5 zoelites. Applied Catalysis B: Environmental, 165, 687–699.Google Scholar
Deris, L., Sharafi, S. & Akbari, G.H. (2014) Effect of milling speed on mechanical activation of Al/ZrO2/ H3BO3 system to prepare Al2O3-ZrB2 composite powder. Journal of Thermal Analysis and Calorimetry 115, 401–407.Google Scholar
Duan, J.M. & Gregory I (2003) Coagulation by hydrolysing metal salts. Advances in Colloid & Interface Science, 100-102, 475–502.Google Scholar
Feng, C., Sun, H.H., Li, S.Q., Camarillo, M.K., Stringfellow, W.T. & Liang, Y.Y. (2015) Treatment of oil-water emulsion from the machinery industry by Fenton's reagent. Water Science and Technology, 71, 1884–1892.Google Scholar
Flynn, C.M.F. Jr. (1984) Hydrolysis of inorganic iron (III) salts. Chemical Reviews, 84, 31–41.Google Scholar
Garrel, L., Bonetti, M., Tonucci, L., Alessandro, N. & Bressan, M. (2006) Photosensitized degradation of cyclohexanol by Fe (III) species in alkaline aqueous media. Journal of Photochemistry & Photobiology A Chemistry 179, 193–199.Google Scholar
Hu, S.H., Wu, Y.G., Yao, H.R., Lu, C. & Zhang, C.J. (2016) Enhanced Fenton-like removal of nitrobenzene via internal microelectrolysis in nano zerovalent iron/ activated carbon composite. Water Science and Technology, 73, 153–160.CrossRefGoogle ScholarPubMed
Khankhasaeva, S.T., Dambueva, D.V., Dashinamzhilova, E.T., Gil, A., Vicente, M.A. & Timofeeva, M.N. (2015) Fenton degradation of sulfanilamide in the presence of Al,Fe-pillared clay: Catalytic behavior and identifica-tion of the intermediates. Journal of Hazardous Materials, 293, 21–29.Google Scholar
Li, Y. & Zhang, F.S. (2010) Catalytic oxidation of methyl orange by an amorphous FeOOH catalyst developed from a high iron-containing fly ash. Chemical Engineering Journal, 158, 148–153.Google Scholar
Pereira, M.C., Oliveira, L.C.A. & Murad, E. (2012) Iron oxide catalysts: Fenton and Fenton-like reactions — a review. Clay Minerals, 47, 285–302.Google Scholar
Pouran, S.R., Raman, A.A.A. & Daud, W.M.A.W. (2014) Review on the application of modified iron oxides as heterogeneous catalysts in Fenton reactions. Journal of Cleaner Production, 64, 24–35.Google Scholar
Richmond, M.D. (2015) 1,2-dichlorobenzene pretreatment via phosphoric acid-mediated Fenton reagent. Water Environment Research, 87, 650–655.Google Scholar
Rosenkranz, S., Breitung-Faes, S. & Kwade, A. (2011) Experimental investigations and modelling of the ball motion in planetary ball mills. Powder Technology, 212, 224–230.Google Scholar
Shao, L.H., Wei, G.T., Wang, Y.Z., Li, Z.M., Zhang, L.Y., Zhao, S.K. & Zhou, M. (2016) Preparation and application of acidified/calcined red mud catalyst for catalytic degradation of butyl xanthate in Fenton-like process. Environmental Science & Pollution Research International, 23, 15202–15207.Google Scholar
Shin, H., Lee, S., Jung, H.S. & Kim, J.B. (2013) Effect of ball size and powder loading on the milling efficiency of a laboratory-scale wet ball mill. Ceramics International, 39, 8963–8968.Google Scholar
Spuhler, D., Rengifo-Herrera, J.A. & Pulgarin, C. (2010) The effect of Fe2+, Fe3+, H2O2 and the photo-Fenton reagent at near neutral pH on the solar disinfection (SODIS) at low temperatures of water containing Escherichia coli K12. Applied Catalysis B: Environmental, 96, 126–141.CrossRefGoogle Scholar
Takacs, L. (2002) Self-sustaining reactions induced by ball milling. Progress in Materials Science, 47, 355–414.Google Scholar
Terzica, A., Pezo, L., Andric, L. & Arsenovic, M. (2015) Effects of mechanical activation on the parameters of talc quality for ceramics production—chemometric approach. Composites Part B: Engineering, 79, 660–666.CrossRefGoogle Scholar
Tikhov, S.F., Sadykov, V.A., Valeev, K.R., Salanov, A.N., Cherepanova, S.V., Bespalko, Y.N., Ramanenkau, V.E., Piatsiushyk, Y.Y. & Dimov, S.V. (2015) Preparation of porous ceramo-metal composites through the stages of mechanical activation and hydrothermal partial oxi-dation of Me-Al powders. Catalysis Today, 246, 232–238.Google Scholar
Tunç, T. & Demirkıran, A.§. (2014) The effects of mechanical activation on the sintering and microstruc-tural properties of cordierite produced from natural zeolite. Powder Technology, 260, 7–14.Google Scholar
Wei, G.T., Fan, C.Y., Zhang, L.Y., Ye, R.C., Wei, T.Y. & Tong, Z.F. (2012) Photo-Fenton degradation of methyl orange using H3PW12O40 supported Fe-bentonite catalyst. Catalysis Communications, 17, 184–188.Google Scholar
Wei, G.T., Li, Z.M., Zhang, L.Y., Deng, Y., Shao, L.H. & Liu, Z.H. (2017) Improve the catalytic activity of FeOOH/ bentonite material by mechanical activation. Journal ofthe Chilean Chemical Society, 62, 3407–3410.Google Scholar
Xue, B., Guo, H., Liu, L. & Chen, M. (2015) Preparation, characterization and catalytic properties of yttrium-zirconium-pillared montmorillonite and their application in supported Ce catalysts. Clay Minerals, 50, 211–220.CrossRefGoogle Scholar
Zhang, L.Y., Cai, S.Y., Huang, K., Li, Z.M., Wei, G.T., Li, X.H., Mo, J.H. & Liang, Y.C. (2013) Preparation of H3PMo12O40/organobentonite by chemical immobil-ization method and its catalytic performance in photo-Fenton process. Desalination and Water treatment Journal, 51, 7815–7824.CrossRefGoogle Scholar
Zhang, L.Z., Zeng, H.H., Zeng, Y.M., Zhang, Z.H. & Zhao, X.F. (2014) Heterogeneous Fenton-like degradation of 4-chlorophenol using a novel FeIII-containing poly-oxometalate as the catalyst. Journal of Molecular Catalysis A: Chemical, 392, 202–207.Google Scholar