Hostname: page-component-cd9895bd7-dzt6s Total loading time: 0 Render date: 2024-12-17T02:37:07.521Z Has data issue: false hasContentIssue false
  • English
  • Français

Enhancement of the adsorption properties of two natural bentonites by ion exchange: equilibrium, kinetics and thermodynamic study

Published online by Cambridge University Press:  24 June 2020

Ali Boukhemkhem ,
Alejandro H. Pizarro  and
Carmen B. Molina Open the ORCID record for Carmen B. Molina [Opens in a new window]
Ali Boukhemkhem
Affiliation:
Laboratory Interactions Materials – Environment (LIME), University of Mohamed Seddik Ben Yahia, Jijel, 18000, Algeria
Alejandro H. Pizarro
Affiliation:
Chemical Engineering Department, Faculty of Sciences, Universidad Autónoma de Madrid, Cantoblanco, 28049, Madrid, Spain
Carmen B. Molina*
Affiliation:
Chemical Engineering Department, Faculty of Sciences, Universidad Autónoma de Madrid, Cantoblanco, 28049, Madrid, Spain
*
*E-mail: [email protected]
Get access Rights & Permissions [Opens in a new window]

Abstract

In this investigation, Maghnia (Ma) and Mostaganem (Ms) bentonite clays, mined from west Algeria, with no prior affinity for anionic dyes, were modified by simple ion exchange with aqueous Fe3+ solutions, followed by calcination at 500°C. The resulting materials, Fe-Ma and Fe-Ms, respectively, were employed as adsorbents for methyl orange. The starting materials and the two adsorbents were characterized by X-ray diffraction, N2 adsorption–desorption isotherms, Brunauer–Emmett–Teller specific surface area and X-ray fluorescence and by determining the point of zero charge. The effects of various variables, such as initial dye concentration, contact time, adsorbent dose, initial pH and adsorption temperature, were studied. The kinetics were well described by the pseudo-second-order model and the mechanism was determined from the intraparticle diffusion model, while corresponding isotherms fitted better to the Freundlich model. Thermodynamic parameters showed that the adsorption process was endothermic, spontaneous and physical in nature, accompanied by an increase of entropy.

Keywords

adsorptionintraparticle diffusion modelmethyl orangemodified bentonitespseudo-second-order modelthermodynamics
Type
Article
Information
Clay Minerals , Volume 55 , Issue 2 , June 2020 , pp. 132 - 141
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland, 2020

