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Adsorption of Pb(II) on raw and organically modified Jordanian bentonite

Published online by Cambridge University Press:  02 January 2018

I. Hamadneh ,
R. Abu-Zurayk ,
B. Abu-Irmaileh ,
A. Bozeya  and
A. H. Al-Dujaili
I. Hamadneh
Affiliation:
Department of Chemistry, Faculty of Science, The University of Jordan, P.O. Box 11942, Amman, Jordan
R. Abu-Zurayk
Affiliation:
Hamdi Mango Center for Scientific Research, The University of Jordan, P.O. Box 11942, Amman, Jordan
B. Abu-Irmaileh
Affiliation:
Hamdi Mango Center for Scientific Research, The University of Jordan, P.O. Box 11942, Amman, Jordan
A. Bozeya
Affiliation:
Hamdi Mango Center for Scientific Research, The University of Jordan, P.O. Box 11942, Amman, Jordan
A. H. Al-Dujaili*
Affiliation:
Department of Chemistry, Faculty of Science, The University of Jordan, P.O. Box 11942, Amman, Jordan
*
E-mail:[email protected]
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Abstract

A comparative study using bentonite (BT), hexadecyltrimethylammonium-modified bentonite (BT-HDTMA) and phenyl fatty hydroxamic acid-modified bentonite (BT-PFHA) as adsorbents for the removal of Pb(II) has been proposed. These adsorbents were characterized by X-ray diffraction, X-ray fluorescence, Fourier-transform infrared spectroscopy and surface area measurement. Cation exchange capacity was also determined in this study. The adsorbent capabilities for Pb(II) from aqueous solution were investigated, and the optimal experimental conditions including adsorption time, adsorbent dosage, the initial concentration of Pb(II), pH and temperature that might influence the adsorption performance were also investigated. The experimental equilibrium adsorption data were tested by four widely used two-parameter equations, the Langmuir, Freundlich, Dubinin- Radushkevich (D-R) and Temkin isotherms. The monolayer adsorption capacities of BT, BT-HDTMA and BT-PFHA for Pb(II) were 149.3, 227.3 and 256.4 mg/g, respectively. The experimental kinetic data were analysed by pseudo-first order, pseudo-second order and intraparticle diffusion kinetics models. The experimental data fitted very well with the pseudo-second order kinetic model. Determination of the thermodynamic parameters, ΔG, ΔH and ΔS showed the adsorption to be feasible, spontaneous and exothermic.

Keywords

adsorptionbentonitefatty hydroxamic acidPb(II)surfactant
Type
Research Article
Information
Clay Minerals , Volume 50 , Issue 4 , September 2015 , pp. 485 - 496
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2015

