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Characterization of clays and the technology of Roman ceramics production

Published online by Cambridge University Press:  17 September 2018

Letizia Ceccarelli ,
Maurizio Pietro Bellotto ,
Marco Caruso ,
Cinzia Cristiani ,
Giovanni Dotelli ,
Paola Gallo Stampino ,
Giuseppina Gasti  and
Luca Primavesi
Letizia Ceccarelli*
Affiliation:
University of Cambridge, McDonald Institute for Archaeological Research, Downing Street, Cambridge CB2 3ER, UK
Maurizio Pietro Bellotto
Affiliation:
Politecnico di Milano, CMIC – Dipartimento di Chimica, Materiali e Ingegneria Chimica ‘G. Natta’, Piazza Leonardo da Vinci 32, I-20133 Milano, Italy
Marco Caruso
Affiliation:
Politecnico di Milano, Materials Testing Laboratory, via Celoria 3, 20133 Milan, Italy
Cinzia Cristiani
Affiliation:
Politecnico di Milano, CMIC – Dipartimento di Chimica, Materiali e Ingegneria Chimica ‘G. Natta’, Piazza Leonardo da Vinci 32, I-20133 Milano, Italy
Giovanni Dotelli
Affiliation:
Politecnico di Milano, CMIC – Dipartimento di Chimica, Materiali e Ingegneria Chimica ‘G. Natta’, Piazza Leonardo da Vinci 32, I-20133 Milano, Italy
Paola Gallo Stampino
Affiliation:
Politecnico di Milano, CMIC – Dipartimento di Chimica, Materiali e Ingegneria Chimica ‘G. Natta’, Piazza Leonardo da Vinci 32, I-20133 Milano, Italy
Giuseppina Gasti
Affiliation:
Politecnico di Milano, CMIC – Dipartimento di Chimica, Materiali e Ingegneria Chimica ‘G. Natta’, Piazza Leonardo da Vinci 32, I-20133 Milano, Italy
Luca Primavesi
Affiliation:
Politecnico di Milano, CMIC – Dipartimento di Chimica, Materiali e Ingegneria Chimica ‘G. Natta’, Piazza Leonardo da Vinci 32, I-20133 Milano, Italy
*
*E-mail: [email protected]
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Abstract

The recent discovery of a Roman ceramics manufacturing workshop at Montelabate (Perugia, Italy), in use from the first century BC until the late-fourth to fifth centuries AD, offers a unique opportunity to study the technical processes for producing Roman amphorae. Ancient and modern clays were sampled and analysed; they do not differ significantly, supporting the hypothesis of the exploitation of the rich local clay source that allowed a continuity of production. Characterization of the clays was performed using geotechnical methods (Atterberg limits and size distribution) and by thermogravimetric and differential thermogravimetric analysis, Fourier-transform infrared spectroscopy, X-ray diffraction and X-ray fluorescence analyses. The material was suitable for pottery making with the addition of calcite and quartz sand temper. Production waste and discarded materials as well as good-quality products were also analysed with the same methodology. It is therefore possible to reconstruct the ancient technology by defining the recipe for the production of the amphorae and their firing temperature on the basis of the decomposition of clay materials and the presence of newly formed minerals.

Keywords

clay characterizationanalytical methodsceramics productionRoman technologyamphorae
Type
Article
Information
Clay Minerals , Volume 53 , Issue 3 , September 2018 , pp. 413 - 429
Copyright
Copyright © Mineralogical Society of Great Britain and Ireland 2018 

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Footnotes

Guest Associate Editor: N. Fagel

This paper was originally presented during the session: ‘CZ-01 – Clays for ceramics’ of the International Clay Conference 2017.