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Footnotes

Associate Editor: Javier Huertas

References

Almeida, C.A.P., Debacher, N.A., Downs, A.J., Cottet, L. & Mello, C.A.D. (2009) Removal of methylene blue from colored effluents by adsorption on montmorillonite clay. Journal of Colloid Interface Science, 332, 46–53.CrossRefGoogle ScholarPubMed
Arshadi, M., Mousavinia, F., Amiri, M.J. & Faraji, A.R. (2016) Adsorption of methyl orange and salicylic acid on a nano-transition metal composite: kinetics, thermodynamic and electrochemical studies. Journal of Colloid Interface Science, 483, 118–131.CrossRefGoogle ScholarPubMed
Auta, M. & Hamedd, B.H. (2012) Modified mesoporous clay adsorbent for adsorption isotherm and kinetics of methylene blue. Chemical Engineering Journal, 198–199, 219–227.CrossRefGoogle Scholar
Belhouchat, N., Zaghouane-Boudiaf, H. & Viseras, C. (2017) Removal of anionic and cationic dyes from aqueous solution with activated organo-bentonite/sodium alginate encapsulated beads. Applied Clay Science, 135, 9–15.CrossRefGoogle Scholar
Boukhemkhem, A., Rida, K., Pizarro, A.H., Molina, C.B. & Rodriguez, J.J. (2019) Fe catalyst supported on modified kaolin for catalytic wet peroxide oxidation. Clay Minerals, 54, 67–73.CrossRefGoogle Scholar
Chen, H., Yan, H., Pei, Z., Wu, J., Li, R., Jin, Y. & Zhao, J. (2015) Trapping characteristic of halloysite lumen for methyl orange. Applied Surface Science, 347, 769–776.CrossRefGoogle Scholar
Chen, J. & Zhu, L. (2009) Comparative study of catalytic activity of different Fe-pillared bentonites in the presence of UV light and H2O2. Separation and Purification Technology, 67, 282–288.CrossRefGoogle Scholar
Chen, S., Zhang, J., Zhang, C., Yue, Q., Li, Y. & Li, C. (2010) Equilibrium and kinetic studies of methyl orange and methyl violet adsorption on activated carbon derived from Phragmites australis. Desalination, 252, 149–156.CrossRefGoogle Scholar
Chen, Z., Jin, X., Chen, Z., Megharaj, M. & Naidu, R. (2011) Removal of methyl orange from aqueous solution using bentonite-supported nanoscale zero-valent iron. Journal of Colloid Interface Science, 363, 601–607.CrossRefGoogle ScholarPubMed
Daud, N.K. & Hameed, B.H. (2010) Decolorization of acid red 1 by Fenton-like process using rice husk ash-based catalyst. Journal of Hazardous Materials, 176, 938–944.CrossRefGoogle ScholarPubMed
De Castro, M.L.F.A., Abad, M.L.B., Sumalinog, D.G., Abarca, R.R.M., Paoprasert, P. & de Luna, M.D.G. (2018) Adsorption of methylene blue dye and Cu(II) ions on EDTA-modified bentonite: isotherm, kinetics and thermodynamic studies. Environment, Development and Sustainability, 5, 197–205.Google Scholar
Gil, A., Assis, F.C.C., Albeniz, S. & Korili, S.A. (2011) Removal of dyes from wastewaters by adsorption on pillared clays. Chemical Engineering Journal, 168, 1032–1040.CrossRefGoogle Scholar
Giles, C., MacEwan, T. & Nakhwa, S.N. (1960) Studies in adsorption. Part XI. A system of classification of solution adsorption isotherms and its use in diagnosis of adsorption mechanisms and in measurement of specific surface areas of solids. Journal of the Chemical Society, 3973–3993.CrossRefGoogle Scholar
Gitari, W.M., Ngulube, T., Masindi, V. & Gumbo, J.R. (2013) Defluoridation of groundwater using Fe3+ modified bentonite clay: optimization of adsorption conditions. Desalination and Water Treatment, 53, 1578–1590.CrossRefGoogle Scholar
Guo, J., Chen, S., Liu, L., Li, B., Yang, P., Zhang, L. & Feng, Y. (2012) Adsorption of dye from wastewater using chitosan–CTAB modified bentonites. Journal of Colloid Interface Science, 382, 61–66.CrossRefGoogle ScholarPubMed
Hamdaoui, O. (2006) Batch study of liquid-phase adsorption of methylene blue using cedar sawdust and crushed brick. Journal of Hazardous Materials, B135, 264–273.CrossRefGoogle Scholar
Hamdaoui, O. & Naffrechoux, E. (2007) Modeling of adsorption isotherms of phenol and chlorophenols onto granular activated carbon. Part I. Two parameter models and equations allowing determination of thermodynamic parameters. Journal of Hazardous Materials, 147, 381–394.CrossRefGoogle ScholarPubMed
Hao, Y., Yan, L., Yu, H., Yang, K., Yu, S., Shan, R. & Du, B. (2014) Comparative study on adsorption of basic and acid dyes by hydroxy-aluminum pillared bentonite. Journal of Molecular Liquids, 199, 202–207.CrossRefGoogle Scholar