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References

Abdulla, N.I., Al-Haidary A.M.A., Al-Jeboori, M.I., Zanganah F.H.H., Al-Azawi, S.R.F. & Al-Dujaili, A. H. (2012) Kinetics and equilibrium adsorption study of lead (II) onto low cost clays. Environmental Engineering Management Journal, 11, 483—491.Google Scholar
Ahmed, M.J. & Theydan, S.K. (2013) Microporous activated carbon from Siris seed pods by microwave-induced KOH activation for metronidazole adsorption. Journal of Analytical and Applied Pyrolysis, 99, 101–109.Google Scholar
Al-Degs, Y., Khraisheh, M.A.M. & Tutunji, M.F. (2001) Sorption of lead ions on diatomite and manganese oxides modified diatomite. Water Research, 35, 3724–3728.Google Scholar
Al-Dujaili, A.H., Awwad, A.M. & Salem, N.M. (2012) Biosorption of cadmium (II) onto loquat leaves (Eriobotrya japonica) and their ash from aqueous solution, equilibrium, kinetics, and thermodynamic studies. International Journal of Industrial Chemistry, 3, 1–7.Google Scholar
Al-Haidary, A.M.A., Zanganah F.H.H., Al-Azawi S.R.F., Khalili, F.I. & Al-Dujaili A.H. (2011) A study on using date palm fibers and leaf base of palm as adsorbents for Pb(II) ions from its aqueous solution. Water, Air, & Soil Pollution, 214, 73–82.Google Scholar
Alkaram, U.F., Mukhlis, A.A. & Al-Dujaili A.H. (2009) The removal of phenol from aqueous solutions by adsorption using surfactant-modified bentonite and kaolinite. Journal of Hazardous Materials, 169, 324–332.Google Scholar
Al-Karam, U.F., de Namor A.F.D., Derwish, G.A.W. & Al-Dujaili A.H. (2012) Removal of chromium, copper, cadmium and lead ions from aqueous solutions by diatomaceous earth. Environmental Engineering Management Journal, 11, 811—819.Google Scholar
Bayramoglu, G., Bekta, S. & Yakup, A.M. (2003) Biosorption of heavy metal ions on immobilized white-rot fungus Trametes versi color. Journal of Hazardous Materials, B 101, 285–300.Google Scholar
BergayaF. & VayerM. (1997) CEC of clays: measurement by adsorption of a copper ethylenediamine complex. Applied Clay Science, 12, 275–280.Google Scholar
Bhattacharjee, S., Chakrabarty, S., Maity, S., Kar, S., Thakur, P. & Bhattacharyya, G. (2003) Removal of lead from contaminated water bodies using sea nodule as an adsorbent. Water Research, 37, 3954–3966.Google Scholar
Dubinin, M.M. & Radushkevich, L.V. (1947) The equation of the characteristic curve of activated charcoal. Proceedings of the Academy of Sciences, Physical Chemistry Section, USSR, 55, 331–333.Google Scholar
Eren, E. (2008) Removal of copper ions by modified Unye clay, Turkey. Journal of Hazardous Materials, 159, 235–244.Google Scholar
Farhan, A.M., Salem, N.M., Al-Dujaili, A.H. & Awwad, A. M. (2012) Biosorption studies of Cr(VI) ions from electroplating wastewater by walnut shell powder. American Journal of Environmental Engineering, 2, 188–195.Google Scholar
Farhan, A.M., Al-Dujaili, A.H. & Awwad, A.M. (2013) Equilibrium and kinetic studies of cadmium(II) and lead(II) ions biosorption onto Ficus carcia leaves. International Journal of Industrial Chemistry, 4, 24.Google Scholar
Freundlich, H. (1906) Adsorption in solution. Physical Chemical Society, 40, 1361–1368.Google Scholar
Furniss, B.S., Hannaford, A.J., Smith, P.W.G. & Tatchell, A. R. (1989) Vogel's Textbook of Practical Organic Chemistry 5th edition. Longman Scientific & Technology, New York.Google Scholar
Greluk, M. & Hubicki, Z. (2009) Sorption of SPADNS azo dye on polystyrene anion exchangers: Equilibrium and kinetic studies. Journal of Hazardous Materials, 172, 289–527.Google Scholar
Gunay, A., Arslankaya, E. & Tosun, I. (2007) Lead removal from aqueous solution by natural and pretreated clinoptilolite: adsorption equilibrium and kinetics. Journal of Hazardous Materials, 146, 362—371.Google Scholar
