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Kaolin and halloysite deposits of Brazil

Published online by Cambridge University Press:  09 July 2018

I. R. Wilson*
Affiliation:
Ian Wilson Consultancy, Withielgoose Farmhouse, Withiel, Bodmin, Cornwall PL305NW, UK
H. de Souza Santos
Affiliation:
Laboratorio de Microscopia Electronica, Instituto de Fisica da USP, Sao Paulo, Brazil
P. de Souza Santos
Affiliation:
Laboratório de Matórias-Primas Particuladas e Sólidos Não-Metálicos, Dpto. de Engenharia Metalúrgica e de Materials, Escola Politécnica da USP, São Paulo, Brazil
*

Abstract

Brazil is a significant producer of kaolin with almost 2.5 Mt in 2005 representing 10% of the world's total of 25.0 Mt. Brazil is now the second largest producer in the world, after the USA, having overtaken the United Kingdom in 2005. The kaolin resources are widespread throughout the country and are varied in their origin, physical and chemical properties and morphology. The kaolin industry in Brazil has shown a dramatic rise over the last 15 years with production of beneficiated kaolin increasing from 0.66 Mt in 1990 to 2.5 Mt in 2005. The reason for the growth is solely the development of large kaolin deposits in the Amazon Basin that account for 90% of Brazil's production. In 2005 there are just two companies involved in the production and sales of kaolin from the Amazon Basin, namely Imerys (RCC — Rio Capim Caulim) and Caemi (a subsidiary of CVRD — Companhia Vale do Rio Doce) with kaolin operations of CADAM (Jari River) and PPSA (Capim River operations).