(Present address: Politecnico di Milano, CMIC – Dipartimento di Chimica, Materiali e Ingegneria Chimica ‘G. Natta’, Piazza Leonardo da Vinci 32, I-20133 Milano, Italy)

References

REFERENCES

ASTM D422 (2007) Standard Test Method for Particle-Size Analysis of Soils. ASTM International, West Conshohocken, PA, USA.Google Scholar
ASTM D854 (2014) Standard Test Methods for Specific Gravity of Soil Solids by Water Pycnometer. ASTM International, West Conshohocken, PA, USA.Google Scholar
ASTM D2216 (2010) Standard Test Methods for Laboratory Determination of Water (Moisture) Content of Soil and Rock by Mass. ASTM International, West Conshohocken, PA, USA.Google Scholar
ASTM D4318 (2017) Standard Test Methods for Liquid Limit, Plastic Limit, and Plasticity Index of Soils. ASTM International, West Conshohocken, PA, USA.Google Scholar
Beringen, F.L., Kolk, H.J. & Windle, D. (1982) Cone penetration and laboratory testing in marine calcareous sediments. Pp. 179–209 in: Proceedings of the Symposium on Geotechnical Properties, Behavior, and Performance of Calcareous Soils. ASTM STP 77 (Demars, K.R. & Chaney, R.C., editors). American Society for Testing and Materials, Philadelphia, PA, USA.Google Scholar
Ceccarelli, L. (2017) Production and trade in central Italy in the roman period: the amphora workshop of Montelabate in Umbria. Papers of the British School at Rome, 85, 109–141.Google Scholar
Ceccarelli, L., Rossetti, I., Primavesi, L. & Stoddart, S. (2016) Non-destructive method for the identification of ceramic production by portable X-rays fluorescence (pXRF). A case study of amphorae manufacture in central Italy. Journal of Archaeological Science: Reports, 10, 253–262.Google Scholar
Comodi, P., Nazzareni, S., Perugini, D. & Bergamini, M. (2006) Technology and provenance of roman ceramics from Scoppieto, Italy: a mineralogical and petrological study. Periodico di Mineralogia, 75, 95–112.Google Scholar
De Bonis, A., Cultrone, G., Grifa, C., Langella, A. & Morra, V. (2014) Clays from the Bay of Naples (Italy): new insight on ancient and traditional ceramics. Journal of the European Ceramic Society, 34, 3229–3244.Google Scholar
De Bonis, A., Cultrone, G., Grifa, C., Langella, A., Leone, A.P., Mercurio, M. & Morra, V. (2017) Different shades of red: the complexity of mineralogical and physicochemical factors influencing the colour of ceramics. Ceramics International, 43, 8065–8074.Google Scholar
Dondi, M., Ercolani, G., Fabbri, B. & Marsigli, M. (1998) An approach to the chemistry of pyroxenes formed during the firing of Ca-rich silicate ceramics. Clay Minerals, 33, 443–452.Google Scholar
El Ouahabi, M., Daoudi, L., Hatert, F. & Fagel, N. (2015) Modified mineral phases during clay ceramic firing. Clays and Clay Minerals, 63, 404–413.Google Scholar
Eramo, G. & Maggetti, M. (2013) Pottery kiln and drying oven from Aventicum (2nd century AD, Ct. Vaud, Switzerland): raw materials and temperature distribution. Applied Clay Science, 82, 16–23.Google Scholar
Fabbri, B., Gualtieri, S. & Shoval, S. (2014) The presence of calcite in archeological ceramics. Journal of the European Ceramic Society, 34, 1899–1911.Google Scholar
Hunt, A.M.W. & Speakman, R.J. (2015) Portable XRF analysis of archaeological sediments and ceramics. Journal of Archaeological Science, 53, 626–638.Google Scholar
Ihli, J., Wong, W.C., Noel, E.H., Kim, Y.Y., Kulak, A.N., Christenson, H.K., Duer, M.J. & Meldrum, F.C. (2014) Dehydration and crystallization of amorphous calcium carbonate in solution and in air. Nature Communications, 5, 3169.Google Scholar
Klug, H.P. & Leroy, E.A. (1974) X-Ray Diffraction Procedures for Polycrystalline and Amorphous Materials, 2nd Edition. John Wiley and Sons, Hoboken, NJ, USA.Google Scholar
