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Synthesis and optical properties of composites based on ZnS nanoparticles embedded in layered magadiite

Published online by Cambridge University Press:  09 July 2018

Yufeng Chen*
Affiliation:
Department of Chemistry, Nanchang University, Jiangxi, 330031, P.R. China
Gensheng Yu
Affiliation:
Department of Chemistry, Nanchang University, Jiangxi, 330031, P.R. China
*

Abstract

Composites based on ZnS nanparticles embedded in layered magadiite were synthesized via a three step process : protonation of Na-magadiite, ion exchange in order to introduce Zn(NH3)42+ in the interlayer space, and addition of Na2S to form ZnS particles in the interlayer space of magadiite. The composites obtained were characterized by X-ray power diffraction (XRD), Scanning Electron Microscopy coupled with Energy Dispersive Spectroscopy (SEM-EDS), Transmission Electron Microscopy (TEM), Raman spectroscopy, Photoluminscence spectra (PL), and UV-visible transmission spectra (UV-vis). Results indicated that ZnS nanoparticles embedded in magadiite presented different optical properties and photoluminescence enhancement properties compared with those of uncovered ZnS particles (without host magadiite).

Type
Research Article
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2013

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