Hostname: page-component-586b7cd67f-r5fsc Total loading time: 0 Render date: 2024-11-30T23:26:17.307Z Has data issue: false hasContentIssue false
  • English
  • Français

Fe-loaded zeolites as catalysts in the formation of humic substance-like darkcoloured polymers in polycondensation reactions of humic precursors

Published online by Cambridge University Press:  09 July 2018

S. Fukuchi ,
M. Fukushima ,
R. Nishimoto ,
G. Qi  and
T. Sato
S. Fukuchi
Affiliation:
Division of Sustainable Resources Engineering, Graduate School of Engineering, Hokkaido University, Sapporo 060-8628, Japan
M. Fukushima*
Affiliation:
Division of Sustainable Resources Engineering, Graduate School of Engineering, Hokkaido University, Sapporo 060-8628, Japan
R. Nishimoto
Affiliation:
Division of Sustainable Resources Engineering, Graduate School of Engineering, Hokkaido University, Sapporo 060-8628, Japan
G. Qi
Affiliation:
Key Laboratory for Solid Waste Management and Environmental Safety, Ministry of Education of China, Tsinghua University, Beijing 100084, China
T. Sato
Affiliation:
Division of Sustainable Resources Engineering, Graduate School of Engineering, Hokkaido University, Sapporo 060-8628, Japan
*
*E-mail: [email protected]
Get access Rights & Permissions [Opens in a new window]

Abstract

To enhance the catalytic activities of zeolites for the polycondensation reactions of humic precursors, Fe was loaded into a zeolite via an ion-exchange reaction and the resulting product was subjected to calcination at 773 K. Two types iron-loaded zeolites were prepared using one equivalent (Fe-Z-1) and 10-equivalents (Fe-Z-10) of Fe2+ to the cation-exchange capacity of a natural zeolite from Niki town (Hokkaido, Japan). X-ray diffraction (XRD) patterns and X-ray photoelectron spectroscopy (XPS) spectra showed that the Fe(II) that was originally loaded into the cation-exchange sites in the zeolite became oxidized to a Fe(III) ionic species during the preparation. The catalytic activities of each zeolite were evaluated, based on the degree of darkening for reaction mixtures containing catechol, glycine and glucose as model humic precursors. The catalytic activities of Fe-Z-1 and Fe-Z-10 were higher than that for an untreated zeolite, and increased with the amount of Fe in the zeolite.

Keywords

Fe-loaded zeolite catalysthumic precursorspolycondensation reactiondark-coloured polymershumic-like acid
Type
Research Papers
Information
Clay Minerals , Volume 47 , Issue 3 , September 2012 , pp. 355 - 364
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2012

