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Modelling, kinetics and equilibrium studies of crystal violet adsorption on modified montmorillonite by sodium dodecyl sulfate and hyamine surfactants

Published online by Cambridge University Press:  11 May 2021

Malihe Sarabadan ,
Hadis Bashiri Open the ORCID record for Hadis Bashiri [Opens in a new window]  and
Seyed Mahdi Mousavi
Malihe Sarabadan
Affiliation:
Department of Physical Chemistry, Faculty of Chemistry, University of Kashan, Kashan, Iran
Hadis Bashiri*
Affiliation:
Department of Physical Chemistry, Faculty of Chemistry, University of Kashan, Kashan, Iran
Seyed Mahdi Mousavi
Affiliation:
Department of Applied Chemistry, Faculty of Chemistry, University of Kashan, Kashan, Iran
*
*Email: [email protected]
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Abstract

Two novel adsorbents – montmorillonite (Mnt)-hyamine and Mnt-hyamine-sodium dodecyl sulfate (SDS) – were synthesized using Mnt nanoparticles. The modified Mnt and Mnt nanoparticles were used for the removal of crystal violet from water, and they were characterized using various techniques. The effects of pH, time, temperature, adsorbent dosage and initial dye concentration on the dye-removal efficiency were investigated using response surface methodology. The optimum conditions for maximum dye removal were obtained. The optimum conditions for crystal violet adsorption on Mnt-hyamine, Mnt-hyamine-SDS and Mnt nanoparticles are temperatures 25.00°C, 29.97°C and 27.28°C; pH values 9.00, 10.41 and 9.40; adsorbent dosages 1.00, 1.15 and 1.06 g L–1; and initial dye concentrations 30.00, 98.74 and 99.44 mg L–1, respectively. The adsorbent dosage is the most critical variable for dye removal. Temkin and Langmuir are the best isotherms for studying adsorption equilibria. In the kinetic study, the fractal-like integrated kinetic Langmuir model was the most appropriate model, and the thermodynamic parameters were also determined. The synthesized adsorbents could be easily separated from solution. The Mnt-hyamine-SDS adsorbent has a high adsorption capacity (690.69 mg g–1) for the removal of crystal violet.

Keywords

adsorptioncrystal violethyaminemodified montmorillonitemontmorillonite nanoparticlesresponse surface methodology
Type
Article
Information
Clay Minerals , Volume 56 , Issue 1 , March 2021 , pp. 16 - 27
Copyright
Copyright © The Author(s), 2021. Published by Cambridge University Press on behalf of The Mineralogical Society of Great Britain and Ireland

