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Determination of layer-charge density of expandable 2:1 clay minerals in soils and loess sediments using the alkylammonium method

Published online by Cambridge University Press:  09 July 2018

G. Rühlicke  and
E. A. Niederbudde
G. Rühlicke
Affiliation:
Institut für Bodenkunde, T. U. München-Weihenstephan, 8050 Freising, FRG
E. A. Niederbudde
Affiliation:
Institut für Bodenkunde, T. U. München-Weihenstephan, 8050 Freising, FRG
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Abstract

The alkylammonium adsorption method for the determination of layer-charge density was slightly modified and applied to mixtures of expandable clay minerals (i.e. predominantly 18 Å minerals after glycerol sorption) from two loess samples and two soils (Haplaquept and Aquentic Chromudert) having different K-adsorption properties. The layer-charge density of the so-called 18 Å minerals from these sediments and soil samples varied between −0·23 and −0·85 per formula unit, which suggested the presence of different amounts of vermiculite within the 18 Å minerals. The amounts of these vermiculites were related to K-fixing and K-buffering properties of the different samples. High-resolution electron micrographs of vermiculites saturated with tetradecylammonium exhibited a basal spacing of 25 Å. It was confirmed, that the alkylammonium ions in the interlayers of the vermiculites formed a paraffin-type structure. In the fine clay from the loess samples an interstratification of vermiculite and illitic layers was observed.

Type
Research Article
Information
Clay Minerals , Volume 20 , Issue 3 , September 1985 , pp. 291 - 300
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1985

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