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Surface modification of halloysite nanotubes grafted by dodecylamine and their application in reinforcing polytetrafluoroethylene

Published online by Cambridge University Press:  24 May 2019

Zhi-Lin Cheng ,
Xing-Yu Chang  and
Zan Liu
Zhi-Lin Cheng*
Affiliation:
School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, China
Xing-Yu Chang
Affiliation:
School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, China
Zan Liu
Affiliation:
School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, China
*
*E-mail: [email protected]
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Abstract

The modification of halloysite nanotubes (HNTs) as fillers is very effective at improving the performance of polymers. A novel modification of HNTs through grafting dodecylamine onto their surfaces was conducted here. Owing to the improvement in dispersibility of HNTs in polytetrafluoroethylene (PTFE), the mechanical properties and wear resistance (in particular) of the dodecylamine-modified HNT-filled PTFE composite were enhanced significantly.

Keywords

PTFEHNTsdodecylaminegraftingmechanical properties
Type
Article
Information
Clay Minerals , Volume 54 , Issue 2 , June 2019 , pp. 219 - 225
Copyright
Copyright © Mineralogical Society of Great Britain and Ireland 2019 

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Footnotes

Associate Editor: Pilar Aranda

References

Bischoff, E., Simon, D.A., Schrekker, H.S., Lavorgna, M., Ambrosio, L., Liberman, S.A. & Mauler, R.S. (2016) Ionic liquid tailored interfaces in halloysite nanotube/heterophasic ethylene–propylene copolymer nanocomposites with enhanced mechanical properties. European Polymer Journal, 82, 82–92.Google Scholar
Carroll, D. & Starkey, H.C. (1971) Reactivity of cay minerals with acids and alkalies. Clays and Clay Minerals, 19, 321–333.Google Scholar
Cheng, Z.L., Chang, X.Y., Liu, Z. & Qin, D.Z. (2017) Halloysite nanotubes–reinforced PTFE nanocomposites with high performance. Clay Minerals, 52, 427–438.Google Scholar
Cheng, Z.L. & Sun, W. (2016) Structure and physical properties of halloysite nanotubes. Acta Petrolei Sinica (Petroleum Processing Section), 32, 150–155.Google Scholar
Drits, V.A., Sakharov, B.A. & Hillier, S. (2018) Phase and structural features of tubular halloysite (7 Å). Clay Minerals, 53, 691–720.Google Scholar
Handge, U.A., Hedicke-Hochstotter, K. & Altstadt, V. (2010) Composites of polyamide 6 and silicate nanotubes of the mineral halloysite: influence of molecular weight on thermal, mechanical and rheological properties. Polymer, 51, 2690–2699.Google Scholar
Luca, V. & Thomson, S. (2000) Intercalation and polymerisation of aniline within a tubular aluminosilicate. Journal of Materials Chemistry, 10, 2121–2126.Google Scholar
Liu, M.X., Guo, B.C., Du, M.L., Cai, X.J. & Jia, D.M. (2007) Properties of halloysite nanotube–epoxy resin hybrids and the interfacial reactions in the systems. Nanotechnology, 18, 455703.Google Scholar
Liu, M.X., Jia, Z.X., Jia, D.M. & Zhou, C.R. (2014) Recent advance in research on halloysite nanotubes–polymer nanocomposite. Progress in Polymer Science, 39, 1498–1525.Google Scholar
Lvov, Y., Wang, W., Zhang, L. & Rawil, F. (2016) Halloysite clay nanotubes for loading and sustained release of functional compounds. Advanced Materials, 28, 1227–1250.Google Scholar
Pasbakhsh, P., Ismail, H., Ahmad Fauzi, M.N. & Bakar, A. (2010) EPDM/modified halloysite nanocomposites. Applied Clay Science, 48, 405–413.Google Scholar
Prashantha, K., Lacrampe, M.F. & Krawczak, P. (2011) Processing and characterization of halloysite nanotubes filled polypropylene nanocomposites based on a masterbatch route: effect of halloysites treatment on structural and mechanical properties. Express Polymer Letters, 5, 295–307.Google Scholar
Qiao, X., Na, X., Gao, P. & Sun, K. (2017) Halloysite nanotubes reinforced ultrahigh molecular weight polyethylene nanocomposite films with different filler concentration and modification. Polymer Testing, 57, 133–140.Google Scholar
Silva, D., Pasbakhsh, P., Goh, K.L., Chai, S.P. & Ismail, H. (2013) Physicochemical characterisation of chitosan/halloysite composite membranes. Polymer Testing, 32, 265–271.Google Scholar
Vergaro, V., Abdullayev, E. & Lvov, Y.M. (2010) Cytocompatibility and uptake of halloysite clay nanotubes. Biomacromolecules, 11, 820–826.Google Scholar
Wang, Y.X. & Yan, F.Y. (2006) Tribological properties of transfer films of PTFE-based composites. Wear, 261, 1359–1366.Google Scholar
Wilson, M.J. (2003) Clay mineralogical and related characteristics of geophagic materials. Journal of Chemical Ecology, 29, 1525–1547.Google Scholar
Xie, Y., Qian, D. & Wu, D. (2011) Magnetic halloysite nanotubes/iron oxide composites for the adsorption of dyes. Chemical Engineering Journal, 168, 959–963.Google Scholar
Yuan, P., Tan, D.Y., Annabi-Bergaya, F., Yan, W.C, Fan, M.D., Liu, D. & He, H.P. (2012) Changes in structure, morphology, porosity, and surface activity of mesoporous halloysite nanotubes under heating. Clays and Clay Minerals, 60, 557–569.Google Scholar
Zhang, Y. & Yang, H. (2012) Halloysite nanotubes coated with magnetic nanoparticles. Applied Clay Science, 56, 97–102.Google Scholar