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Footnotes

Associate Editor: Miroslav Pospišil

References

Acisli, O., Khataee, A., Karaca, S. & Sheydaei, M. (2016) Modification of nanosized natural montmorillonite for ultrasound-enhanced adsorption of Acid Red 17. Ultrasonics Sonochemistry, 31, 116–121.CrossRefGoogle ScholarPubMed
Ali, I., Asim, M. & Khan, T.A. (2012) Low cost adsorbents for the removal of organic pollutants from wastewater. Journal of Environmental Management, 113, 170–183.CrossRefGoogle ScholarPubMed
Alipanahpour Dila, E., Ghaedi, M., Ghaedi, A., Asfaram, A., Jamshidi, M. & Purkait, M.K. (2016) Application of artificial neural network and response surface methodology for the removal of crystal violet by zinc oxide nanorods loaded on activate carbon: kinetics and equilibrium study. Journal of the Taiwan Institute of Chemical Engineers, 59, 210–220.Google Scholar
Amodu, O.S., Ojumu, T.V., Ntwampe, S.K. & Ayanda, O.S. (2015) Rapid adsorption of Crystal Violet onto magnetic zeolite synthesized from fly ash and magnetite nanoparticles. Journal of Encapsulation and Adsorption Sciences, 5, 191–203.CrossRefGoogle Scholar
Atta, A.M., Al-Lohedan, H.A., Alothman, Z.A., Abdel-Khalek, A.A. & Tawfeek, A.M. (2015) Characterization of reactive amphiphilic montmorillonite nanogels and its application for removal of toxic cationic dye and heavy metals water pollutants. Journal of Industrial and Engineering Chemistry, 31, 374–384.CrossRefGoogle Scholar
Azizian, S. & Bashiri, H. (2008) Adsorption kinetics at the solid/solution interface: statistical rate theory at initial times of adsorption and close to equilibrium. Langmuir, 24, 11669–11676.CrossRefGoogle Scholar
Bashiri, H. & Eris, S. (2016) Statistical thermodynamic study of gas adsorption with different adsorption geometries on homogeneous solid surface. Chemical Engineering Communications, 203, 628–634.CrossRefGoogle Scholar
Bertolini, T.C.R., Izidoro, J.C., Magdalena, C.P. & Fungaro, D.A. (2013) Adsorption of crystal violet dye from aqueous solution onto zeolites from coal fly and bottom ashes. Orbital: The Electronic Journal of Chemistry, 5, 179–191.Google Scholar
Chen, D., Chen, J., Luan, X., Ji, H. & Xia, Z. (2011) Characterization of anion–cationic surfactants modified montmorillonite and its application for the removal of methyl orange. Chemical Engineering Journal, 171, 1150–1158.CrossRefGoogle Scholar
Chen, Y., Zhai, S.-R., Liu, N., Song, Y., An, Q.-D. & Song, X.-W. (2013) Dye removal of activated carbons prepared from NaOH-pretreated rice husks by low-temperature solution-processed carbonization and H3PO4 activation. Bioresource Technology, 144, 401–409.CrossRefGoogle ScholarPubMed
Chen, L., Zhou, C.H., Fiore, S., Tong, D.S., Zhang, H., Li, C.S., Ji, S.F. & Yu, W.H. (2016) Functional magnetic nanoparticle/clay mineral nanocomposites: preparation, magnetism and versatile applications. Applied Clay Science, 127–128, 143–163.CrossRefGoogle Scholar
Cohen, E., Joseph, T., Lapides, I. & Yariv, S. (2018) The adsorption of berberine by montmorillonite and thermo-XRD analysis of the organo-clay complex. Clay Minerals, 40, 223–232.CrossRefGoogle Scholar
Fahn, R. & Fenderl, K. (1983) Reaction products of organic dye molecules with acid-treated montmorillonite. Clay Minerals, 18, 447–458.CrossRefGoogle Scholar
Foo, K.Y. & Hameed, B.H. (2010) Insights into the modeling of adsorption isotherm systems. Chemical Engineering Journal, 156, 2–10.CrossRefGoogle Scholar
Freundlich, H. (1907) Über die Adsorption in Lösungen. Zeitschrift für Physikalische Chemie, 57U, 385.CrossRefGoogle Scholar
Gamoudi, S. & Srasra, E. (2018) Removal of cationic and anionic dyes using purified and surfactant-modified Tunisian clays: kinetic, isotherm, thermodynamic and adsorption-mechanism studies. Clay Minerals, 53, 159–174.CrossRefGoogle Scholar
