Hostname: page-component-cd9895bd7-dk4vv Total loading time: 0 Render date: 2024-12-29T00:22:57.677Z Has data issue: false hasContentIssue false
  • English
  • Français

Adsorption of lead by kaolinite, montmorillonite, goethite and ferrihydrite: performance and mechanisms based on quantitative analysis

Published online by Cambridge University Press:  09 December 2022

Xiao Mao ,
Haibo Liu Open the ORCID record for Haibo Liu [Opens in a new window] ,
Ziyang Chu ,
Tianhu Chen ,
Xuehua Zou ,
Dong Chen Open the ORCID record for Dong Chen [Opens in a new window] ,
Xuemei Zhang  and
Jinchao Hu
Xiao Mao
Affiliation:
Key Laboratory of Nano-Minerals and Pollution Control of Anhui Higher Education Institutes, Hefei University of Technology, Hefei 230009, China
Haibo Liu*
Affiliation:
Key Laboratory of Nano-Minerals and Pollution Control of Anhui Higher Education Institutes, Hefei University of Technology, Hefei 230009, China
Ziyang Chu
Affiliation:
Key Laboratory of Nano-Minerals and Pollution Control of Anhui Higher Education Institutes, Hefei University of Technology, Hefei 230009, China
Tianhu Chen
Affiliation:
Key Laboratory of Nano-Minerals and Pollution Control of Anhui Higher Education Institutes, Hefei University of Technology, Hefei 230009, China
Xuehua Zou
Affiliation:
Key Laboratory of Nano-Minerals and Pollution Control of Anhui Higher Education Institutes, Hefei University of Technology, Hefei 230009, China
Dong Chen
Affiliation:
Key Laboratory of Nano-Minerals and Pollution Control of Anhui Higher Education Institutes, Hefei University of Technology, Hefei 230009, China
Xuemei Zhang
Affiliation:
Key Laboratory of Nano-Minerals and Pollution Control of Anhui Higher Education Institutes, Hefei University of Technology, Hefei 230009, China
Jinchao Hu
Affiliation:
Key Laboratory of Nano-Minerals and Pollution Control of Anhui Higher Education Institutes, Hefei University of Technology, Hefei 230009, China
*
*Email: [email protected]
Get access Rights & Permissions [Opens in a new window]

Abstract

This work elucidated the performance and mechanisms of Pb2+ adsorption by kaolinite, montmorillonite, goethite and ferrihydrite using batch experiments. The contributions of various adsorption mechanisms were quantified using a stepwise extraction method. Several characterizations (scanning electron microscopy, X-ray diffraction, Fourier-transform infrared spectroscopy, point of zero charge analysis and X-ray fluorescence) were utilized to analyse the physicochemical properties and the potential adsorption mechanisms. The results indicated that the adsorption processes of montmorillonite and goethite approached equilibrium within 20 min, while 60 min were required for the adsorption processes of kaolinite and ferrihydrite. The adsorption processes of Pb2+ by the four minerals best fit the pseudo-second order model. The adsorption capacities of the four minerals for Pb2+ followed the order: montmorillonite > goethite > ferrihydrite > kaolinite, and the maximum adsorption capacities were 69.20, 46.95, 34.32 and 18.62 mg g–1, respectively. The stepwise extraction test showed that the adsorption mechanism of Pb2+ was dominated by ion exchange for montmorillonite, precipitation and complexation for goethite and complexation for kaolinite and ferrihydrite.

Keywords

adsorption mechanismleadquantitativesoil minerals
Type
Article
Information
Clay Minerals , Volume 57 , Issue 3-4 , September 2022 , pp. 230 - 240
Copyright
Copyright © The Author(s), 2022. Published by Cambridge University Press on behalf of The Mineralogical Society of Great Britain and Ireland