Type
Review
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2006

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References

Almeida, M.J. (1987) Caulim CADAM no revestimento. Papel. 48, 5763.Google Scholar
Almeida, S.C., Johnston, W.D. Jr., Leonardos, O.H. & Scorza, E.P. (1944) The beryl/tantalite/ cassiterite bearing pegmatites of Paraiba and Rio Grande do Norte, Northeastern Brazil. Economic Geology. 39, 206223.Google Scholar
Amarante, A., Neves, L.M. & Pierro, J. (1981) Caulim Horii de Mogi das Crazes, SP, como padrâo. Cerâmica. 27(138), 219224.Google Scholar
Angeleri, F.B., Souza Santos, P. & Souza Santos, H. (1963) Caracteristicos fisico-quimicos e cerâmicos de caulins e argilas usados na Industria Cerâmica de Paulo S. VII — Caulins creme-amarelados de Parelheiros, Estado de S. Paulo”. Cerâmica. 9(36), 1929.Google Scholar
Barbosa, E.M. (2002) Evolution du kaolin supergène de la rivière Capim (Nord Est du Para-Brésil). Relations entre les characteristiques mineralogiques, cristalochimiques et les propriétés industrielles. Thèse, Docteur, École Nationale Supérieure de Géologie de Nancy, France.Google Scholar
Beissner, H., Carvalho, A., Lopes, L.M. & Valeton, I.(1997) The Cataguazes bauxite deposit (Mantiqueiraregion: Muriaé). Pp. 195206 in: Brazilian Bauxites(Carvalho, A., Boulangé, B., Melfi, A.J. and Lucas, Y.,editors). USP-FAPESP-ORSTOM, Sâo Paulo, Brazil.Google Scholar
Biondi, J.C. & Furtado, L.C. (1999) Geologia e gênese dos depôsitos de caulim Floresta e Cambui (Formaçâo Campo Alegre-Santa Catarina). Revista Brasileira de Geociências. 29, 141150.Google Scholar
Biondi, J.C., Moser, D., Fagundes, M.R. & Silveira, L.S. (2000) Carateristicas fîsicas dos minérios de caulim das minas Floresta, Cavalheiro, Turvo e Kowalski em Campo Alegre (SC) e de Trigolandia (PR). Cerâmica. 46(298), 6775.Google Scholar
Boulangé, B., Carvalho, A., Varajâo, CA.C. & Varajâo, A.F.D.C. (1997) The bauxite of the Quadrilâtero Ferrifero (Vargem dos Oculos). Pp. 165194 in: Brazilian Bauxite. (Carvalho, A., Boulang, B.é, Melfi, AJ. and Lucas, Y., editors). USP-FAPESPORSTOM, Sâo Paulo, Brazil.Google Scholar
Brindley, G.W., Souza Santos, P. & Souza Santos, H. (1963) Mineralogical studies of kaolinite-halloysite clays. I Identification problems. American Mineralogist. 48, 897910.Google Scholar
Campos, T.W. & Souza Santos, H. (1986) Estudos de caulins brasileiros por microscopia eletrônica de transmissâo. Cerâmica. 32(203), 355360.Google Scholar
Cardoso, S.R.F., Souza Santos, H., Vieira Coelho, A.C. & Souza Santos, P. (1998) Caraterizaçâo e propriedades cerâmicas de caulins e argilas usados em Cerâmica Branca no Estado de Sâo Paulo. Cerâmica Industrial. 3(47), 3947.Google Scholar
Citrobi, S.B. & Basci, MA.S. (2001) Volcanism and stratigraphy of the Neoprotereozoic. Campo Alegre basin, S.C., Brazil. Anais de Academia Brasileira de Ciências. 73, 581597.CrossRefGoogle Scholar
Costa, M.L. & Moraes, E.L. (1998) Mineralogy geochemistry and genesis of kaolins from the Amazon region. Mineralium Deposita. 33, 283297.Google Scholar
Crossley, P. (2001) Brazil's industrial minerals; markets and supply. Industrial Minerals. 407 August, 2649.Google Scholar
Eisenlohr, V. (1980) Caulim do Rio Jari. Cerâmica. 26(118), 2533.Google Scholar
Formoso, M.L.L. (1966) Aspectos geolôgicos dos caulins e argilas do Rio Grande do Sul. Cerâmica. 12(47–48), 132144.Google Scholar
Gopinath, T.R. & Souza, J.M.B. (1990) Processos de formaçâo de caulim primârio nos pegmatites da regiâo de Junco do Seridô, Paraiba. Anais do Congreso Brasileira Geologia. 3.Google Scholar
Gopinath, T.R. & Souza, J.M.B. (2000) Characteristics of the kaolin in the pegmatites of the Paraiba and Rio Grande do Norte States, Brazil. Proceedings of the 15’ Conference on Clay Mineralogy and Petrology. Brno, Czech Republic, pp. 2829.Google Scholar
Halward, A., Sanchez, C. & Oliveira, A.P. (1977) Comparaçâo entre algumas propriedades fisicoquimicas do caulim Amazon 88 e outros caulins. Revista Brasileira de Tecnologia. 8, 8395.Google Scholar
Harben, P. & Virta, B. (1999) High grade kaolin fillers: production review. Industrial Minerals. 386, November, 2537.Google Scholar
Harben, P. & Virta, B. (2000) High grade kaolin fillers: trade and distribution. Industrial Minerals. 388, January, 3437.Google Scholar