García-Montaño, J., Pérez-Estrada, L., Oller, I., Maldonado, M.I., Torrades, F. & Peral, J. (2008) Pilot plant scale reactive dyes degradation by solar photo-Fenton and biological processes. Journal of Photochemistry and Photobiology A: Chemistry, 195, 205–214.CrossRefGoogle Scholar
Gomez-Serrano, V., Pastor-Villegas, J., Perez-Florindo, A., Duran-Valle, C. & Valenzuela-Calahorro, C. (1996) FT-IR study of rockrose and of char and activated carbon. Journal of Analytical and Applied Pyrolysis, 36, 71–80.CrossRefGoogle Scholar
Haerifar, M. & Azizian, S. (2012) Fractal-like adsorption kinetics at the solid/solution interface. Journal of Physical Chemistry C, 116, 13111–13119.CrossRefGoogle Scholar
Ho, Y.S. & McKay, G. (1999) Batch lead(II) removal from aqueous solution by peat: equilibrium and Kinetics. Process Safety and Environmental Protection, 77, 165–173.CrossRefGoogle Scholar
Ishaq, M., Javed, F., Amad, I., Ullah, H., Hadi, F. & Sultan, S. (2016) Adsorption of crystal violet dye from aqueous solutions onto low-cost untreated and NaOH treated almond shell. Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 35, 97–106.Google Scholar
Kıranşan, M., Soltani, R.D.C., Hassani, A., Karaca, S. & Khataee, A. (2014) Preparation of cetyltrimethylammonium bromide modified montmorillonite nanomaterial for adsorption of a textile dye. Journal of the Taiwan Institute of Chemical Engineers, 45, 2565–2577.CrossRefGoogle Scholar
Lagergren, S. (1898) Zur theorie der sogenannten adsorption geloster stoffe. Kungliga Svenska Vetenskapsakademiens. Handlingar, 24, 1–39.Google Scholar
Langmuir, I. (1916) The constitution and fundamental properties of solids and liquids. Part I. Solids. Journal of the American Chemical Society, 38, 2221–2295.CrossRefGoogle Scholar
Li, S. (2010) Removal of crystal violet from aqueous solution by sorption into semi-interpenetrated networks hydrogels constituted of poly(acrylic acid-acrylamide-methacrylate) and amylose. Bioresource Technology, 101, 2197–2202.CrossRefGoogle ScholarPubMed
Marczewski, A.W. (2010) Analysis of kinetic Langmuir model. Part I: integrated kinetic Langmuir equation (IKL): a new complete analytical solution of the Langmuir rate equation. Langmuir, 26, 15229–15238.CrossRefGoogle ScholarPubMed
Monash, P. & Pugazhenthi, G. (2009) Removal of crystal violet dye from aqueous solution using calcined and uncalcined mixed clay adsorbents. Separation Science and Technology, 45, 94–104.CrossRefGoogle Scholar
Mousavi, S.M., Salari, D., Niaei, A., Panahi, P.N. & Shafiei, S. (2014) A modelling study and optimization of catalytic reduction of NO over CeO2–MnOx (0.25)–Ba mixed oxide catalyst using design of experiments. Environmental Technology, 35, 581–589.CrossRefGoogle ScholarPubMed
Nezamzadeh-Ejhieh, A. & Shahriari, E. (2011) Heterogeneous photodecolorization of methyl green catalyzed by Fe(II)-o-phenanthroline/zeolite Y nanocluster. International Journal of Photoenergy, 2011, 518153.Google Scholar
Nourmoradi, H., Avazpour, M., Ghasemian, N., Heidari, M., Moradnejadi, K., Khodarahmi, F., Javaheri, M. & Moghadam, F.M. (2016) Surfactant modified montmorillonite as a low cost adsorbent for 4-chlorophenol: equilibrium, kinetic and thermodynamic study. Journal of the Taiwan Institute of Chemical Engineers, 59, 244–251.CrossRefGoogle Scholar
Rasouli, F., Aber, S., Salari, D. & Khataee, A.R. (2014) Optimized removal of Reactive Navy Blue SP-BR by organo-montmorillonite based adsorbents through central composite design. Applied Clay Science, 87, 228–234.CrossRefGoogle Scholar
Redlich, O. & Peterson, D.L. (1959) A useful adsorption isotherm. Journal of Physical Chemistry, 63, 1024–1024.CrossRefGoogle Scholar
Saka, C. (2012) BET, TG–DTG, FT-IR, SEM, iodine number analysis and preparation of activated carbon from acorn shell by chemical activation with ZnCl2. Journal of Analytical and Applied Pyrolysis, 95, 21–24.CrossRefGoogle Scholar
