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Organo-metallic clay complexes Part II*

Published online by Cambridge University Press:  14 March 2018

W. Bodenheimer ,
L. Heller ,
B. Kirson  and
SH. Yariv
W. Bodenheimer
Affiliation:
Geological Survey of Israel, Jerusalem
L. Heller
Affiliation:
Geological Survey of Israel, Jerusalem
B. Kirson
Affiliation:
Department of Inorganic Chemistry, Hebrew University, Jerusalem
SH. Yariv
Affiliation:
Department of Inorganic Chemistry, Hebrew University, Jerusalem
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Abstract

Complex formation enhances the sorption of various diamines from aqueous solutions by montmorillonite in the presence of copper and vice versa. A distinct difference was observed between chelating and nonchelating diamines. The effects were measured quantitatively, and the resulting structures were investigated by X-ray diffraction tedhniques. No direct correlation was observed between cell height and the configuration of the interlayer complexions; ‘keying’ of organic and organometallic cations into the oxygen surfaces is inferred.

Type
Research Article
Information
Clay Minerals Bulletin , Volume 5 , Issue 28 , December 1962 , pp. 145 - 154
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1962

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Footnotes

†

This paper is an abridged version of part of a thesis to be submitted by Sh. Yariv to the Hebrew University for the degree of Fh.D.

*

Part I was presented at a meeting of the Israel Chemical Society, Haifa, 28th September, 1961.

References

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