Hostname: page-component-78c5997874-j824f Total loading time: 0 Render date: 2024-11-08T05:03:33.667Z Has data issue: false hasContentIssue false
  • English
  • Français

27Al Satellite Transition MAS-NMR Spectroscopy of Kaolinite

Published online by Cambridge University Press:  09 July 2018

J. Rocha  and
J. D. Pedrosa De Jesus
J. Rocha
Affiliation:
Department of Chemistry, University of Aveiro, 3800 Aveiro, Portugal
J. D. Pedrosa De Jesus
Affiliation:
Department of Chemistry, University of Aveiro, 3800 Aveiro, Portugal
Get access Rights & Permissions [Opens in a new window]

Abstract

Highly crystalline kaolinite has been studied by 27Al satellite transition magic angle-spinning (MAS) nuclear magnetic resonance (NMR) spectroscopy. This technique provides an additional narrowing of the MAS spectral lines by a factor of more than three compared with the width of the prominent central transition. Evidence for the presence of two crystallographically inequivalent hexacoordinated Al sites has been found. The results support the kaolinite crystal structure proposed by Bish & Von Dreele (1989).

Type
Research Article
Information
Clay Minerals , Volume 29 , Issue 2 , June 1994 , pp. 287 - 291
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1994

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Bish, D.L. & Von Dreele, R.B. (1989) Rietveld refinement of non-hydrogen atomic positions in kaolinite. Clays Clay Miner, 37, 289–296.Google Scholar
Engelhardt, G. & Michel, D. (1987) High-resolution Solid State NMR of Silicates and Zeolites. J. Wiley, New York.Google Scholar
Jäger, C., Rocha, J. & Klinowski, J. (1992) High-speed satellite transition 27A1 MAS NMR spectroscopy. Chem. Phys. Lett, 188, 208–212.CrossRefGoogle Scholar
Jakobsen, H.J., Skibsted, J., Bildsøe, H. & Nielsen, N.C. (1989) Magic-angle spinning NMR spectra of satellite transitions for quadrupolar nuclei in solids. J. Magn. Reson, 85, 173–180.Google Scholar
Rocha, J. & Klinowski, J. (1990) Kaolinite as a convenient standard for setting the Hartmann-Hahn match for 29Si CP/MAS NMR of silicates. J. Magn. Reson, 90, 567–568.Google Scholar
Samoson, A. (1985) Satellite transition high-resolution NMR of quadrupolar nuclei in powders. Chem. Phys. Lett, 119, 29–32.Google Scholar
Skibsted, J., Nielsen, N.C., Bildsøe, H. & Jakobsen, H.J. (1991) Satellite transitions in MAS NMR spectra of quadrupolar nuclei. J. Magn. Reson, 95, 88–117.Google Scholar