Larson, A.C. & von Dreele, R.B. (1994) General Structure Analysis System (GSAS). Los Alamos National Laboratory Report LAUR, 86–748.Google Scholar
Li, X.-G., Lv, Y., Ma, B.-G., Wang, W.-Q. & Jian, S.-W. (2017) Decomposition kinetic characteristics of calcium carbonate containing organic acids by TGA. Arabian Journal of Chemistry, 10, S2534–S2538.Google Scholar
Maritan, L., Nodari, L., Mazzoli, C., Milano, A. & Russo, U. (2006) Influence of firing conditions on ceramic products: experimental study on clay rich in organic matter. Applied Clay Science, 31, 1–15.Google Scholar
Mitchel, J. & Soga, K. (2005) Fundamentals of Soil Behavior, 3rd Edition. John Wiley & Sons, Hoboken, NJ, USA.Google Scholar
Panella, C. (1989) Le anfore italiche del II secolo d.C. Pp. 139–178 in: Amphores Romaines et Histoire Économique: Dix Ans de Recherche. Actes, du Colloque, de Sienne (22–24 Mai 1986). École Française de Rome, Rome, Italy.Google Scholar
Rao, A.S., Phanikumar, B.R. & Sharma, R.S. (2004) Prediction of swelling characteristics of remoulded and compacted expansive soils using free swell index. Quarterly Journal of Engineering Geology and Hydrogeology, 37, 217–226.Google Scholar
Rathossi, C. & Pontikes, Y. (2010a) Effect of firing temperature and atmosphere on ceramics made of NW Peloponnese clay sediments. Part I: Reaction paths, crystalline phases, microstructure and colour. Journal of the European Ceramic Society, 30, 1841–1851.Google Scholar
Rathossi, C. & Pontikes, Y. (2010b) Effect of firing temperature and atmosphere on ceramics made of NW Peloponnese clay sediments: Part II. Chemistry of pyrometamorphic minerals and comparison with ancient ceramics. Journal of the European Ceramic Society, 30, 1853–1866.Google Scholar
Rodriguez-Blanco, J.D., Shaw, S. & Benning, L.G. (2011) The kinetics and mechanisms of amorphous calcium carbonate (ACC) crystallization to calcite, via vaterite. Nanoscale, 3, 265–271.Google Scholar
Rodríguez, C., Bermúdez Coronel-Prats, R., Barone, G., Cultrone, G., Mazzoleni, P. & Tanasi, D. (2015) Petrographic and chemical characterization of Bronze Age pottery from the settlement of Mount San Paolillo (Catania, Italy). Rendiconti Lincei, 26, 485–497.Google Scholar
Rowe, R.K. (2012) Geotechnical and Geoenvironmental Engineering Handbook. Springer Science & Business Media, Berlin, Germany.Google Scholar
Skempton, A.W. (1953) The colloidal ‘activity’ of clays. Pp. 57–61 in: Proceedings of the third International Conference on Soil Mechanics and Foundation Engineering, Organizing Committee, Zurich, Switzerland.Google Scholar
Stoddart, S., Barone, P.M., Bennett, J., Ceccarelli, L., Cifani, G., Clackson, J., della Giovampaola, I., Ferrara, C., Fulminante, F., Licence, T., Malone, C., Matacchioni, L., Mullen, A., Nomi, F., Pettinelli, E., Redhouse, D. & Whitehead, N. (2012) Opening the frontier: the Gubbio–Perugia frontier in the course of history. Papers of the British School at Rome, 80, 257–294.Google Scholar
Vagenas, N. (2003) Quantitative analysis of synthetic calcium carbonate polymorphs using FT-IR spectroscopy. Talanta, 59, 831–836.Google Scholar
Whitehead, N. (1994) The Roman countryside. Pp. 188–203 in: Territory, Time and State. The Archaeological Development of the Gubbio Basin (Stoddart, S. & Malone, C., editors). Cambridge University Press, Cambridge, UK.Google Scholar
Zampori, L., Dotelli, G., Gallo Stampino, P., Cristiani, C., Zorzi, F. & Finocchio, E. (2012) Thermal characterization of a montmorillonite, modified with polyethylene-glycols (PEG1500 and PEG4000), by in situ HT-XRD and FT IR: formation of a high-temperature phase. Applied Clay Science, 59–60, 140–147.Google Scholar