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Glutamic acid deamination in the presence of montmorillonite

Published online by Cambridge University Press:  09 July 2018

A. Naidja  and
B. Siffert
A. Naidja
Affiliation:
Centre de Recherches sur la Physico-Chimie des Surfaces Solides-CNRS, 24, Avenue du Président Kennedy, 68200 Mulhouse, France
B. Siffert
Affiliation:
Centre de Recherches sur la Physico-Chimie des Surfaces Solides-CNRS, 24, Avenue du Président Kennedy, 68200 Mulhouse, France
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Abstract

Glutamic acid deamination was realized in the absence and in the presence of montmorillonite saturated with various metallic cations (Na+, Mn2+, Cu2+). The catalytic activity depends upon the interlayer exchangeable cation and the pH of the suspension. A maximum was observed near pH = 5–6. In the presence of the enzyme l-glutamate dehydrogenase and the coenzyme nicotinamide adenine dinucleotide, glutamic acid transforms into α-ketoglutaric acid, but in the presence of montmorillonite, it yields α-hydroxyglutaric acid and traces of butyric acid. However, kinetic and reaction yield are significantly reduced compared to the biological system.

Type
Research Article
Information
Clay Minerals , Volume 24 , Issue 4 , December 1989 , pp. 649 - 661
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1989

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