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Footnotes

Associate Editor: Balwant Singh

References

Adebayo, G.B., Adegoke, H.I. & Fauzeeyat, S. (2020) Adsorption of Cr(VI) ions onto goethite, activated carbon and their composite: kinetic and thermodynamic studies. Applied Water Science, 10, 213.CrossRefGoogle Scholar
Ahmad, Z., Gao, B., Mosa, A., Yu, H., Yin, X., Bashir, A. et al. (2018) Removal of Cu(II), Cd(II) and Pb(II) ions from aqueous solutions by biochars derived from potassium-rich biomass. Journal of Cleaner Production, 180, 437–449.CrossRefGoogle Scholar
Al-Ghouti, M.A. & Da'Ana, D.A. (2020) Guidelines for the use and interpretation of adsorption isotherm models: a review. Journal of Hazardous Materials, 393, 122383.CrossRefGoogle ScholarPubMed
Bedelean, H., Măicăneanu, A., Burcă, S. & Stanca, M. (2009) Removal of heavy metal ions from wastewaters using natural clays. Clay Minerals, 44, 487–495.CrossRefGoogle Scholar
Bourliva, A., Michailidis, K., Sikalidis, C., Filippidis, A. & Betsiou, M. (2013) Lead removal from aqueous solutions by natural Greek bentonites. Clay Minerals, 48, 771–787.CrossRefGoogle Scholar
Cao, Y., Xiao, W., Shen, G., Ji, G., Zhang, Y., Gao, C. et al. (2019) Carbonization and ball milling on the enhancement of Pb(II) adsorption by wheat straw: competitive effects of ion exchange and precipitation. Bioresource Technology, 273, 70–76.CrossRefGoogle ScholarPubMed
Chen, M.A. & Kocar, B.D. (2018) Radium sorption to iron (hydr)oxides, pyrite, and montmorillonite: implications for mobility. Environmental Science & Technology, 52, 4023–4030.CrossRefGoogle ScholarPubMed
Fang, Q., Chen, B., Lin, Y. & Guan, Y. (2014) Aromatic and hydrophobic surfaces of wood-derived biochar enhance perchlorate adsorption via hydrogen bonding to oxygen-containing organic groups. Environmental Science & Technology, 48, 279–288.CrossRefGoogle ScholarPubMed
Gan, W., Shang, X., Li, X., Zhang, J. & Fu, X. (2019) Achieving high adsorption capacity and ultrafast removal of methylene blue and Pb2+ by graphene-like TiO2@C. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 561, 218–225.CrossRefGoogle Scholar
Gu, S., Kang, X., Wang, L., Lichtfouse, E. & Wang, C. (2019) Clay mineral adsorbents for heavy metal removal from wastewater: a review. Environmental Chemistry Letters, 17, 629–654.CrossRefGoogle Scholar
Guo, Y.X., Liu, J.H., Gates, W.P. & Zhou, C.H. (2020) Organo-modification of montmorillonite. Clays and Clay Minerals, 68, 601–622.CrossRefGoogle Scholar
Jung, K., Lee, S.Y., Choi, J. & Lee, Y.J. (2019) A facile one-pot hydrothermal synthesis of hydroxyapatite/biochar nanocomposites: adsorption behavior and mechanisms for the removal of copper(II) from aqueous media. Chemical Engineering Journal, 369, 529–541.CrossRefGoogle Scholar
Lai, L., He, Y., Zhou, H., Huang, B., Yao, G. & Lai, B. (2021) Critical review of natural iron-based minerals used as heterogeneous catalysts in peroxide activation processes: characteristics, applications and mechanisms. Journal of Hazardous Materials, 416, 125809.CrossRefGoogle ScholarPubMed
Lin, J., Sun, M., Su, B., Owens, G. & Chen, Z. (2019) Immobilization of cadmium in polluted soils by phytogenic iron oxide nanoparticles. Science of the Total Environment, 659, 491–498.CrossRefGoogle ScholarPubMed
Liu, D., Yuan, P., Liu, H., Cai, J., Tan, D., He, H. et al. (2013) Quantitative characterization of the solid acidity of montmorillonite using combined FTIR and TPD based on the NH3 adsorption system. Applied Clay Science, 80–81, 407–412.CrossRefGoogle Scholar
