Hostname: page-component-78c5997874-g7gxr Total loading time: 0 Render date: 2024-11-07T21:10:10.851Z Has data issue: false hasContentIssue false
  • English
  • Français

Characterization of natural and chemically modified kaolinite from Mako (Senegal) to remove lead from aqueous solutions

Published online by Cambridge University Press:  27 February 2018

A. Mbaye ,
C. A. K. Diop ,
J. Miehe-Brendle ,
F. Senocq  and
F. Maury
A. Mbaye
Affiliation:
Laboratoire de Chimie Minérale et Analytique-Université Cheikh Anta Diop-Dakar-Sénégal
C. A. K. Diop*
Affiliation:
Laboratoire de Chimie Minérale et Analytique-Université Cheikh Anta Diop-Dakar-Sénégal
J. Miehe-Brendle
Affiliation:
Equipe Matériaux à Porosité Contrôlée, Institut de Science des Matériaux de Mulhouse (IS2M, UMR CNRS 7361. Université de Haute- Alsace, Institut de Recherche Jean-Baptiste Donnet, 3b rue Alfred Werner, 68093 Mulhouse cedex, France
F. Senocq
Affiliation:
CIRIMAT, ENSIACET, 4 allée E. Monso, BP 44362, 31030 Toulouse, cedex 4, France
F. Maury
Affiliation:
CIRIMAT, ENSIACET, 4 allée E. Monso, BP 44362, 31030 Toulouse, cedex 4, France
*
*E-mail: [email protected]
Get access Rights & Permissions [Opens in a new window]

Abstract

The chemical and sorption properties of clay minerals from the Mako area, Senegal, were investigated using FTIR spectroscopy, X-ray diffraction, scanning electron microscopy equipped with an X-ray energy dispersion spectrometer, thermal analysis and chemical analysis. The clay sample is essentially dominated by kaolinite and quartz as also shown by treatment with ethylene glycol and dimethylsulfoxide (DMSO). The clay fraction of this natural clay was organically modified by grafting with 3-aminopropyltriethoxysilane (APTES) in order to improve significantly its retention ability of heavy metals. The silane groups of the APTES reagent were partly grafted on the surface of platy kaolinite particles and the remaining ethoxy groups could be hydrolysed by aqueous treatment. The natural clay, its clay fraction and the organo-functionalized clay (with APTES) were investigated as adsorbents for the removal of Pb(II) from aqueous solutions. Evidence for an organic grafting has been demonstrated by comparing the spectroscopic characteristics of the natural clay and those of its chemically modified derivatives. The effects of different parameters (i.e. initial Pb(II) concentration and contact time) on the adsorption efficiency were studied. For an initial concentration of 10 mg L−1 Pb(II), the adsorption was maximized after 30 min contact time both for the raw material and its clay fraction and after 90 min for the APTES grafted clay. Although the maximum of sorption for the APTES grafted clay is reached with slower kinetics, this maximum amount of Pb(II) uptake at room temperature (Xmax) is significantly higher since it is 0.99 mg g−1 for the raw clay, 1.46 mg g−1 for its clay fraction and 3.02 mg g−1 for the organically modified clay, i.e. three times greater than the raw clay.

Keywords

kaolinitefunctionalized clayhybrid materialamino-compoundretention capacityheavy metal removallead
Type
Research Article
Information
Clay Minerals , Volume 49 , Issue 4 , September 2014 , pp. 527 - 539
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2014