Hao, L.Y., Song, H.J. & Zhang, L.C. (2012) SiO2/graphene composite for highly selective adsorption of Pb(II) ion. Journal of Colloid and Interface Science, 369, 381–87.Google Scholar
Ho, Y.S. & McKay, G. (1999) Pseudo-second order model for sorption processes. Process Biochemistry, 34, 451–465.Google Scholar
Hoidy, W.H., Ahmad, M.B., Al-Mulla E.A.J., Yunus, W.M.Z.& Ibrahim N.B. (2010) Synthesis and characteriza¬tion of fatty hydroxamic acids from triacylglycerides. Journal ofOleo Science, 59, 15–19.Google Scholar
Jahangirian, H., Haron, M.J., Yusof, N.A., Silong, S., Kassim, A., Moghaddam, R.R., Peyda, M. & Gharayebi Y (2011) Enzymatic synthesis of fatty hydroxamic acid derivatives based on palm kernel oil. Molecules, 16, 6634–6644.Google Scholar
Jiang, M.Q., Wang, Q.P., Jin X.Y & Chen, Z.L. (2009) Removal of Pb(II) from aqueous solution using modified and unmodified kaolinite clay. Journal of Hazardous Materials, 170, 332–339.Google Scholar
Jovic-Jovicic, N.P., Milutinovic-Nikolic, A.D., Zunic, M.J., MojovicZ.D., Bankovic, P.T., Gržetic, I.A. & Jovanovic, D.M. (2013) Synergic adsorption of Pb2+ and reactive dye-RB5 on two series of organomodified bentonites. Journal of Contaminant Hydrology, 150, 1—11.Google Scholar
Khan, A.A. & Singh, R.P. (1987) Adsorption thermo-dynamics of carbofuran on Sn(IV) arseno silicate in H+, Na+ and Ca2+ forms. Colloid Surfaces, 24, 33-42.Google Scholar
Kim, Y., Kim, C., Choi, I., Rengraj, S. & Yi, J. (2004) Arsenic removal using mesoporous alumina prepared via a templating method. Environmental Science & Technology, 38, 924–931.Google Scholar
Kooli, F. (2014) Organo-bentonites with improved cetyl-trimethyl-ammonium contents. Clay Minerals, 49, 683–692.Google Scholar
Krishna, B.S., Murty, D.S.R. & Prakash B.S.J. (2000) Thermodynamics of chromium (IV) anionic species sorption onto surfactant-modified montmorillonite clay. Journal of Colloid and Interface Science, 229, 230–236.Google Scholar
Krishnan, A.A. & Anirudhan, T.S. (2002) Removal of P. (II) in the presence of organic ligand from aqueous solution using activated carbon. Indian Journal of Environmental Protection, 22, 52–59.Google Scholar
Lagergren, S. (1898) About the theory of so-called adsorption of soluble substances. Kungliga Svenska Vetenskapsakademiens Handlingar, 24, 1—39.Google Scholar
Langmuir, I. (1918) The adsorption of gases on plane surfaces of glass, mica and platinum. Journal of the American Chemical Society, 40, 1361–1403.Google Scholar
Li, Z., Yao, M., Lin, J., Yang, B., Zhang, X. & Lei, L. (2013) Pentachlorophenol sorption in the cetyltrimethylam-monium bromide/bentonite one-step process in single and multiple solute systems. Journal of Chemical & Engineering Data, 58, 2610–2615.Google Scholar
Mello F.G.A., Ciminelli, V.S.T. & Vasconcelos, W.L. (2009) Smectite organofunctionalized with thiol groups for adsorption of heavy metal ions. Applied Clay Science, 42, 410–414.Google Scholar
Mohapatra, M., Rout, K., Mohapatra B.K & Anand, S. (2009) Sorption behavior of Pb(II) and Cd(II) on iron ore slime and characterization of metal ion loaded sorbent. Journal of Hazardous Materials, 166, 1506–1513.Google Scholar
Onyang, M.S., Kojima, A. & Kuchar, D. (2006) Uptake of fluoride by A. + pretreated low-silica synthetic zeolites: Adsorption equilibrium and rate studies. Separation Science and Technology, 41, 683–704.Google Scholar
Potgieter J.H. (1991) Adsorption of methylene blue on activated carbon: an experiment illustrating both the Langmuir and Freundlich isotherms. Journal of Chemical Education, 68, 349–350.Google Scholar
Rawajfih, Z. & Nsour, N. (2006) Characteristics of phenol and chlorinated phenols sorption onto surfactant-modified bentonite. Journal of Colloid and Interface Science, 298, 39-49.Google Scholar
Richards, S. & Bouazza, A. (2007) Phenol adsorption in organo-modified basaltic clay and bentonite. Applied Clay Science, 37, 133–142.Google Scholar