Hurst, V.J. & Bôsio, N.J. (1975) Rio Capim kaolin deposit, Brazil. Economic Geology. 70, 990992.Google Scholar
Kiyohara, P.K. & Souza Santos, P. (1987) Estudos por microscopia eletrônica de varredura sobre a forma de ocorrência de haloisita em caulins brasileiros. Cerâmica. 33(215), 246252.Google Scholar
Kotschoubey, B., Duarte, A.L.S. & Truckenbrodt, W. (1999) Cobertura bauxitica e origem do caulim do Mono do Felipe, Baixo Rio Jari, Estado do Amapâ. Revista Brasileira de Geociências. 29, 331338.Google Scholar
Kotschoubey, B., Truckenbrodt, W. & Hieronymus, B. (1996) Depôsitos de caolim e argila semi-flint no nordeste do Para. Revista Brasileira de Geociências. 26, 7180.CrossRefGoogle Scholar
Kulaif, Y. (2005) Caulim. Sumârio Minera. 2005, DNPM-MME, Brasilia.Google Scholar
Larroyd, F., Petter, .C.O. & Sampaio, C.H. (2002) Purification of north Brazilian kaolin by selective flocculation. Minerals Engineering. 15, 11911192.Google Scholar
Lucas, Y. (1989) Systèmes pédologiques en Amazonie brésilienne. Thèse, Docteur, Université de Poitiers, France, pp. 8084.Google Scholar
Melchiades, F.G. & Boschi, A.O. (2002) Caraterizaçâo de uma jazida de caulim de Campo Alegre (SC). Cerâmica Industrial. 7(6), 3033.Google Scholar
Mesquita, L.M.S., Rodrigues, T. & Gomes, S.S. (1996) Bleaching of Brazilian kaolins using organic acids and fermented medium. Minerals Engineering. 9, 965971.Google Scholar
Moeri, N.E., Hennies, W.T. & Coura, F.J. (1987) Geological model and computer control for planning and operating the Jari kaolin mine, Morro do Felipe, Brazil. 13th World Mining Congress, Stockholm. Google Scholar
Montes, C.R., Melfi, A.J., Carvalho, A., Vieira Coelho, A.C. & Formoso, M.L.L. (2002) Genesis, mineralogy and geochemistry of kaolin deposits of the Jari River, Amapâ State, Brazil. Clays and Clay Minerals. 50, 494503.Google Scholar
Murray, H.H. & Partridge, P. (1982) Genesis of Rio Jari kaolin. Proceedings of the 8th International Clay Conference, Bologna and Pavia, Italy. 1981. Elsevier, Amsterdam.Google Scholar
Nascimento, M.S. & Goes, A.N. (2005) Distribuiçào estratigrâfica e proveniência de minerais pesados das Formaçôes Ipixuna e Barreiras, regiâo do rio Capim, sul da sub-bacia de Cameta. Revista Brasileira de Geociências Brasilia. 35, 4958.CrossRefGoogle Scholar
Oliveira, S.M.B. & Toledo, M.C. (1997) The bauxite of Nazaré Paulista and associate deposits (Curucuta andMogi das Cruzes). Pp. 209224 in: Brazilian Bauxite. (Carvalho, A., Boulangé, B., Melfi, A.J. and Lucas, Y., editors). USP-FAPESP-ORSTOM, Sâo Paulo, Brazil.Google Scholar
Padua, A.R.A. & Barauna, O.S. (1981) Estudo tecnolôgico de caulins sedimentares da faixa costeira ao sul de Recife, Pernambuco. Revista Pernambucana de Tecnologia. 1, 67100.Google Scholar
Paiva, G. (1946) Provincias pegmatiticas do Brasil. Boleti. no. 78 do DNPM-MME. Rio de Janeiro, Brazil.Google Scholar
Pandolfo, C. (1979) Bauxito, caulins e argilas na Amazônia. Cerâmica. 25(109), 1.Google Scholar
Pickering, S.M. Jr (1994) Brazil's development as a world supplier of pigment grade paper coating clays. Society for Mining, Metallurgy and Exploration Abstract. SME, Littleton, Colorado.Google Scholar
Pickering, S.M. Jr & Linkous, M. (1997) Comparison of the fine and coarse commercial kaolin deposits from Georgia USA and Brazil. Society for Mining, Metallurgy and Exploration Preprint. SME, Littleton, Colorado, pp. 97163.Google Scholar
Pickering, S.M. Jr. & Murray, H.H. (1994) Kaolin, . Pp. 255277 in: Industrial Minerals and Rocks. 6 edition (Carr, D.D., editor). Society for Mining, Metallurgy and Exploration, Littleton, Colorado.Google Scholar
Pinheiro, P.G. (2002) Caraterizaçâo quimica, ocorrência e distribuiçâo de ferro em minerais do caulim da regiâo de Mar de Espanha, Minas Gérais. Tese, Master, Universidade Federal de Minas Gérais, Belo Horizonte, Brazil.Google Scholar
Pruett, J.P. & Pickering, J.M. Jr. (2006) Kaolin, . Pp. 383399 in: Industrial Minerals & Rocks. 7th edition (Elzea Kogel, J., Trivedi, N.C., Barker, J.M. & Krubowski, S.T., editors). Society for Mining, Metallurgy and Exploration, Littleton, Colorado.Google Scholar
Ribeiro Filho, A.R. (1976) A industrializaçào do caulim no Nordeste do Brasil. Geologia e Metallurgia. 40(249), 356361.Google Scholar