Hassan, H. & Hameed, B.H. (2011) Fe-clay as effective heterogeneous Fenton catalyst for the decolorization of reactive blue 4. Chemical Engineering Journal, 171, 912–918.CrossRefGoogle Scholar
He, J., Dai, J., Zhang, T., Sun, J., Xie, A., Tian, S. et al. (2016) Preparation of highly porous carbon from sustainable αcellulose for superior performance removal of tetracycline and sulfamethazine from water. RSC Advances, 6, 28023–28033.CrossRefGoogle Scholar
He, K., Chen, G., Zeng, G., Chen, A., Huang, Z., Shi, J. et al. (2018) Enhanced removal performance for methylene blue by kaolin with graphene oxide modification. Journal of the Taiwan Institute of Chemical Engineers, 89, 77–85.CrossRefGoogle Scholar
Huang, R., Liu, Q., Zhang, L. & Yang, B. (2015) Utilization of cross-linked chitosan/bentonite composite in the removal of methyl orange from aqueous solution. Water Science and Technology, 71, 174–182.CrossRefGoogle ScholarPubMed
Huo, X.X., Deng, Q.F.R.T.Z. & Yuan, Z.Y. (2013) Adsorption of Cu2+ and methyl orange from aqueous solutions by activated carbons of corncob-derived char wastes. Environmental Science and Pollution Research, 20, 8521–8534.Google Scholar
Issa, A.A., Al-Degs, Y.S., Al-Ghouti, M.A. & Olimat, A.A.M. (2014) Studying competitive sorption behavior of methylene blue and malachite green using multivariate calibration. Chemical Engineering Journal, 240, 554–564.CrossRefGoogle Scholar
Jiang, R., Fu, Y., Zhu, H., Yao, J. & Xiao, L. (2012) Removal of methyl orange from aqueous solutions by magnetic maghemite/chitosan nanocomposite films: adsorption kinetics and equilibrium. Journal of Applied Polymer Science, 125, 540–549.CrossRefGoogle Scholar
Khenifi, A., Bouberka, Z., Sekrane, F., Kamech, M. & Derriche, Z. (2007) Adsorption study of an industrial dye by an organic clay. Adsorption, 13, 149–158.CrossRefGoogle Scholar
Kumar, M. & Tamilarasan, R. (2013) Modeling of experimental data for the adsorption of methyl orange from aqueous solution using a low cost activated carbon prepared from Prosopis juliflora. Polish Journal of Chemical Technology, 15, 29–39.CrossRefGoogle Scholar
Kushwaha, A.K., Gupta, N. & Chattopadhyaya, M.C. (2011) Removal of cationic methylene blue and malachite green dyes from aqueous solution by waste materials of Daucus carota. Journal of Saudi Chemical Society, 18, 200–207.CrossRefGoogle Scholar
Leodopoulos, C., Doulia, D., Gimouhopoulos, K. & Triantis, T.M. (2012) Single and simultaneous adsorption of methyl orange and humic acid onto bentonite. Applied Clay Science, 70, 84–90.CrossRefGoogle Scholar
Leon, G., Garcia, F., Miguel, B. & Bayo, J. (2015) Equilibrium, kinetic and thermodynamic studies of methyl orange removal by adsorption onto granular activated carbon. Desalination and Water Treatment, 57, 17104–171171.Google Scholar
Li, D., Yang, Y., Li, C. & Liu, Y. (2017) A mechanistic study on decontamination of methyl orange dyes from aqueous phase by mesoporous pulp waste and polyaniline. Environmental Research, 154, 139–144.CrossRefGoogle Scholar
Liu, Z., Zhou, A., Wang, G. & Zhao, X. (2009) Adsorption behavior of methyl orange onto modified ultrafine coal powder. Chinese Journal of Chemical Engineering, 17, 942–948.CrossRefGoogle Scholar
Luo, Z., Gao, M., Ye, Y. & Yang, S. (2015) Modification of reduced-charge montmorillonites by a series of Gemini surfactants: characterization and application in methyl orange removal. Applied Surface Science, 324, 807–816.CrossRefGoogle Scholar
Ma, Q., Shen, F., Lu, X., Bao, W. & Ma, H. (2013) Studies on the adsorption behavior of methyl orange from dye wastewater onto activated clay. Desalination and Water Treatment, 51, 19–21.CrossRefGoogle Scholar
Mobarak, M., Selim, A.Q., Mohammed, E.A. & Seliem, M.K. (2018) A superior adsorbent of CTAB/H2O2 solution-modified organic carbon rich-clay for hexavalent chromium and methyl orange uptake from solutions. Journal of Molecular Liquids, 259, 384–397.CrossRefGoogle Scholar
Morais, W.A., de Almeida, A.L.P., Pereira, M.R. & Fonseca, J.L.C. (2008) Equilibrium and kinetic analysis of methyl orange sorption on chitosan spheres. Carbohydrate Research, 343, 2489–2493.CrossRefGoogle ScholarPubMed