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Barruseau, J.P., Duvail, C., Nehlig, P., Roger, J. & Serrano, O. (2009) Notice explicative de la carte géologique du bassin sédimentaire du Sénégal. Direction des Mines du Sénégal.Google Scholar
Beall, G.W. (2003) The use of organo-clays in water treatment. Applied Clay Science, 24, 11–20.Google Scholar
Bouna, L., Rhouta, B., Amjoud, M., Jada, A., Maury, F., Daoudi, L. & Senocq, F. (2010) Correlation between eletrokinetic mobility and ionic dyes adsorption of Moroccan stevensite. Applied Clay Science, 48, 527–530.Google Scholar
Bouna, L., Rhouta, B., Amjoud, M., Maury, F., Lafont, M.C., Jada, A., Senocq, F. & Daoudi, L. (2011) Synthesis, characterization and photocatalytic activity of TiO2 supported natural palygorskite microfibers. Applied Clay Science, 52, 301–311.Google Scholar
Celis, R., Hermosin, M.C. & Cornejo, J. (2000) Heavy metal adsorption by functionalized clays. Environmental Science and Technology, 34, 4593–4599.CrossRefGoogle Scholar
Chi, M. & Eggleton, R.A. (1999) Cation exchange capacity of kaolinite. Clays and Clay Minerals, 47, 174–180.CrossRefGoogle Scholar
de Faria, E.H., Ciuffi, K.J., Nassar, E.J., Vicente, M.A., Trujillano, R. & Calefi, P.S. (2010) Novel reactive amino-compound: Tris(hydroxymethyl)aminomethane covalently grafted on kaolinite. Applied Clay Science, 48, 516–521.Google Scholar
Dennis, H.R., Hunter, D.L., Chang, D., Kim, S., White, J.L., Cho, J.W. & Paul, D.R. (2001) Effect of melt processing conditions on the extent of exfoliation in organo-clay-based nanocomposites. Polymer, 42, 9513–9522.Google Scholar
Do, D.D. (1998) Adsorption Analysis: Equilibria and Kinetics. Imperial College Press, London.Google Scholar
Erdemoglu, M., Erdemoglu, S., Sayilkan, F., Akarsu, M., Sener, S. & Sayilkan, H. (2004) Organo-functional modified pyrophyllite: preparation, characterization and Pb(II) ion adsorption property. Applied Clay Science, 27, 41–52.CrossRefGoogle Scholar
Farmer, V.C. (1974) The Infrared Spectra of Minerals. Monograph 4, pp 331–363. Mineralogical Society, London.Google Scholar
Farmer, V.C. & Russell, J.D. (1964) The infrared spectra of layer silicates. Spectrochimica Acta, 20, 1149–1173.Google Scholar
Franco, F., Pérez-Maqueda, L.A. & Pérez-Rodríguez, J.L. (2004) The effect of ultrasound on the particle size and structural disorder of a well-ordered kaolinite. Journal of Colloid and Interface Science, 274, 107–117.Google Scholar
Frost, R.L., Kristof, J., Paroz, G.N. & Kloprogge, J.T. (1998) Molecular structure of dimethyl sulfoxide intercalated kaolinites. Journal of Physical Chemistry B, 102, 8519–8532.Google Scholar
Gómez-Romero, P. & Sanchez, C. (2004) Functional Hybrid Materials. Wiley-VCH, Weinheim.Google Scholar
Grim, R.E. (1953) Clay Mineralogy. McGraw-Hill Book Co., Inc., New York.Google Scholar
Groisman, L., Rav-Acha, C., Gerstl, Z. & Mingelgrin, U. (2004) Sorption of organic compounds of varying hydrophobicities from water and industrial wastewater by long- and short-chain organo-clays. Applied Clay Science. 24, 159–166.Google Scholar
Gupta, S.S. & Bhattacharyya, K.G. (2008) Immobilization of Pb(II), Cd(II) and Ni(II) ions on kaolinite and montmorillonite. Journal of Environmental Management, 87, 46–58.CrossRefGoogle Scholar
Harvey, C.C. & Murray, H.H. (1997) Industrial clays in the 21st century: a perspective of exploration, technology and utilization. Applied Clay Science, 11, 285–310.Google Scholar
He, H.P., Duchet, J., Galy, J. & Gerard, J.F. (2005) Grafting of swelling clay materials with 3-aminopropyltriethoxysilane. Journal of Colloid and Interface Science, 288, 171–176.CrossRefGoogle ScholarPubMed