Ribeiro, F.R. (2003) Identification of iron-bearing minerals in solid residues from industrial kaolin processing (Mar de Espanha, Minas Gérais, Brasil). Hyperfine Interactions. 47, 148149.Google Scholar
Roy, P.R., Dottin, O. & Madon, H.L. (1964) Estudo dos pegmatites do Rio Grande do Norte e da Paraiba. Série Geolôgica no 1, Divisâo de Geologia, DRNSUDENE. Recife, Brasil.Google Scholar
Santos, A.E. Jr. & Rossetti, D.F. (2003) Paleoambiente e estratigrafia da Formaçâo Ipixuna, area do rio Capim, leste da sub-bacia de Cameta. Revista Brasileira de Geociências. 33, 313324.Google Scholar
Santos, A.E. Jr. & Rossetti, D.F. (2006) Origin of the Rio Capim kaolin with basis on optical data. DSR — Institut» Nacional de Pesquisas Espaciais, Sâo José dos Campos, 32 pp.Google Scholar
Silva, E.H.R.D. (1973) Caulim no Nordeste, Divisâo de Geologia, DRN-SUDENE. Recife, Brazil.Google Scholar
Souza Santos, H. (1966) Microscopia eletrônica de caulins e argilas brasileiros na Indûstria Cerâmica. Cerâmica. 12(47-48), 173202.Google Scholar
Souza Santos, P. (1975) New sedimentary kaolin deposits in the Amazon region; Jari and Capim rivers, Brazil. Proceedings of the International Clay Conference, Mexico. Applied Publishing, Wilmette, p. 553.Google Scholar
Souza Santos, P. (1992) Ciência e Tecnologia de Argilas. 2nd edition. Edgard Blucher, Sao Paulo, Brazil.Google Scholar
Souza Santos, P. (1993) The use of clay particle morphology studies to characterize industrial clay deposits; examples from Brazil. Clay Mineral. 28, 539553.Google Scholar
Souza Santos, P. & Souza Santos, H. (1968) Presença de haloisita 4H20 em caulins primarios brasileiros. Cerâmica. 14(68), 53.Google Scholar
Souza Santos, P. & Souza Santos, H. (1969) Estudos sobre a composiçâo mineralôgica de caulins primarios e secundârios brasileiros. Cerâmica. 15(5758), 21.Google Scholar
Souza Santos, P., Brindley, G.W & Souza Santos, H. (1964) Mineralogical studies of kaolinite-halloysite clays. II Some Brazilian kaolins. American Mineralogist. 49, 15431548.Google Scholar
Souza Santos, P. & Wilson, I.R. (1995) Geological environment of Brazilian kaolins. Pp. 116121 in: Clays: Controlling the Envrionmen. (Churchman, G.J., Fitzpatrick, R.W. and Eggleton, R.A., editors). 10th International Clay Conference, Adelaide, Australia, 1993. CSIRO Publishing, Melbourne, Australia.Google Scholar
Souza Santos, P., Souza Santos, H. & Ferreira, H.C. (1974) Microscopia eletrônica de caulins dos Estados da Paraiba e Rio Grande do Norte. Ciência e Cultura,. 26, 6, 581.Google Scholar
Toledo, S.P., Souza Santos, H. & Souza Santos, P. (2002) Clay mineral characterization in kaolins and ball clays from Santa Catarina. Acta Microscopica. 11(1), 12.Google Scholar
Toledo, S.P., Souza Santos, H. & Souza Santos, P. (2003) Caraterizaçâo dos argilominerais do grupo da caulinita em alguns caulins e ball clays de Santa Catarina. Cerâmica Industrial. 8(4), 712 , (5), 27–39.Google Scholar
Varajâo, A.F.D.C., Gilkes, R.J. & Hart, R.D. (2001) The relationship between kaolinite crystal properties and the original materials for a Brazilian kaolin deposit (Quadrilâtero Ferrifero, Minas Geraes). Clays and Clay Minerals. 49, 4459.Google Scholar
Vieira Coelho, A.C. & Souza Santos, P. (2001) Study of the structural order degree of Brazilian kaolinites by X-ray diffraction. Proceedings of the International Clay Conference. Elsevier, Amsterdam, pp. 347354.Google Scholar
Wilson, I. R. (1995) Constituiçâo, avaliaçào e propriedades cerâmicas de caulins de alta qualidade. Cerâmica. 41, 270281.Google Scholar
Wilson, I.R. (1998) The constitution, evaluation and ceramic properties of ball clays. Cerâmica. 44, No. 287–288, 88117.Google Scholar
Wilson, I.R. (2005) Kaolin Review. Mining Annual Review for 2004.Google Scholar
Wilson, I.R. & Souza Santos, P. (1982) Propriedades para Cerâmica Branca do Caulim de Mogi das Cruzes. Cerâmica. 28, No. 147, 109119.Google Scholar
Wilson, I.R. & Souza Santos, P. (1982) Properties of the china clay from Varinhas, Mogi das Cruzes, SP, Brazil. Proceedings of the 8th International Clay Conference, Bologna and Pavia. 1981, Elsevier, Amsterdam, pp. 711718.Google Scholar
Wilson, I.R., Souza Santos, H & Souza Santos, P. (1998) Brazilian kaolins: some aspects of the geology and mineralogy. Cerâmica. 44, No. 287288, 118129.Google Scholar