Mouni, L., Belkhiri, L., Bollinger, J.C., Bouzaza, A., Assadi, A., Tirri, A. et al. (2018) Removal of methylene blue from aqueous solutions by adsorption on kaolin: kinetic and equilibrium studies. Applied Clay Science, 153, 38–45.CrossRefGoogle Scholar
Nadaroglu, H., Kalkan, E., Celebi, N. & Tasgin, E. (2015) Removal of reactive black 5 from wastewater using natural clinoptilolite modified with apolaccase. Clay Minerals, 50, 65–76.CrossRefGoogle Scholar
Patrulea, V., Negrulescu, A., Mincea, M.M., Pitulice, L.D., Spiridon, O.B. & Ostafe, V. (2013) Optimization of the removal of copper (II) ions from aqueous solution on chitosan and cross-linked chitosan beads. Bioresources, 8, 1147–1165.CrossRefGoogle Scholar
Rocher, V., Bee, A., Siaugue, J.M. & Cabuil, V. (2010) Dye removal from aqueous solution by magnetic alginate beads crosslinked with epichlorohydrin. Journal of Hazardous Materials, 178, 434–439.CrossRefGoogle ScholarPubMed
Soloman, P.A., Basha, C.A., Velan, M., Ramamurthi, V., Koteeswaran, K. & Balasubramanian, N. (2009) Electrochemical degradation of remazol black B dye effluent. Clean – Soil Air Water, 37, 889–900.CrossRefGoogle Scholar
Sui, K., Li, Y., Liu, R., Zhang, Y., Zhao, X., Liang, H. & Xia, Y. (2012) Biocomposite fiber of calcium alginate/multi-walled carbon nanotubes with enhanced adsorption properties for ionic dyes. Carbohydrate Polymers, 90, 399–406.CrossRefGoogle ScholarPubMed
Tang, Y., Yang, R., Ma, D., Zhou, B., Zhu, L. & Yang, J. (2017) Removal of methyl orange from aqueous solution by adsorption onto a hydrogel composite. Polymers and Polymer Composites, 26, 161–168.CrossRefGoogle Scholar
Tomic, Z.P., Logar, V.P., Babic, B.M., Rogan, J.R. & Makreski, P. (2011) Comparison of structural, textural and thermal characteristics of pure and acid treated bentonites from Aleksinac and Petrovac (Serbia), Spectrochimica Acta Part A, 82, 389–395.CrossRefGoogle Scholar
Trevino-Cordero, H., Juarez-Aguilar, L.G., Mendoza-Castillo, D.I., Hernandez-Montoya, V., Bonilla-Petriciolet, A. & Montes-Moran, M.A. (2013) Synthesis and adsorption properties of activated carbons from biomass of Prunus domestica and Jacaranda mimosifolia for the removal of heavy metals and dyes from water. Industrial Crops and Products, 42, 315–323.CrossRefGoogle Scholar
Wan, J., Tao, T., Zhang, Y., Liang, X., Zhou, A. & Zhu, C. (2016) Phosphate adsorption on novel hydrogel beads with interpenetrating network (IPN) structure in aqueous solutions: kinetics, isotherms and regeneration. RSC Advances, 6, 23233–23241.CrossRefGoogle Scholar
Zang, W., Gao, M., Shen, T., Ding, F. & Wang, J. (2017) Facile modification of homoionic-vermiculites by a Gemini surfactant: comparative adsorption exemplified by methyl orange. Colloids and Surfaces A, 533, 99–108.CrossRefGoogle Scholar
Zeng, L., Xie, M., Zhang, Q., Kang, Y., Guo, X., Xiao, H. et al. (2015) Chitosan/organic rectorite composite for the magnetic uptake of methylene blue and methyl orange. Carbohydrate Polymers, 123, 89–98.CrossRefGoogle ScholarPubMed
Zhang, G., Liu, G. & Guo, Y. (2011) Adsorption of methylene blue from aqueous solution onto hydrochloric acid-modified rectorite. Journal of the Wuhan University of Technology, Materials Science Edition, 26, 817–822.CrossRefGoogle Scholar
Zhang, L., Hu, P., Wang, J., Liu, Q. & Huang, R. (2015) Adsorption of methyl orange (MO) by Zr (IV)-immobilized cross-linked chitosan/bentonite composite. International Journal of Biological Macromolecules, 81, 818–827.CrossRefGoogle ScholarPubMed
Zhu, H.Y., Giang, R. & Xiao, L. (2010) Adsorption of an anionic azo dye by chitosan/kaolin/γ-Fe2O3 composites. Applied Clay Science, 48, 522–526.CrossRefGoogle Scholar
Supplementary material: Image

Boukhemkhem et al. supplementary material

Boukhemkhem et al. supplementary material 1

Download Boukhemkhem et al. supplementary material(Image)
Image 74.5 KB
Supplementary material: Image

Boukhemkhem et al. supplementary material

Boukhemkhem et al. supplementary material 2

Download Boukhemkhem et al. supplementary material(Image)
Image 70.7 KB
Supplementary material: File

Boukhemkhem et al. supplementary material

Boukhemkhem et al. supplementary material 3

Download Boukhemkhem et al. supplementary material(File)
File 12.2 KB
Supplementary material: Image

Boukhemkhem et al. supplementary material

Boukhemkhem et al. supplementary material 4
Download Boukhemkhem et al. supplementary material(Image)
Image 2.6 MB