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Arcoya, A., Gonzalez, J.A., Tavieso, N. & Seoane, X.L. (1994) Physicochemical and catalytic properties of a modified natural clinoptilolite. Clay Minerals, 29, 123–131.CrossRefGoogle Scholar
Chen, Y.M., Tsao, T.M., Liu, C.C., Huang, P.M. & Wang, M.K. (2010) Polymerization of catechin catalyzed by Mn-, Fe-, and Al-oxides. Colloids and Surfaces B. Biointerface, 81, 217–223.Google Scholar
Dai, Y.L., Zheng, S.Q. & Qian, D. (2009) Sulphur reduction in fluid catalytic cracking using a kaolin in situ crystallization catalyst modified with vanadium. Clay Minerals, 44, 281–288.CrossRefGoogle Scholar
Duxiao, J., Nongyue, H., Yuanying, Z., Chunxiang, X., Chunwei, Y. & Zuhong, L. (2001) Catalytic growth of carbon nanotubes from the internal surface of Feloading mesoporous molecular sieves materials. Materials Chemistry and Physics, 69, 246–251.CrossRefGoogle Scholar
Fukuchi, S., Miura, A., Okabe, R., Fukushima, M., Sasaki, M. & Sato, T. (2010) Spectroscopic investigations of humic-like acids formed via polycondensation reactions between glycine, catechol, and glucose in the presence of natural zeolites. Journal of Molecular Structure, 982, 181–186.Google Scholar
Fukushima, M., Tanaka, S., Nakamura, H. & Ito, S. (1996) Acid-based characterization of molecular weight fractioned humic acid. Talanta, 43, 383–390.Google Scholar
Fukushima, M., Tanabe, Y., Morimoto, K. & Tatsumi, K. (2007) Role of humic acid fraction with higher aromaticity in enhancing the activity of a biomimetic catalyst, tetra(p-sulfonatophenyl)porphineiron(III). Biomacromolecules, 8, 386–391.CrossRefGoogle ScholarPubMed
Fukushima, M., Miura, A., Sasaki, M. & Izumo, K. (2009a) Effect of an allophonic soil on humification reactions between catechol and glycine: Spectroscopic investigations of reaction products. Journal of Molecular Structure, 917, 142–147.Google Scholar
Fukushima, M., Yamamoto, M., Komai, T. & Yamamoto, K. (2009b) Studies of structural alterations of humic acids from conifer bark residue during composting by pyrolysis-gas chromatography/mass spectrometry using tetramethylammonium hydroxide (TMAH-py-GC/MS). Journal of Analytical and Applied Pyrolysis, 86, 200–206.CrossRefGoogle Scholar
Fukushima, M., Furubayashi, K., Fujisawa, N., Takeuchi, M., Komai, T., Otsuka, K., Yamamoto, M., Kawabe, Y. & Horiya, S. (2011) Characterization of humic acids in sediments from dam reservoirs by pyrolysis-gas chromatography/mass spectrometry using tetramethylammonium hydroxide: Influence of the structural features of humic acids on iron(II) binding capacity. Journal of Analytical and Applied Pyrolysis, 91, 323–331.Google Scholar
Haffenden, L.J.W. & Yaylayan, V.A. (2005) Mechanism of formation ofredox-active hydroxylated benzenes and pyrazine in 13C-labeled glycine/D-glucose model systems. Journal of Agricultural and Food Chemistry, 53, 9742–9746.Google Scholar
Hsu, P.-H. & Hatcher, P.G. (2005) New evidence for covalent coupling of peptides to humic acids based on 2D NMR spectroscopy: A means for preservation. Geochimica et Cosmochimica Acta, 69, 4521–4533.Google Scholar
Ikeya, K., Yamamoto, S. & Watanabe, A. (2004) Semiquantitative GC/MS analysis of thermochemolysis products of soil humic acids with various degrees of humification. Organic Geochemistry, 35, 583–594.Google Scholar
Kashiwaya, Y., Nakamitsu, T., Kinoshita, H. & Miura, S. (2011) Binding energy of carbon in planted into hematite and in situ observation of reaction behavior during heating up experiment. ISIJ International, 51, 1204–1212.Google Scholar
Kowalak, S. & Jankowska, A. (2011) Natural zeolites for styrene oligomerization. Clay Minerals, 46, 189–195.Google Scholar
Kumada, K. (1955) Absorption spectra of humic substances. Soil and Plant Food, 1, 29–30.Google Scholar