Holtzapffel, T. (1985) Les minéraux argileux: préparation, analyse diffractométrique et détermination. Société géologique du nord, 12, 1–135.Google Scholar
Huang, P. & Fuerstenau, D.W. (2001) The effect of the adsorption of lead and cadmium ions on the interfacial behavior of quartz and talc. Colloids and Surfaces A. Physiochemical and Engineering Aspects, 177, 147–156.Google Scholar
Ikhsan, J., Johnson, B.B. & Wells, J.D. (1999) A comparative study of the adsorption of transition metals on kaolinite. Journal of Colloid and Interface Science, 217, 403–410.Google Scholar
Jiang, M., Wang, Q., Jin, X. & Chen, Z. (2009) Removal of Pb(II) from aqueous solution using modified and unmodified kaolinite clay. Journal of Hazardous Materials, 170, 332–339.CrossRefGoogle Scholar
Lagadic, I.L., Mitchell, M.K., Payne, B.D. (2001) Highly effective adsorption of heavy metal ions by a thiolfunctionalized magnesium phyllosilicate clay. Environmental Science and Technology, 35, 984–990.Google Scholar
Ledoux, R.L. & White, J.L. (1964) Infrared study of selective deuteration of kaolinite and halloysite at room temperature. Science, 145, 47–49.Google Scholar
Letaief, S. & Detellier, C. (2008) Interlayer grafting of glycidol (2,3-epoxy-1-propanol) on kaolinite. Canadian Journal of Chemistry, 86, 1–6.Google Scholar
Lothenbach, B., Furrer, G. & Schulin, R. (1997) Immobilization of heavy metals by polynuclear aluminium and montmorillonite compounds. Environmental Science and Technology, 31, 1452–1462.Google Scholar
Malakul, P., Srinivasan, K.R. & Wang, H.Y. (1998) Metal adsorption and desorption characteristics of surfactant modified clay complexes. Industrial and Engineering Chemistry Research, 37, 4296–4301.Google Scholar
Mbaye, A., Diop, C.A.K., Rhouta, B., Brendle, J., Senocq, F., Maury, F. & Diallo, D.P. (2012) Mineralogical and physico-chemical characterizations of clay from Keur Saër (Senegal). Clay Minerals, 47, 499–511.Google Scholar
Mercier, L. & Detellier, C. (1995) Preparation, characterization and applications as heavy metals sorbents of covalently grafted thiol functionalities on the interlamelar surface of montmorillonite. Environmental Science and Technology, 29, 1318–1323.Google Scholar
Murray, H.H. (2000) Traditional and New Applications for Kaolin, Smectite, and Palygorskite: a General Overview. Applied Clay Science, 17, 207–221.Google Scholar
Nakagaki, S., Benedito, F.L. & Wypych, F. (2004) Anionic iron(III) porphyrin immobilized on silanized kaolinite as catalyst for oxidation reactions. Journal of Molecular Catalysis A: Chemical, 217, 121–131.Google Scholar
Oyanedel-Craver, V.A. & Smith, J.A. (2006) Effect of quaternary ammonium cation loading and pH on heavy metal sorption to Ca bentonite and two organobentonites. Journal of Hazardous Materials, B137, 1102–1114.Google Scholar
Paul, D.R. & Robeson, L.M. (2008) Polymer nanotechnology: Nanocomposites. Polymer, 49, 3187–3204.Google Scholar
Pagenkopf, G.K. (1978) Introduction to Natural Water Chemistry. Marcel Dekker Inc., New York.Google Scholar
Petit, S. & Decarreau, A. (1990) Hydrothermal (200°C) synthesis and crystal chemistry of iron-rich kaolinites. Clay Minerals, 25, 181–196.CrossRefGoogle Scholar
Petit, S., Decarreau, A. Mosser, C., Ehret, G. & Grauby, O. (1995) Hydrothermal synthesis (250°C) of copper substituted kaolinites. Clay Minerals, 43, 482–494.CrossRefGoogle Scholar
Rao, M.M., Ramana, D.K., Seshaiah, K., Wang, C. & Chien, S.W.C. (2009) Removal of some metal ions by activated carbon prepared from Phaseolus aureus hulls. Journal of Hazardous Materials, 166, 1006–1013.CrossRefGoogle ScholarPubMed
Saikia, N.J., Bharali, D.J., Sengupta, P., Bordoloi, D., Goswamee, R.L., Saskia, P.C. & Borthakur, P.C. (2003) Characterization, beneficiation and utilization of a kaolinite clay from Assam, India. Applied Clay Science, 24, 93–103.Google Scholar