Sarabadan, M., Bashiri, H. & Mousavi, S.M. (2019a) Adsorption of crystal violet dye by zeolite-montmorillonite: modeling, kinetic and equilibrium studies. Clay Minerals, 54, 357–368.CrossRefGoogle Scholar
Sarabadan, M., Bashiri, H. & Mousavi, S.M. (2019b) Removal of crystal violet dye by an efficient and low cost adsorbent: modeling, kinetic, equilibrium and thermodynamic studies. Korean Journal of Chemical Engineering, 36, 1575–1586.CrossRefGoogle Scholar
Satapathy, M.K. & Das, P. (2014) Optimization of crystal violet dye removal using novel soil-silver nanocomposite as nanoadsorbent using response surface methodology. Journal of Environmental Chemical Engineering, 2, 708–714.CrossRefGoogle Scholar
Senthilkumaar, S., Kalaamani, P. & Subburaam, C.V. (2006) Liquid phase adsorption of crystal violet onto activated carbons derived from male flowers of coconut tree. Journal of Hazardous Materials, 136, 800–808.CrossRefGoogle ScholarPubMed
Simonin, J.-P. (2016) On the comparison of pseudo-first order and pseudo-second order rate laws in the modeling of adsorption kinetics. Chemical Engineering Journal, 300, 254–263.CrossRefGoogle Scholar
Sips, R. (1948) On the structure of a catalyst surface. Journal of Chemical Physics, 16, 490–495.CrossRefGoogle Scholar
Subramaniam, R. & Kumar Ponnusamy, S. (2015) Novel adsorbent from agricultural waste (cashew NUT shell) for methylene blue dye removal: optimization by response surface methodology. Water Resources and Industry, 11, 64–70.CrossRefGoogle Scholar
Temkin, M.J. & Pyzhev, V. (1940) Kinetics of ammonia synthesis on promoted iron catalysts. Acta Physicochimica URSS, 12, 217–222.Google Scholar
Vasques, É.d.C., Carpiné, D., Dagostin, J.L.A., Canteli, A.M.D., Igarashi-Mafra, L., Mafra, M.R. & Scheer, A.d.P. (2014) Modelling studies by adsorption for the removal of sunset yellow azo dye present in effluent from a soft drink plant. Environmental Technology, 35, 1532–1540.CrossRefGoogle Scholar
Wang, X.S. & Zhang, W. (2011) Removal of basic dye crystal violet from aqueous solution by Cu(II)-loaded montmorillonite. Separation Science and Technology, 46, 656–663.CrossRefGoogle Scholar
Wang, L., Zhang, J. & Wang, A. (2008) Removal of methylene blue from aqueous solution using chitosan-g-poly(acrylic acid)/montmorillonite superadsorbent nanocomposite. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 322, 47–53.CrossRefGoogle Scholar
Wang, G., Wang, S., Sun, Z., Zheng, S. & Xi, Y. (2017) Structures of nonionic surfactant modified montmorillonites and their enhanced adsorption capacities towards a cationic organic dye. Applied Clay Science, 148, 1–10.CrossRefGoogle Scholar
Wu, F.-C., Tseng, R.-L. & Juang, R.-S. (2009) Initial behavior of intraparticle diffusion model used in the description of adsorption kinetics. Chemical Engineering Journal, 153, 1–8.CrossRefGoogle Scholar
Yang, X. & Al-Duri, B. (2005) Kinetic modeling of liquid-phase adsorption of reactive dyes on activated carbon. Journal of Colloid and Interface Science, 287, 25–34.CrossRefGoogle ScholarPubMed
Zeldowitsch, J. (1934) Über den mechanismus der katalytischen oxydation von CO an MnO2. Acta Physicochimica URSS, 1, 449–464.Google Scholar
Zhang, Z., Zhang, J., Liao, L. & Xia, Z. (2013) Synergistic effect of cationic and anionic surfactants for the modification of Ca-montmorillonite. Materials Research Bulletin, 48, 1811–1816.CrossRefGoogle Scholar
Zhu, R., Chen, Q., Liu, H., Ge, F., Zhu, L., Zhu, J. & He, H. (2014) Montmorillonite as a multifunctional adsorbent can simultaneously remove crystal violet, cetyltrimethylammonium, and 2-naphthol from water. Applied Clay Science, 88–89, 33–38.CrossRefGoogle Scholar
Zhu, R., Chen, Q., Zhou, Q., Xi, Y., Zhu, J. & He, H. (2016) Adsorbents based on montmorillonite for contaminant removal from water: a review. Applied Clay Science, 123, 239–258.CrossRefGoogle Scholar
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