Kung, K.-H. & McBride, M.B. (1988) Electron transfer processes between hydroquinone and iron oxides. Clays and Clay Minerals, 36, 303–309.Google Scholar
McBride, M.B. (1987) Adsorption and oxidation of phenolic compounds by iron and manganese oxides. Soil Science Society of America Journal, 51, 1466–1472.CrossRefGoogle Scholar
Mahieu, N., Olk, D.C. & Randall, E.W. (2000) Accumulation of heterocyclic nitrogen in humified organic matter: a 15N-NMR study of lowland rice soils. European Journal of Soil Science, 51, 379–389.Google Scholar
Miura, A., Okabe, R., Izumo, K. & Fukushima, M. (2009) Influence of the physicochemical properties of clay minerals on the degree of darkening via polycondensation reactions between catechol and glycine. Applied Clay Science, 46, 277–282.Google Scholar
Miura, A., Fukuchi, S., Okabe, R., Fukushima, M., Sasaki, M. & Sato, T. (2011) Effect of different fractions of weathered pumice in the formation of humic-like substances. Clay Minerals, 46, 637–648.Google Scholar
Okabe, R., Miura, A., Fukushima, M., Terashima, M., Sasaki, M., Fukuchi, S. & Sato, T. (2011) Characterization of an adsorbed humic-like substance on an allophonic soil formed via catalytic polycondensation between catechol and glycine, and its adsorption capacity to pentachlorophenol. Chemosphere, 83, 1502–1506.Google Scholar
Orlov, D.S. (1995) Humic Substances of Soils and General Theory of Humification, pp. 8–49. Moscow University Press, Moscow.Google Scholar
Qi, G., Yue, D., Fukushima, M., Fukuchi, S. & Nie, Y. (2012) Enhanced humification by carbonated basic oxygen furnace steel slag – I. Characterization of humic-like acids produced from humic precursors. Bioresource Technology, 104, 497–502.Google Scholar
Shindo, H. & Huang, P.M. (1982) Role of Mn(IV) oxide in abiotic formation of humic substances in the environment, Nature, 298, 363–365.Google Scholar
Shindo, H. & Huang, P.M. (1984a) Catalytic effects of manganese(IV), iron(III), aluminum and siliconoxides on the formation of phenolic polymers. Soil Sciences Society of America Journal, 48, 927–934.Google Scholar
Shindo, H. & Huang, P.M. (1984b) Significance of Mn(IV) oxide in abiotic formation of organic nitrogen complexes in natural environments. Nature, 298, 363–365.Google Scholar
Shindo, H. & Huang, P.M. (1985) The catalytic powers of inorganic components in the abiotic synthesis of hydroquinone-derived humic polymers. Applied Clay Science, 1, 71–81.CrossRefGoogle Scholar
Tan, K. (2003) Humic Matter in Soil and Environment: Principles and Controversies, Chapter 2. Dekker, New York.Google Scholar
Tressl, R., Wondrac, G.T., Garbe, L.-A. & Agric, J. (1998) Pentoses and hexoses as sources of new melanoidinlike Maillard polymers. Food Chemistry, 46, 1765–1776.Google Scholar
Wang, M.C. & Huang, P.M. (2000) Ring cleavage and oxidative transformation of pyrogarollol catalyzed by Mn, Fe, Al, Si Oxides. Soil Science, 165, 934–942.Google Scholar
Wang, M.C. & Huang, P.M. (2003) Cleavage and polycondensation of pyrogallol and glycine catalyzed by natural soil clays. Geoderma, 112, 31–50.Google Scholar
Wang, M.C. & Huang, P.M. (2005) Cleavage of 14Clabeled glycine and its polycondensation with pyrogallol as catalyzed by birnessite. Geoderma, 124, 415–426.Google Scholar
Ward, J.W. (1967) The nature of active sites on zeolites: II. Temperature dependence of the infrared spectra of hydrogen Y zeolite. Journal of Catalysis, 9, 396–402.Google Scholar
Yabuta, H., Fukushima, M., Kawasaki, M., Tanaka, F., Kobayashi, T. & Tatsumi, K. (2008) Multiple polar components in poorly-humified humic acids stabilizing free radicals: carboxyl and nitrogen-containing carbons. Organic Geochemistry, 39, 1319–1335.Google Scholar
Zheng, S.Q., Sun, S.H., Wang, Z.F., Gao, X.H. & Xu, X.L. (2005) Suzhou kaolin as FCC catalyst. Clay Minerals, 40, 303–310.Google Scholar