Ma, J., Lei, M., Weng, L., Li, Y., Chen, Y., Islam, M.S. et al. (2019) Fractions and colloidal distribution of arsenic associated with iron oxide minerals in lead-zinc mine-contaminated soils: comparison of tailings and smelter pollution. Chemosphere, 227, 614–623.CrossRefGoogle ScholarPubMed
Mbaye, A., Diop, C.A.K., Miehe-Brendle, J., Senocq, F. & Maury, F. (2014) Characterization of natural and chemically modified kaolinite from Mako (Senegal) to remove lead from aqueous solutions. Clay Minerals, 49, 527–539.CrossRefGoogle Scholar
Mouni, L., Belkhiri, L., Bollinger, J., Bouzaza, A., Assadi, A., Tirri, A. et al. (2018) Removal of Methylene Blue from aqueous solutions by adsorption on kaolin: kinetic and equilibrium studies. Applied Clay Science, 153, 38–45.CrossRefGoogle Scholar
Notini, L., Latta, D.E., Neumann, A., Pearce, C.I., Sassi, M., N Diaye, A.T. et al. (2018) The role of defects in Fe(II)-goethite electron transfer. Environmental Science & Technology, 52, 2751–2759.CrossRefGoogle ScholarPubMed
Otunola, B.O. & Ololade, O.O. (2020) A review on the application of clay minerals as heavy metal adsorbents for remediation purposes. Environmental Technology & Innovation, 18, 100692.CrossRefGoogle Scholar
Pehlivan, E., Özkan, A.M., Dinç, S. & Parlayici, S. (2009) Adsorption of Cu2+ and Pb2+ ion on dolomite powder. Journal of Hazardous Materials, 167, 1044–1049.Google ScholarPubMed
Penido, E.S., Melo, L.C.A., Guilherme, L.R.G. & Bianchi, M.L. (2019) Cadmium binding mechanisms and adsorption capacity by novel phosphorus/magnesium-engineered biochars. Science of the Total Environment, 671, 1134–1143.CrossRefGoogle Scholar
Qu, C., Du, H., Ma, M., Chen, W., Cai, P. & Huang, Q. (2018) Pb sorption on montmorillonite–bacteria composites: a combination study by XAFS, ITC and SCM. Chemosphere, 200, 427–436.CrossRefGoogle ScholarPubMed
Qu, J., Tian, X., Jiang, Z., Cao, B., Akindolie, M.S., Hu, Q. et al. (2020a) Multi-component adsorption of Pb(II), Cd(II) and Ni(II) onto microwave-functionalized cellulose: kinetics, isotherms, thermodynamics, mechanisms and application for electroplating wastewater purification. Journal of Hazardous Materials, 387, 121718.CrossRefGoogle Scholar
Qu, J., Yuan, Y., Meng, Q., Zhang, G., Deng, F., Wang, L. et al. (2020b) Simultaneously enhanced removal and stepwise recovery of atrazine and Pb(II) from water using β-cyclodextrin functionalized cellulose: characterization, adsorptive performance and mechanism exploration. Journal of Hazardous Materials, 400, 123142.CrossRefGoogle ScholarPubMed
Ramola, S., Belwal, T., Li, C.J., Wang, Y.Y., Lu, H.H., Yang, S.M. et al. (2020) Improved lead removal from aqueous solution using novel porous bentonite– and calcite–biochar composite. Science of the Total Environment, 709, 136171.CrossRefGoogle ScholarPubMed
Rui, D., Wu, Z., Ji, M., Liu, J., Wang, S. & Ito, Y. (2019) Remediation of Cd- and Pb-contaminated clay soils through combined freeze–thaw and soil washing. Journal of Hazardous Materials, 369, 87–95.CrossRefGoogle ScholarPubMed
Schwertmann, U. & Cornell, R.M. (2008). Iron Oxides in the Laboratory: Preparation and Characterization. John Wiley & Sons, Hoboken, NJ, USA, 188 pp.Google Scholar
Shen, Z., Zhang, Y., Jin, F., McMillan, O. & Al-Tabbaa, A. (2017) Qualitative and quantitative characterisation of adsorption mechanisms of lead on four biochars. Science of the Total Environment, 609, 1401–1410.CrossRefGoogle ScholarPubMed
