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Esterified lignins from Pinus caribaea as bentonite-dispersing agents

Published online by Cambridge University Press:  13 March 2018

Nacarid Delgado ,
Fredy Ysambertt ,
Raúl Ochoa ,
Gerson Chávez ,
Bélgica Bravo ,
Jorge Santos  and
Danny E. García
Nacarid Delgado*
Affiliation:
Área de Bioproductos, Unidad de Desarrollo Tecnológico (UDT), Universidad de Concepción, Coronel, Biobío, Chile Laboratorio de Petroquímica y Surfactantes (LPS), Departamento de Química, Facultad Experimental de Ciencias, Universidad del Zulia, Maracaibo, Venezuela
Fredy Ysambertt
Affiliation:
Laboratorio de Instrumentación Analítica (LIA), Departamento de Química, Facultad Experimental de Ciencias, Universidad del Zulia, Maracaibo, Venezuela
Raúl Ochoa
Affiliation:
Laboratorio de Petroquímica y Surfactantes (LPS), Departamento de Química, Facultad Experimental de Ciencias, Universidad del Zulia, Maracaibo, Venezuela
Gerson Chávez
Affiliation:
Laboratorio de Petroquímica y Surfactantes (LPS), Departamento de Química, Facultad Experimental de Ciencias, Universidad del Zulia, Maracaibo, Venezuela
Bélgica Bravo
Affiliation:
Laboratorio de Petroquímica y Surfactantes (LPS), Departamento de Química, Facultad Experimental de Ciencias, Universidad del Zulia, Maracaibo, Venezuela
Jorge Santos
Affiliation:
Área de Bioproductos, Unidad de Desarrollo Tecnológico (UDT), Universidad de Concepción, Coronel, Biobío, Chile
Danny E. García
Affiliation:
Laboratorio de Fitoquímica, Departamento de Química Ambiental, Facultad de Ciencias, Universidad Católica de la Santísima Concepción (UCSC), Biobío, Chile Centro de Investigación en Biodiversidad y Ambientes Sustentables (CIBAS). UCSC, Biobío, Chile Investigador Asociado Área de Bioproductos, UDT, UdeC, Concepción, Biobío, Chile
*
*E-mail: [email protected]
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Abstract

Chemical modification of kraft lignin from Pinus caribaea (Sénécl.) W.H.G. was performed with cyclic anhydrides (succinic, maleic and glutaric) assisted by microwave radiation. Esterification of the lignin was proven by the mass increase and Fourier Transform Infrared (FTIR) spectroscopy. Aqueous suspensions of bentonite were prepared using unmodified lignin and the corresponding derivatives as dispersants. Suspensions were evaluated in term of stability, viscosity and dispersibility. The esterified derivatives showed better dispersing properties than the neat lignin because the derivatives-based suspensions were less viscous. The dispersing properties of lignin and the esterified derivatives were compared with those of a high-molecular-weight lignin fraction obtained by ultrafiltration. In addition, two commercial lignosulfonate dispersants commonly used for drilling muds were used as references. The high-molecular-weight esterified derivatives proved to be better dispersants than their unfractionated counterparts. In general, the esterified derivatives showed similar properties to those obtained with the commercial dispersants. Modified lignin based on succinic-, maleic- and glutaric-anhydride is expected to play a key role in the design of novel bio-based dispersants for drilling-mud applications.

Keywords

ligninesterificationdispersantbentonite
Type
Article
Information
Clay Minerals , Volume 53 , Issue 1 , March 2018 , pp. 41 - 51
Copyright
Copyright © Mineralogical Society of Great Britain and Ireland 2018 

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Footnotes

Associate Editor: Miroslav Pospíšil

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