Sari, A., Tuzen, M., Citak, D. & Soylak, M. (2007) Equilibrium, kinetic and thermodynamic studies of adsorption of Pb(II) from aqueous solution onto Turkish kaolinite clay. Journal of Hazardous Materials, 149, 283–291.Google Scholar
Sarr, D., Fall, M., Ngom, P.M. & Ndiaye, M. (2011) Mechanical Behaviour of Pillow Lavas in Mako Supergroup: Case of South Mako Hill. International Journal of Geosciences, 4, 640–647.CrossRefGoogle Scholar
Shanmugharaj, A.M., Rhee, K.Y. & Ryu, S.H. (2006) Influence of dispersing medium on grafting of aminopropyltriethoxysilane in swelling clay materials. Journal of Colloid and Interface Science, 298, 854–859.CrossRefGoogle ScholarPubMed
Shu-qin, Y., Peng, Y., Hong-ping, H., Zong-hua, Q., Qing, Z., Jian-xi, Z. & Dong, L. (2012) Effect of reaction temperature on grafting of g-aminopropyltriethoxysilane (APTES) onto kaolinite. Applied Clay Science, 62-63, 8–14.Google Scholar
Srivasta, P., Singh, B. & Angove, M. (2005) Competitive adsorption behaviour of heavy metals on kaolinite, Journal of Colloid and Interface Science, 290, 28–38.Google Scholar
Stathi, P., Litina, K., Gournis, D., Giannopoulos, T.S. & Deligiannakis, Y. (2007) Physicochemical study of novel organo-clays as heavy metal ion adsorbents for environmental remediation. Journal of Colloid and Interface Science, 316, 298–309.Google Scholar
Theng, B.K.G. (1974) The Chemistry of Clay Organic Reactions. Adam Hilger, London.Google Scholar
Tonlé, I.K., Diaco, T., Ngameni, E. & Detellier, C. (2007) Nanohybrid kaolinite-based materials obtained from the interlayer grafting of 3-aminopropyl triethoxysilane and their potential use as electrochemical sensors. Chemistry of Materials, 19, 6629–6636.Google Scholar
Tunney, J.J. & Detellier, C. (1993) Interlamellar covalent grafting of organic units on kaolinite. Chemistry of Materials, 5, 747–748.Google Scholar
Tunney, J.J. & Detellier, C. (1997) Interlamellar amino functionalization of kaolinite. Canadian Journal of Chemistry, 75, 1766–1772.Google Scholar
Van der Marel, H.W. & Beutelspacher, S. (1976) Atlas of Infrared Spectroscopy of Clay Minerals and their Admixtures, 397 pp. Elsevier, Amsterdam.Google Scholar
Vansant, E.F., Van der Voort, P. & Vrancken, K.C. (1995) Characterization and Chemical Modification of the Silica Surface. Elsevier, Amsterdam.Google Scholar
Vizcayno, C. Gutierrez, R.M., Castello, R., Rodriguez, E. & Guerrero, C.E. (2010) Pozzolan obtained by mechanochemical and thermal treatments of kaolin. Applied Clay Science, 49, 405–413.Google Scholar
Vengris, T., Binkiene, R. & Sveikauskaite, A. (2001) Nickel, copper, and zinc removal from wastewater by a modified clay sorbent. Applied Clay Science, 18, 183–190.Google Scholar
Wang, C., Shi, H., Zhang, P. & Li, Y. (2011) Synthesis and characterization of kaolinite/TiO2 nano-photocatalysts. Applied Clay Science, 53, 646–649.Google Scholar
Wang, S., Dong, Y., He, M., Chen, L. & Yu, X. (2009) Characterization of GMZ bentonite and its application in the adsorption of Pb(II) from aqueous solutions. Applied Clay Science, 43, 164–171.Google Scholar
Wilson, M.J. (1994) Clay Mineralogy: Spectroscopic and Chemical Determinative Methods, 18–60. Chapman and Hall, London, UK.Google Scholar
Xi, Y., Zhou, Q., Frost, R.L. & He, H., (2007) Thermal stability of octadecyltrimethyl ammonium bromide modified montmorillonite organo-clay. Journal of Colloid and Interface Science, 311, 347–353.Google Scholar
Yariv, S. (2002) Introduction to organo-clay complexes and interactions. Pp 39–112 in: Organo-clay complexes and interactions (S. Yariv & H. Cross, editors). Marcel Dekker Inc., New York.Google Scholar