Tang, Q., Tang, X., Li, Z., Chen, Y., Kou, N. & Sun, Z. (2009) Adsorption and desorption behaviour of Pb(II) on a natural kaolin: equilibrium, kinetic and thermodynamic studies. Journal of Chemical Technology & Biotechnology, 84, 1371–1380.CrossRefGoogle Scholar
Tessier, A., Campbell, P.G. & Bisson, M. (1979) Sequential extraction procedure for the speciation of particulate trace metals. Analytical Chemistry, 51, 844–851.CrossRefGoogle Scholar
Trivedi, P., Dyer, J.A. & Sparks, D.L. (2003) Lead sorption onto ferrihydrite. 1. A macroscopic and spectroscopic assessment. Environmental Science & Technology, 37, 908–914.Google ScholarPubMed
Uddin, M.K. (2017) A review on the adsorption of heavy metals by clay minerals, with special focus on the past decade. Chemical Engineering Journal, 308, 438–462.CrossRefGoogle Scholar
Vhahangwele, M. & Mugera, G.W. (2015) The potential of ball-milled South African bentonite clay for attenuation of heavy metals from acidic wastewaters: simultaneous sorption of Co2+, Cu2+, Ni2+, Pb2+, and Zn2+ ions. Journal of Environmental Chemical Engineering, 3, 2416–2425.CrossRefGoogle Scholar
Wu, J., Wang, T., Wang, J., Zhang, Y. & Pan, W. (2021) A novel modified method for the efficient removal of Pb and Cd from wastewater by biochar: enhanced the ion exchange and precipitation capacity. Science of the Total Environment, 754, 142150.CrossRefGoogle ScholarPubMed
Wu, P., Zhang, Q., Dai, Y., Zhu, N., Dang, Z., Li, P. et al. (2011) Adsorption of Cu(II), Cd(II) and Cr(III) ions from aqueous solutions on humic acid modified Ca-montmorillonite. Geoderma, 164, 215–219.CrossRefGoogle Scholar
Yang, K., Zhou, C., Li, C., Dou, S., Li, X., Wang, X. et al. (2021) Efficient removal of Sb(V) in textile wastewater through novel amorphous Si-doped Fe oxide composites: phase composition, stability and adsorption mechanism. Chemical Engineering Journal, 407, 127217.CrossRefGoogle Scholar
Yin, H., Tan, N., Liu, C., Wang, J., Liang, X., Qu, M. et al. (2016) The associations of heavy metals with crystalline iron oxides in the polluted soils around the mining areas in Guangdong Province, China. Chemosphere, 161, 181–189.CrossRefGoogle ScholarPubMed
Yu, J., Zeng, X., Wu, S., Wang, L. & Liu, G. (2007) Preparation and properties of montmorillonite modified asphalts. Materials Science and Engineering: A, 447, 233–238.CrossRefGoogle Scholar
Zhang, J., Li, L., Li, Y. & Yang, C. (2017) Microwave-assisted synthesis of hierarchical mesoporous nano-TiO2/cellulose composites for rapid adsorption of Pb2+. Chemical Engineering Journal, 313, 1132–1141.CrossRefGoogle Scholar
Zhang, Y., Zou, X., Liu, H., Chen, Y., Dong, S., Ji, M. et al. (2022) Comparative study of mineral with different structures supported Fe–Ni catalysts for steam reforming of toluene. Fuel (Guildford), 315, 123253.CrossRefGoogle Scholar
Zhong, X., Chen, Z., Li, Y., Ding, K., Liu, W., Liu, Y. et al. (2020) Factors influencing heavy metal availability and risk assessment of soils at typical metal mines in eastern China. Journal of Hazardous Materials, 400, 123289.CrossRefGoogle ScholarPubMed
Zhou, S.Q., Niu, Y.Q., Liu, J.H., Chen, X.X., Li, C.S., Gates, W.P. et al. (2022) Functional montmorillonite/polymer coatings. Clays and Clay Minerals, 70, 209–232.CrossRefGoogle Scholar
Zhu, R., Chen, Q., Zhou, Q., Xi, Y., Zhu, J. & He, H. (2016) Adsorbents based on montmorillonite for contaminant removal from water: a review. Applied Clay Science, 123, 239–258.CrossRefGoogle Scholar