Saha, P., Chowdhury, S., Gupta, S. & Kumar, I. (2010) Insight into adsorption equilibrium, kinetics and thermodynamics of malachite green onto clayey soil of Indian origin. Chemical Engineering Journal, 165, 874–882.Google Scholar
Salem, N.M., Awwad, A.M. & Al-Dujaili A.H. (2012) Biosorption of Pb(II), Zn(II) and Cd(II) from aqueous solution by (Eriobotrya japonica) loquat bark. International Journal of Environmental Protection, 2 (11), 1–7.Google Scholar
Saravanane, R., Sundararajan, T. & Reddy, S.S. (2002) Efficiency of chemically modified low cost adsorbents for the removal of heavy metals from waste water: a comparative study. Indian Journal of Environmental Health, 44, 78–87.Google Scholar
Sari, A., Tuzen, M. & Soylak, M. (2007) Adsorption of P. (II) and Cr(III) from aqueous solution on Celtek clay. Journal of Hazardous Materials, 144, 41–46.Google Scholar
Senturka, H.B., Ozdesa, D., Gundogdua, A., Durana, C. & Soylakb, M. (2009) Removal of phenol from aqueous solutions by adsorption onto organomodified Tirebolu bentonite: Equilibrium, kinetic and thermo-dynamic study. Journal of Hazardous Materials, 172, 353–362.Google Scholar
Shotyk, W. & LeRoux, G. (2005) Biogeochemistry and cycling of lead. Pp. 239—276 in: Metal Ions in Biological Systems, Vol. 43: Biogeochemical Cycles of Elements (A. Sigel, H. Sigel & R.K.O. Sigel, editors). CRC Press, Boca Raton, Florida, USA.Google Scholar
Simsek, S., Baybas, D., Kocyigit, M.C. & Yildirim, H. (2014) Organoclay modified with lignin as a new adsorbent for removal of Pb2+ and UO2+2. Journal of Radioanalytical and Nuclear Chemistry, 299, 283–292.Google Scholar
Temkin, M.I. & Pyzhev V (1940) Kinetics of ammonia synthesis on promoted iron catalysts. A cta Physicochimica URSS, 12, 327–356.Google Scholar
Tewari, P.N., Vasudevan, B. & Guha, K. (2005) Study of biosorption of Cr(VI) by Mucor hiemalis. Biochemical Engineering Journal, 23, 185—192.Google Scholar
Unuabonah, E.I., Adebowale, K.O., Owolabi, B.I., Yang, L. Z. & Kong, L.X. (2008) Adsorption of Pb(II) and C. (II) from aqueous solutions onto sodium tetraborate-modified kaolinite clay: Equilibrium and thermo-dynamic studies. Hydrometallurgy, 93, 1–9.Google Scholar
Wang, Y., Jiang, X., Zhou, L., Wang, C., Liao, Y., Duan, M. & Jiang, X. (2013) A comparison of new gemini surfactant modified clay with its monomer modified one: Characterization and application in methyl orange removal. Journal of Chemical & Engineering Data, 58, 1760–1771.Google Scholar
Wang, G., Chen, K., Li, W., Wan, D., Hu, Q. & Lu, L. (2014) Synthesis of magnetic modified organobentonite as adsorbent for degradation of orange II. Advanced Materials Research (Durnten-Zurich, Switzerland). 838-841, 2306–2309.Google Scholar
Weber, W.J. & Morris, J.C. (1963) Kinetics of adsorption on carbon from solutions. Journal of Sanitary Engineering Division, Proceedings of the American Society of Civil Engineers, 89, 31—60.Google Scholar
Xi, Y., Mallavarapu, M. & Naidu, R. (2010) Preparation, characterization of surfactants-modified clay minerals and nitrate adsorption. Applied Clay Science, 48, 92–96.Google Scholar
Xue, Y.J., Hou, H.B. & Zhu, S.J. (2009) Competitive adsorption of copper(II), cadmium(II), lead(II) and zinc(II) onto basic oxygen furnace slag. Journal of Hazardous Materials, 162, 391–401.Google Scholar
Yao, Q., Xie, J., Liu, J., Kang, H. & Liu Y (2014) Adsorption of lead ions using a modified lignin hydrogel. Journal of Polymer Research, 21, 465-480.Google Scholar
Zhao, D.L., Sheng, G.D. & Hu, J. (2011) The adsorption of Pb(II) on Mg2Al layered double hydroxide. Chemical Engineering Journal, 171, 167—174Google Scholar
Zubair, A., Bhatti, H.N., Hanif, M.A. & Shafqat, F. (2008) Kinetic and equilibrium modeling for Cr(III) and, C. (VI) removal from aqueous solutions by Citrus reticulata waste biomass. Water, Air, & Soil Pollution, 191,305–318.Google Scholar