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Adsorption of cetyltrimethyl ammonium bromide surfactant for organophilization of palygorskite clay

Published online by Cambridge University Press:  07 September 2021

Rhaul P. Silva ,
Alisson G.B. Gois ,
Michele O. Ramme ,
Tereza N. Castro Dantas ,
Jennys L.M. Barillas  and
Vanessa C. Santanna Open the ORCID record for Vanessa C. Santanna [Opens in a new window]
Rhaul P. Silva
Affiliation:
Graduate Program in Petroleum Engineering, Federal University of Rio Grande do Norte, RN, CEP 59072-970, Brazil
Alisson G.B. Gois
Affiliation:
Graduate Program in Petroleum Engineering, Federal University of Rio Grande do Norte, RN, CEP 59072-970, Brazil
Michele O. Ramme
Affiliation:
Graduate Program in Petroleum Engineering, Federal University of Rio Grande do Norte, RN, CEP 59072-970, Brazil
Tereza N. Castro Dantas
Affiliation:
Graduate Program in Petroleum Engineering, Federal University of Rio Grande do Norte, RN, CEP 59072-970, Brazil
Jennys L.M. Barillas
Affiliation:
Graduate Program in Petroleum Engineering, Federal University of Rio Grande do Norte, RN, CEP 59072-970, Brazil
Vanessa C. Santanna*
Affiliation:
Graduate Program in Petroleum Engineering, Federal University of Rio Grande do Norte, RN, CEP 59072-970, Brazil
*
*E-mail: [email protected]
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Abstract

This work determines the optimal palygorskite (Plg) content (maximum surfactant adsorption point) to achieve organophilization using the cationic surfactant cetyltrimethyl ammonium bromide (CTAB) at various concentrations. Adsorption assays were carried out in a finite bath after varying the content of Plg and CTAB in solution. In those assays, the effects of time, temperature, pH and thermodynamic characteristics were studied. The results were analysed using the Langmuir, Freundlich, Dubinin–Radushkevich and Tempkin adsorption models. The increase in clay content in the dispersion leads to a decrease in adsorption of surfactant on the clay. It was possible to obtain the optimal Plg content to achieve organophilization at various concentrations of CTAB surfactant. The experimental data fitted well to the Freundlich model. The Dubinin–Radushkevich and Tempkin isotherms confirmed the chemical adsorption of CTAB on Plg clay.

Keywords

adsorptionorganoclayorganophilizationpalygorskite
Type
Article
Information
Clay Minerals , Volume 56 , Issue 2 , June 2021 , pp. 140 - 147
Copyright
Copyright © The Author(s), 2021. Published by Cambridge University Press on behalf of The Mineralogical Society of Great Britain and Ireland

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Footnotes

Associate Editor: Huaming Yang

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